Citation: DOU Bao-juan, ZHAO Chen-chen, ZHANG Qing, YAN Ning-na, YANG De-yu, HAO Qing-lan. Catalytic degradation of toluene over Cu-Mn-Ce-Zr/TiO₂ coupled with low temperature plasma[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(5): 598-604. shu

Catalytic degradation of toluene over Cu-Mn-Ce-Zr/TiO₂ coupled with low temperature plasma

Tianjin University of Science and Technology, Tianjin 300457, China

Corresponding author: HAO Qing-lan, haoqinglan@tust.edu.cn
Received Date: 30 November 2018
Revised Date: 28 February 2019

Fund Project: The project was supported by the China Postdoctoral Science Foundation 2017M623284The project was supported by the China Postdoctoral Science Foundation (2017M623284).

Figures(6)

A series of supported Cu_xMn_1-xCe_0.75Zr_0.25/TiO₂ (x = 1.0, 0.75, 0.5, 0.25, 0) catalysts were prepared by impregnation and characterized by XRD, H₂-TPR, O₂-TPD and XPS; the performance of Cu_xMn_1-xCe_0.75Zr_0.25/TiO₂ catalysts in the degradation of toluene coupled with low temperature plasma under high space velocity was then investigated. The results indicate that the composite catalysts with single Cu or Mn as the main active component exhibit higher activity than those with double Cu and Mn components; the addition of second component may weaken the interaction between Cu and Ce, leading to a decrease in the content of lattice oxygen and the reducibility at low temperature. The CuCe_0.75Zr_0.25/TiO₂ catalyst exhibits superior performance for toluene oxidation in the initial reaction stage, owing to its high content of lattice oxygen and oxygen vacancies. With the increase of the specific energy density (SED) of low temperature plasma, the concentration of O₃ increases and the MnCe_0.75Zr_0.25/TiO₂ catalyst then displays higher activity in toluene degradation than CuCe_0.75Zr_0.25/TiO₂, because of the prominent enhancement of synergistic effect between plasma and catalyst over the former MnCe_0.75Zr_0.25/TiO₂ catalyst.
- low temperature plasma,
- Cu-Mn bimetal catalyst,
- synergistic catalysis,
- toluene degradation
1. [1]
  CHEN Ying, YE Dai-qi, LIU Xiu-zhen, WU Jun-liang, HUANG Bi-chun, ZHENG Ya-nan. Source tracing and characteristics of industrial VOCs emissions in China[J]. China Environ Sci, 2012,32(1):48-55. doi: 10.3969/j.issn.1000-6923.2012.01.008
2. [2]
  KARUPPIAH J, SIVACHANDIRAN L, KARVEMBU R, SUBRAHMANYAM C. Catalytic nonthermal plasma reactor for the abatement of low concentrations of isopropanol[J]. Chem Eng J, 2010,165(1):194-199. doi: 10.1016/j.cej.2010.09.017
3. [3]
  HU Hui, LI Sheng-li, YANG Chang-he, LI Jin. The progress on study of treatment of volatile organic compounds by discharge plasma[J]. High Volt Eng, 2002,28(3):43-47. doi: 10.3969/j.issn.1003-6520.2002.03.018
4. [4]
  DOU B J, LIU D L, ZHANG Q, ZHAO R Z, HAO Q L, BIN F, CAO J G. Enhanced removal of toluene by dielectric barrier discharge coupling with Cu-Ce-Zr supported ZSM-5/TiO₂/Al₂O₃[J]. Catal Commun, 2017,92:15-18. doi: 10.1016/j.catcom.2016.12.024
5. [5]
  FAN H Y, SHI C, LI X S, ZHAO D Z, XU Y, ZHU A M. High-efficiency plasma catalytic removal of dilute benzene from air[J]. J Phys D:Appl Phys, 2009,42(22):225105-225109. doi: 10.1088/0022-3727/42/22/225105
6. [6]
  ZHANG H B, LI K, SUN T H, JIA J P, LOU Z Y, FENG L L. Removal of styrene using dielectric barrier discharge plasmas combined with sol-gel prepared TiO₂ coated λ-Al₂O₃[J]. Chem Eng J, 2014,241:92-102. doi: 10.1016/j.cej.2013.12.019
7. [7]
  DANG Xiao-qing, ZHOU Yu-xiang, HUANG Jia-yu, ZHU Hai-ying, QIN Cai-hong. Plasma-catalytic decomposition of adsorbed benzene withgas circulation[J]. Chin J Environ Eng, 2015,9(3):1355-1360.
8. [8]
  GUAN Xiu-juan, YE Dai-qi, HUANG Hai-bao. Study on toluene destruction in air stream by dielectric barrier discharge combined with catalytic system[J]. Chin J Environ Eng, 2008,2(7):977-982.
9. [9]
  HASAN M A, ZAKI M I, PASUPULETY L, KUMARI K. Promotion of the hydrogen peroxide decomposition activity of manganese oxide catalysts[J]. Appl Catal A:Gen, 1999,181(1):171-179. doi: 10.1016/S0926-860X(98)00430-X
10. [10]
  ZHANG Xiao-yu, LIU Zhi-min, WEI Zhen-ling, DU Xiao-chun, GONG Mao-chu. Preparation of high performance methane combustion catalyst and its application to natural gas catalytic combustion Fan-Boiler[J]. J Catal, 2006,27(9):823-826. doi: 10.3321/j.issn:0253-9837.2006.09.015
11. [11]
  LI W B, CHU W B, ZHUANG M, HUA J. Catalytic oxidation of toluene on Mn-containing mixed oxides prepared in reverse microemulsions[J]. Catal Today, 2004,93(3):205-209.
12. [12]
  LI Hong-fang, LIU Xue-song, GUO Cun-xia, LIU Tong, LUO Meng-fei, LU Ji-qing. The influence of the carrier on the catalytic oxidation of formaldehyde on the loaded gold catalyst[J]. J Catal, 2009,30(10):1001-1006. doi: 10.3321/j.issn:0253-9837.2009.10.007
