Citation: WANG Xiao-liu, YANG Meng, ZHU Ling-jun, ZHU Xiao-nan, WANG Shu-rong. CO₂ methanation over Ni/Mg@MCM-41 prepared by in-situ synthesis method[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(4): 456-465. shu

CO₂ methanation over Ni/Mg@MCM-41 prepared by in-situ synthesis method

State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China

Corresponding author: WANG Shu-rong, srwang@zju.edu.cn
Received Date: 17 January 2020
Revised Date: 8 March 2020

Fund Project: The project was supported by the National Science Fund for Distinguished Young Scholars (51725603)the National Science Fund for Distinguished Young Scholars 51725603

Figures(8)

A series of xMg@MCM-41(x=0, 0.05, 0.1) functional mesoporous materials were synthesized by a novel in-situ one pot method and then were used as support for Ni based catalysts. The results of XRD and TEM show that when the amount of Mg/Si (molar ratio) is 0.05, Mg@MCM-4 with a regular and ordered mesoporous structure is synthesized where Mg is introduced into the framework of MCM-41. Introducing Mg into the framework of the support can significantly enhance the basic properties of the catalyst, thus promoting the adsorption and activation of CO₂. The catalysts prepared in the experiments all have good thermal stability and catalytic activity. Among them, Ni/0.05Mg@MCM-41 shows the best low temperature reaction activity in the CO₂ methanation reaction.
- CO₂,
- methanation,
- in-situ,
- Mg@MCM-41,
- catalytic activity
1. [1]
  SONG Q, ZHOU Z, HE L. Efficient, selective and sustainable catalysis of carbon dioxide[J]. Green Chem, 2017,19(16):3707-3728. doi: 10.1039/C7GC00199A
2. [2]
  FRONTERA P, MACARIO A, FERRARO M, ANTONUCCI P. Supported catalysts for CO₂ methanation:A review[J]. Catalysts, 2017,7(2).
3. [3]
  BAILERA M, LISBONA P, ROMEO L M, ESPATOLERO S. Power to gas projects review:Lab, pilot and demo plants for storing renewable energy and CO₂[J]. Renewable Sustainable Energy Rev, 2017,69:292-312. doi: 10.1016/j.rser.2016.11.130
4. [4]
  CHEN J, WANG M, WANG S, LI X. Hydrogen production via steam reforming of acetic acid over biochar-supported nickel catalysts[J]. Int J Hydrogen Energy, 2018,4(39):18160-18168.
5. [5]
  AZIZ M A A, JALIL A A, TRIWAHYONO S, SAAD M W A. CO₂ methanation over Ni-promoted mesostructured silica nanoparticles:Influence of Ni loading and water vapor on activity and response surface methodology studies[J]. Chem Eng J, 2015,260:757-764. doi: 10.1016/j.cej.2014.09.031
6. [6]
  ZHU L, YIN S, YIN Q, WANG H, WANG S. Biochar:A new promising catalyst support using methanation as a probe reaction[J]. Energy Sci Eng, 2015,3(2):126-134.
7. [7]
  LI W, WANG H, JIANG X, ZHU J, LIU Z, GUO X, SONG C. A short review of recent advances in CO₂ hydrogenation to hydrocarbons over heterogeneous catalysts[J]. Rsc Adv, 2018,8(14):7651-7669. doi: 10.1039/C7RA13546G
8. [8]
  YIN S, ZHU L, LIU Y, WANG S. The effect of titanium source on methanation over Ni/TiO₂ catalysts[J]. Chem Res Chin Univ, 2017,34(2).
9. [9]
