Citation: Lai Jin TIAN, Zhi Cai SHANG, Qing Sen YU, Wen Na ZHAO, Bing ZHANG. Synthesis and Transesterification of the Complexes of Methyl 2-Methyl-3-trichlorostannylpropoinate with Benzylmethylsulfoxide[J]. Chinese Chemical Letters, ;2002, 13(12): 1168-1169. shu

Synthesis and Transesterification of the Complexes of Methyl 2-Methyl-3-trichlorostannylpropoinate with Benzylmethylsulfoxide

Department of Chemistry, Zhejiang University, Hangzhou 310027

Received Date: 12 March 2002

The title complex, Cl₃SnCH₂CH(CH₃)CO₂CH₃·L (1), was synthesized by the reaction of methyl 2-methyl-3-trichlorostannylpropionate with benzylmethylsulfoxide (L) in solid state at room temperature and readily underwent transesterification into the corresponding analogues Cl₃SnCH₂CH(CH₃)CO₂R·L when reacted with an alcohol ROH. The structural features of these compounds were described, and the possible mechanism of transesterification was suggested.
- 2-Methyl-3-trichlorostannylpropionate complexes,
- solid state reaction,
- crystal structure,
- transesterification
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