Citation: WANG Xiao-liu, YANG Meng, ZHU Ling-jun, ZHU Xiao-nan, WANG Shu-rong. CO₂ methanation over Ni/Mg@MCM-41 prepared by in-situ synthesis method[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(4): 456-465. shu

CO₂ methanation over Ni/Mg@MCM-41 prepared by in-situ synthesis method

State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China

Corresponding author: WANG Shu-rong, srwang@zju.edu.cn
Received Date: 17 January 2020
Revised Date: 8 March 2020

Fund Project: The project was supported by the National Science Fund for Distinguished Young Scholars (51725603)the National Science Fund for Distinguished Young Scholars 51725603

Figures(8)

A series of xMg@MCM-41(x=0, 0.05, 0.1) functional mesoporous materials were synthesized by a novel in-situ one pot method and then were used as support for Ni based catalysts. The results of XRD and TEM show that when the amount of Mg/Si (molar ratio) is 0.05, Mg@MCM-4 with a regular and ordered mesoporous structure is synthesized where Mg is introduced into the framework of MCM-41. Introducing Mg into the framework of the support can significantly enhance the basic properties of the catalyst, thus promoting the adsorption and activation of CO₂. The catalysts prepared in the experiments all have good thermal stability and catalytic activity. Among them, Ni/0.05Mg@MCM-41 shows the best low temperature reaction activity in the CO₂ methanation reaction.
- CO₂,
- methanation,
- in-situ,
- Mg@MCM-41,
- catalytic activity
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CO₂ methanation over Ni/Mg@MCM-41 prepared by in-situ synthesis method