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Citation: ZENG Peng-hui, ZHANG Li-li, GUO Xiao-zhong, LI Ming-fu, GUO Qiao-xia, NIU Chao, SHEN Bao-jian. Catalytic performances of Al-ITQ-13 zeolites with different SiO2/Al2O3 ratios in the conversion of methanol to propene[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(11): 1349-1355. shu

Catalytic performances of Al-ITQ-13 zeolites with different SiO2/Al2O3 ratios in the conversion of methanol to propene

  • State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, College of Sciences, China University of Petroleum(Beijing), Beijing 102249, China

  • Corresponding author: SHEN Bao-jian, baojian@cup.edu.cn
  • Received Date: 3 May 2017
    Revised Date: 13 June 2017

    Fund Project: the National Natural Science Foundation of China U1462202The project was supported by the National Natural Science Foundation of China (U1462202), the Science Foundation of China University of Petroleum-Beijing (2462015YQ0309)the Science Foundation of China University of Petroleum-Beijing 2462015YQ0309

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  • Al-ITQ-13 zeolites with different SiO2/Al2O3 molar ratios were synthesized by using seeds in the gel and characterized by XRD, SEM, N2 physisorption, MAS NMR and NH3-TPD. The effect of SiO2/Al2O3 molar ratio on the catalytic performance of Al-ITQ-13 in the conversion of methanol to propene (MTP) was investigated in a fixed-bed micro-reactor. The results showed that the Al-ITQ-13 zeolites with different SiO2/Al2O3 molar ratios are similar in their textural properties; however, the amount and strength of acid sites decrease with the increase of SiO2/Al2O3 molar ratio. Moreover, the SiO2/Al2O3 molar ratio has a significant influence on the catalytic behavior of Al-ITQ-13 in MTP. As the hydrogen transfer and aromatization reactions were suppressed over the Al-ITQ-13 zeolite with high SiO2/Al2O3 molar ratio, with the increase of SiO2/Al2O3 molar ratio, the selectivity to propene and butene is increased at the expense of the selectivity to propene; that is, with the increase of SiO2/Al2O3 molar ratio from 137 to 309, the selectivity to propene is increased from 46.04% to 55.52% and meanwhile, the propene/ethene ratio is increased from 3.39 to 6.57.
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    1. [1]

      ZHOU Huo-sheng. Purchasing strategy and scheme of propylene in 2012[J]. Yunnan Chem Technol, 2012,39(2):60-64.  

    2. [2]

      HUANG Hui-wei, MENG Xiao-jing, CHEN Chen, ZHANG Min-xiu, LI Chun-yi, CUI Qiu-kai. Study on SiO2/Al2O3 molar ratio of HZSM-5 catalyst in methanol to propylene reaction performance[J]. Petrochem Technol Appl, 2016,34(4):284-289.  

    3. [3]

      WEI Ru-chao, LI Chun-yi, YANG Chao-he, SHAN Hong-hong. Characterization and catalytic performance of (NH4)2SiF6-modified nanosized HZSM-5 catalyst for conversion of methanol to olefins[J]. Ind Catal, 2011,19(3):40-44.  

    4. [4]

      GUO Qiang-sheng, MAO Dong-sen, LAO Yan-ping, LU Guan-zhong. The effect of fluorine modification on catalytic performance of nanosized HZSM-5 zeolite for conversion of methanol to propene[J]. Chin J Catal, 2009,30(12):1248-1254. doi: 10.3321/j.issn:0253-9837.2009.12.012

    5. [5]

      BOIX T, PUCHE M, CAMBLOR M, CORMA A. Synthetic porous crystalline material ITQ-13, its synthesis and use:US6471941[P]. 2002-10-29. 

    6. [6]

      CORMA A, PUCHE M, REY F, SANKAR G, TEAT S J. A zeolite structure (ITQ-13) with three sets of medium-pore crossing channels formed by 9-and 10-rings[J]. Angew Chem Int Ed, 2003,42:1156-1159. doi: 10.1002/anie.200390304

    7. [7]

      SKISTAD W, TEKETEL S, BLEKEN F L, BEATO P, BORDIGA S, NILSEN M H, OLSBYE U, SVELLE S, LILLERUD K P. Methanol conversion to hydrocarbons (MTH) over H-ITQ-13(ITH) zeolite[J]. Top Catal, 2014,57:143-158. doi: 10.1007/s11244-013-0170-7

    8. [8]

      CASTANEDA R, CORMA A, FORNES V, MARTINEZ-TRIGUERO J, VALENCIA S. Direct synthesis of a 9×10 member ring zeolite (Al-ITQ-13):A highly shape-selective catalyst for catalytic cracking[J]. J Catal, 2006,238:79-87. doi: 10.1016/j.jcat.2005.11.038