  LEE G D, MOON M J, PARK J H, PARK S S, HONG S S. Raney Ni catalysts derived from different alloy precursors Part II. CO and CO₂ methanation activity[J]. Korean J Chem Eng, 2005,22(4):541-546.
10. [10]
  BAYSAL Z, KURETI S. CO₂ methanation on Mg-promoted Fe catalysts[J]. Appl Catal B:Environ, 2020,262118300. doi: 10.1016/j.apcatb.2019.118300
11. [11]
  ALI S H, GIURCO D, ARNDT N, NICKLESS E, BROWN G, DEMETRIADES A, DURRHEIM R, ENRIQUEZ M A, KINNAIRD J, LITTLEBOY A, MEINERT L D, OBERHÄNSLI R, SALEM J, SCHODDE R, SCHNEIDER G, VIDAL O, YAKOVLEVA N. Mineral supply for sustainable development requires resource governance[J]. Nature, 2017,543(7645):367-372. doi: 10.1038/nature21359
12. [12]
  AZIZ M A A, JALIL A A, TRIWAHYONO S, AHMAD A. CO₂ methanation over heterogeneous catalysts:Recent progress and future prospects[J]. Green Chem, 2015,17(5):2647-2663. doi: 10.1039/C5GC00119F
13. [13]
  WANG W, GONG J. Methanation of carbon dioxide:An overview[J]. Front Chem Sci Eng, 2011,5(1):2-10. doi: 10.1007/s11705-010-0528-3
14. [14]
  ZHAO D, SUN J, LI Q, STUCKY G D. Morphological control of highly ordered mesoporous silica SBA-15[J]. Chem Mater, 2000,12(2):275-279.
15. [15]
  BECK J S, VARTULI J C, ROTH W J, LEONOWICZ M E, KRESGE C T, SCHMITT K D, CHU C T W, OLSON D H, SHEPPARD E W. A new family of mesoporous molecular sieves prepared with liquid crystal templates[J]. J Am Chem Soc, 1992,114(27):10834-10843. doi: 10.1021/ja00053a020
16. [16]
  BACARIZA M C, GRACA I, BEBIANO S S, LOPES J M, HENRIQUES C. Micro- and mesoporous supports for CO₂ methanation catalysts:A comparison between SBA-15, MCM-41 and USY zeolite[J]. Chem Eng Sci, 2018,175:72-83. doi: 10.1016/j.ces.2017.09.027
17. [17]
  ZHANG Jia-ying, XIN Zhong, MENG Xin, TAO Miao. Activity and stability of nickel based MCM-41 methanation catalysts for production of synthetic natural gas[J]. CIESC J, 2014,65(1):160-168. doi: 10.3969/j.issn.0438-1157.2014.01.020
18. [18]
  TAN J, WANG J, ZHANG Z, MA Z, WANG L, LIU Y. Highly dispersed and stable Ni nanoparticles confined by MgO on ZrO₂ for CO₂ methanation[J]. Appl Surf Sci, 2019,481:1538-1548. doi: 10.1016/j.apsusc.2019.03.217
19. [19]
  ZENG Yan, MA Hong-fang, ZHANG Hai-tao, YING Wei-yong, FANG Ding-ye. Ni-based methanation catalysts prepared by solution combustion method:Effect of Mg, Mn and La promoters[J]. Nat Gas Ind, 2015,40(4):6-10. doi: 10.3969/j.issn.1001-9219.2015.04.002
20. [20]
  BACARIZA M C, GRACA I, BEBIANO S S, LOPES J M, HENRIQUES C. Magnesium as promoter of CO₂ methanation on Ni-Based USY zeolites[J]. Energy Fuels, 2017,31(9):9776-9789. doi: 10.1021/acs.energyfuels.7b01553
21. [21]
  XU L, WANG F, CHEN M, YANG H, NIE D, QI L, LIAN X. Alkaline-promoted Ni based ordered mesoporous catalysts with enhanced low-temperature catalytic activity toward CO₂ methanation[J]. Rsc Adv, 2017,7(30):18199-18210. doi: 10.1039/C7RA01673E
22. [22]
  WANG X, ZHU L, ZHUO Y, ZHU Y, WANG S. Enhancement of CO₂ methanation over La-Modified Ni/SBA-15 catalysts prepared by different doping methods[J]. ACS Sustainable Chem Eng, 2019,7:14647-14660. doi: 10.1021/acssuschemeng.9b02563