13. [13]
  OKUMURA K, KOBAYASHI T, TANAKA H, NIWA M. Toluene combustion over palladium supported on various metal oxide supports[J]. Appl Catal B:Environ, 2003,44(4):325-331. doi: 10.1016/S0926-3373(03)00101-2
14. [14]
  YAO Shui-liang, MAO Lin-ai, ZHANG Xia, TANG Xiu-juan. Mechanism analysis of benzene catalytic oxidation using plasma reactor with micro-level noble catalysts[J]. High Volt Eng, 2017,43(12):3973-3980.
15. [15]
  SELLICK D R, ARANDA A, GARCÍA T, LÓPEZ J M, SOLAONA B, MASTRAL A M, MORGAN D J, CARLEY A F, TAYLOR S H. Influence of the preparation method on the activity of ceria zirconia mixed oxides for naphthalene total oxidation[J]. Appl Catal B:Environ, 2013,132/133(1):98-106.
16. [16]
  ZHAO C C, HAO Q L, ZHANG Q, YAN N N, LIU J R, DOU B J, BIN F. Catalytic self-sustained combustion of toluene and reaction pathway over Cu_xMn_1-xCe_0.75Zr_0.25/TiO₂ catalysts[J]. Appl Catal A:Gen, 2019,569:66-74. doi: 10.1016/j.apcata.2018.10.034
17. [17]
  GUO X L, LI J, ZHOU R X. Catalytic performance of manganese doped CuO-CeO₂ catalysts for selective oxidation of CO in hydrogen-rich gas[J]. Fuel, 2016,163:56-64. doi: 10.1016/j.fuel.2015.09.043
18. [18]
  SANTOS V P, PEREIRA M F R, ÓRFÄO J J M, FIGUEIREDO J L. The role of lattice oxygen on the activity of manganese oxides towards the oxidation of volatile organic compounds[J]. Appl Catal B:Environ, 2010,99(1/2):353-363.
19. [19]
  LI L M, JING F L, YAN J L, JING J, CHU W. Highly effective self-propagating synthesis of CeO₂-doped MnO₂ catalysts for toluene catalytic combustion[J]. Catal Today, 2017,297:167-172. doi: 10.1016/j.cattod.2017.04.053
20. [20]
  DENG Q F, REN T Z, BAO A, LIU Y P, YUAN Z Y. Mesoporous Ce_x Zr_1-xO₂ solid solutions supported CuO nanocatalysts for toluene total oxidation[J]. J Ind Eng Chem, 2014,20(5):3303-3312. doi: 10.1016/j.jiec.2013.12.012
21. [21]
  TANG W X, WU X F, LIU G, LI S D, LI D Y, LI W H, CHEN Y F. Preparation of hierarchical layer-stacking Mn-Ce composite oxide for catalytic total oxidation of VOCs[J]. J Rare Earth, 2015,33(1):62-69. doi: 10.1016/S1002-0721(14)60384-7
22. [22]
  DOU B J, LV G, WANG C, HAO Q L, HUI K S. Cerium doped copper/ZSM-5 catalysts used for the selective catalytic reduction of nitrogen oxide with ammonia[J]. Chem Eng J, 2015,270:549-556. doi: 10.1016/j.cej.2015.02.004
23. [23]
  DOU B J, BIN F, WANG C, JIA Q Z, LI J. Discharge characteristics and abatement of volatile organic compounds using plasma reactor packed with ceramic Raschig rings[J]. J Electrost, 2013,71(5):939-944. doi: 10.1016/j.elstat.2013.08.003
1. [1]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
2. [2]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
3. [3]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
4. [4]
  Zhengyu Zhou , Huiqin Yao , Youlin Wu , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Synergistic Effect of Cu-Graphdiyne/Transition Bimetallic Tungstate Formed S-Scheme Heterojunction for Enhanced Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2024, 40(10): 2312010-. doi: 10.3866/PKU.WHXB202312010
5. [5]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
6. [6]
  Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
7. [7]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
8. [8]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . 软模板法诱导Cu/Al₂O₃深孔道结构促进等离子催化CO₂加氢制二甲醚. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-. doi: 10.1016/j.actphy.2025.100054
9. [9]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
10. [10]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
11. [11]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
12. [12]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
13. [13]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
14. [14]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
15. [15]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
16. [16]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
17. [17]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
18. [18]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Cu基和Pt基甲醇水蒸气重整制氢催化剂研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-. doi: 10.1016/j.actphy.2025.100049
19. [19]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
20. [20]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(854)
HTML views(144)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Catalytic degradation of toluene over Cu-Mn-Ce-Zr/TiO2 coupled with low temperature plasma

Metrics

通讯作者: 陈斌, bchen63@163.com

Catalytic degradation of toluene over Cu-Mn-Ce-Zr/TiO₂ coupled with low temperature plasma