    9. [9]

      SASTRE G, PULIDO A, CASTANEDA R, CORMA A. Effect of the germanium incorporation in the synthesis of EU-1, ITQ-13, ITQ-22, and ITQ-24 zeolites[J]. J Phys Chem B, 2004,108:8830-8835. doi: 10.1021/jp0378438

    10. [10]

      LLOPIS F, SASTRE G, CORMA A. Isomerization and disproportionation of m-xylene in a zeolite with 9-and 10-membered ring pores:Molecular dynamics and catalytic studies[J]. J Catal, 2006,242:195-206. doi: 10.1016/j.jcat.2006.05.034

    11. [11]

      CORMA A, VALENCIA. Catalytic cracking process:US 6709572[P]. 2004-3-23. 

    12. [12]

      EMEIS C A. Determination of integrated molar extinction coefficients for infrared absorption bands of pyridine adsorbed on solid acid catalysts[J]. J Catal, 1993,141:347-354. doi: 10.1006/jcat.1993.1145

    13. [13]

      ZENG P H, LIANG Y, JI S F, SHEN B J, LIU H H, WANG B J, ZHAO H J, LI M F. Preparation of phosphorus-modified PITQ-13 catalysts and their performance in 1-butene catalytic cracking[J]. J Energy Chem, 2014,23:193-200. doi: 10.1016/S2095-4956(14)60135-2

    14. [14]

      ZENG Peng-hui, JI Sheng-fu, LIANG Yun, SHEN Bao-jian, FU Li-na, ZHAO Xiao-zheng. Alkali modification of Al-ITQ-13 zeolite and its performances for catalytic cracking[J]. Petrochem Technol, 2014,43(4):405-411.  

    15. [15]

      ZENG P H, GUO X Z, ZHU X C, GUO Q X, WANG Y D, REN S Y, SHEN B J. On the synthesis and catalytic cracking properties of Al-ITQ-13 zeolites[J]. Microporous Mesoporous Mater, 2017,246:186-192. doi: 10.1016/j.micromeso.2017.03.033

    16. [16]

      SKISTAD W, TEKETEL S, BLEKEN F L, BEATO P, BORDIGA S, NILSEN M H, OLSBYE U, SVELLE S, LILLERUD K P. Methanol conversion to hydrocarbons (MTH) over H-ITQ-13(ITH) zeolite[J]. Top Catal, 2014,57:143-158. doi: 10.1007/s11244-013-0170-7

    17. [17]

      SASTRE G, PULIDO A, CASTANEDA R, CORORM A. Effect of the germanium incorporation in the synthesis of EU-1, ITQ-13, ITQ-22, and ITQ-24 zeolites[J]. J Phys Chem B, 2004,108(26):8830-8835. doi: 10.1021/jp0378438

    18. [18]

      CORMA A, REY F, VALENCIA S. A zeolite with interconnected 8-, 10-and 12-ring pores and its unique catalytic selectivity[J]. Nat Mater, 2003,2:493-497. doi: 10.1038/nmat921

    19. [19]

      JIAO Yong-dong, ZHU Bin, LIN Ming, ZHU Hua-yuan. Synthesis, characterization and catalytic light olefin aromatization performance of zeolite ITQ-13[J]. Acta Pet Sin (Pet Process Sect), 2006(Supplement):184-187.  

    20. [20]

      XU G, ZHU X, LIU S, XIE S, XU L. Synthesis of pure silica ITQ-13 zeolite using fumed silica as silica source[J]. Microporous Mesoporous Mater, 2010,129:278-284. doi: 10.1016/j.micromeso.2009.10.005

    21. [21]

      XU C, Guan GUAN J., WU S, KAN Q. Effect of silica source on the hydrothermal synthesis of ITQ-13 zeolite[J]. Acta Phys Chim Sin, 2009,25:2275-2278.  

    22. [22]

      REN X, LIU J, LI Y, YU J, XU R. Hydrothermal synthesis of an ITH-type germanosilicate zeolite in a non-concentrated gel system[J]. J Porous Mater, 2013,20:975-981. doi: 10.1007/s10934-013-9676-4

    23. [23]

      WEI Ru-chao. Synthesis, characterization of ZSM-5 zeolite and studies on its catalytic performance for the reaction of MTO[D]. Qingdao:China University of Petroleum (Huadong), 2011. 

    24. [24]

      ZHAO T S, TAKEMOTO T, YONEYAMA Y. Selective conversion of dimethyl ether to propylene and light olefins over modified H-ZSM-5[J]. Chem Lett, 2005,34(7):970-971. doi: 10.1246/cl.2005.970

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