23. [23]
  WANG X, ZHU L, LIU Y, WANG S. CO₂ methanation on the catalyst of Ni/MCM-41 promoted with CeO₂[J]. Sci Total Environ, 2018,625:686-695. doi: 10.1016/j.scitotenv.2017.12.308
24. [24]
  LIU Y, ZHU L, WANG S, FUKUDA S. Bio-MCM-41:A high-performance catalyst support derived from pyrolytic biochar[J]. New J Chem, 2018,42(15):12394-12402. doi: 10.1039/C8NJ01063C
25. [25]
  WANG X, LIU Y, ZHU L, LI Y, WANG K, QIU K, TIPPAYAWONG N, AGGARANGSI P, REUBROYCHAROEN P, WANG S. Biomass derived N-doped biochar as efficient catalyst supports for CO₂ methanation[J]. J CO₂ Util, 2019,34:733-741. doi: 10.1016/j.jcou.2019.09.003
26. [26]
  HONG Xin, TANG Ke. Preparation of heteroatomic mesoporous Ce-MCM-41 molecular sieve and its performance in the adsorptive removal of dimethyl sulfide[J]. J Fuel Chem Technol, 2015,43(4):456-461. doi: 10.3969/j.issn.0253-2409.2015.04.013
27. [27]
  JIA W, LIU T, LI Q, YANG J. Highly efficient photocatalytic reduction of CO₂ on surface-modified Ti-MCM-41 zeolite[J]. Catal Today, 2019,335:221-227. doi: 10.1016/j.cattod.2018.11.046
28. [28]
  MARLER B, OBERHAGEMANN U, VORTMANN S, GIES H. Influence of the sorbate type on the XRD peak intensities of loaded MCM-41[J]. Microporous Mater, 1996,6(5/6):375-383.
29. [29]
  SONG X, GUAN Q, SHU Y, ZHANG X, LI W. Facile in-situ encapsulation of highly dispersed Ni@MCM-41 for the trans-decalin production from hydrogenation of naphthalene at low temperature[J]. ChemCatChem, 2019,11(4):1286-1294. doi: 10.1002/cctc.201801788
30. [30]
  HAMMOND W, PROUZET E, MAHANTI S D, PINNAVAIA T J. Structure factor for the periodic walls of mesoporous MCM-41 molecular sieves[J]. Microporous Mesoporous Mater, 1999,27(1):19-25. doi: 10.1016/S1387-1811(98)00222-4
31. [31]
  ZHANG M, LIU Z, LIN G, ZHANG H. Pd/CNT-promoted CuZrO₂/HZSM-5 hybrid catalysts for direct synthesis of DME from CO₂/H₂[J]. Appl Catal A:Gen, 2013,451:28-35. doi: 10.1016/j.apcata.2012.10.038
32. [32]
  ZHANG Xu, SUN Wen-jing, CHU Wei. Effect of glow discharge plasma treatment on the performance of Ni/SiO₂ catalyst in CO₂ methanation[J]. J Fuel Chem Technol, 2013,41(1):96-101. doi: 10.3969/j.issn.0253-2409.2013.01.016
33. [33]
  SONG J, SUN Y, BA R, HUANG S, ZHAO Y, ZHANG J, SUN Y, ZHU Y. Monodisperse Sr-La₂O₃ hybrid nanofibers for oxidative coupling of methane to synthesize C₂ hydrocarbons[J]. Nanoscale, 2015,7(6):2260-2264. doi: 10.1039/C4NR06660J
34. [34]
  OCAMPO F, LOUIS B, KIWI-MINSKER L, ROGER A-C. Effect of Ce/Zr composition and noble metal promotion on nickel based Ce_xZr_1-xO₂ catalysts for carbon dioxide methanation[J]. Appl Catal A:Gen, 2011,392(1):36-44.
35. [35]
  ZHU Qiu-jun, WANG Hai-yang, LI Zhen-hua. Study on methanation of carbon monoxide over nickel-based catalysts[J]. Nat Gas Ind, 2012,37(2):17-20. doi: 10.3969/j.issn.1001-9219.2012.02.004
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CO₂ methanation over Ni/Mg@MCM-41 prepared by in-situ synthesis method