Citation: Fang Wenting, Hu Hualei, Hu Danxin, Liu Xincai, Zhang Jian, Zhang Yajie, Wang Lei. Ionothermal Synthesis of MAPO Molecular Sieves at High Temperature[J]. Chemistry, ;2017, 80(7): 692-695. shu

Ionothermal Synthesis of MAPO Molecular Sieves at High Temperature

Fang Wenting ^1,2 ,
Hu Hualei ¹ ,
Hu Danxin ¹ ,
Liu Xincai ² ,
Zhang Jian ¹ ,
Zhang Yajie ^1,, ,
Wang Lei ^1,,

1.
Ningbo Institute of Materials Technology & Engineering, Chinese Academy of Sciences, Ningbo 315201
2.
Faculty of Material Science and Chemical Engineering, Ningbo University, Ningbo 315211

Corresponding author: Zhang Yajie, zhangyj@nimte.ac.cn Wang Lei, wanglei@nimte.ac.cn
Received Date: 24 January 2017
Accepted Date: 2 May 2017

Figures(5)

A series of MAPO molecular sieves has been synthesized ionothermally in[BMIM]Br ionic liquid at 280℃ using H₃PO₄, Al[OCH(CH₃)₂]₃, n-dipropylamine, magnesium acetate and HF as raw materilas. The structure transformation process (MAPO-5 to MAPO-11, finally MAPO-25) obeys the Ostwald's rule of successive crystallization, along with the increase in framework density and the change in morphology and state of the templates.
- Ionothermal synthesis,
- MAPO,
- Molecular sieves,
- Crystal transformation
1. [1]
  M E Davis. Nature, 2002, 417(6891):813~821.
2. [2]
  Sujandi, S E Park, D S Han et al. Chem. Commun., 2006, (39):4131~4133.
3. [3]
  J Yu, R Xu. Chem. Soc. Rev., 2006, 35(7):593~604.
4. [4]
  R Murugavel, A Choudhury, M G Walawalkar et al. Chem. Rev., 2008, 108:3549~3655.
5. [5]
  E R Cooper, C D Andrews, P S Wheatley et al. Nature, 2004, 430:1012~1016.
6. [6]
  E R Parnham, R E Morris. Acc. Chem. Res., 2007, 40(10):1005~1013.
7. [7]
  R E Morris. Chem. Commun., 2009, (21):2990~2998.
8. [8]
  L Wang, Y P Xu, B C Wang et al. Chem. Eur. J., 2008, 14(34):10551~10555.
9. [9]
  L Wang, Y P Xu, Ying Wei et al. J. Am. Chem. Soc., 2006, 128(23):7432~7433.
10. [10]
  Ying Wei, Z J Tian, H Gies et al. Angew. Chem. Int. Ed., 2010, 122:1~5.
11. [11]
  Y P Xu, Z J Tian, L Wang et al. Angew. Chem. Int. Ed., 2006, 45:3965~3970.
12. [12]
  R D Rogers, K R Seddon. Science, 2003, 302:792~793.
13. [13]
  K R Seddon. J. Chem. Technol. Biotechnol. 1997, 68:351~356.
14. [14]
  T Welton. Chem. Rev., 1999, 99:2071~2083.
15. [15]
16. [16]
  R Y Pei, Y Wei, K D Li et al. Dalton Transac., 2010, 39:1441~1443.
17. [17]
  R S Xu, X C Shi, W P Zhang et al. Phys. Chem. Chem. Phys., 2010, 12:2443~2449.
18. [18]
  S T Wilson, B M Lok, C A Messina et al. J. Am. Chem. Soc., 1982, 104(4):1146~1147.
19. [19]
  J Yu, R Xu. Chem. Soc. Rev., 2006, 35(7):593~604.
20. [20]
  B M Lok, C A Messina, R L Patton et al. J. Am. Chem. Soc., 1984, 106(20):6092~6093.
21. [21]
  M Hartmann, L Kevan. Chem. Rev., 1999, 99(3):635~663.
22. [22]
  D Arias, I Campos, D Escalante et al. J. Mol. Catal. A, 1997, 122(2-3):175~186.
23. [23]
  E R Parnham, R E Morris. J. Am. Chem. Soc., 2006, 128(7):2204~2205.
24. [24]
  Y P Xu, Z J Tian, Z S Xu et al. Chin. J. Catal., 2005, 26:446~448.
25. [25]
  S Gopalakrishnan, K R Viswanathan, S V Priya et al. Calal. Commun., 2008, 10:23~28.
26. [26]
  M S Machado, J P Pariente, E Sastre et al. J. Catal., 2002, 205:299~308.
27. [27]
  J W Richardson, J J Pluth. Acta Crystallogr., 1988, B44, 367~373.
28. [28]
  C Baerlocher, W M Meire, D H Olson et al. Atlas of Zeolite Framework Types. 5th ed.; Elsevier:Amsterdam, 2001.
29. [29]
  R M Barrer. Hydrothermal Chemistry of Zeolites. Academic Press:London, 1982.
30. [30]
  J W Richardson, J Smith, J J Pluth. J. Phys. Chem., 1990, 94:3365~3367.
31. [31]
  L Marchese, A Frache, E Giannotti et al. Micropor. Mesopor. Mater., 1999, 30:145~153.
32. [32]
  R Fernandez, M V Giotto, H O Pastore et al. Micropor. Mesopor. Mater., 2002, 53:135~144.
33. [33]
  P S Singh, R Bandyopadhyay, B S Rao et al. J. Mol. Catal. A, 1995, 104(1):103~110.
1. [1]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 2406012-0. doi: 10.3866/PKU.WHXB202406012
2. [2]
  Qinhui Guan , Yuhao Guo , Na Li , Jing Li , Tingjiang Yan . Molecular sieve-mediated indium oxide catalysts for enhancing photocatalytic CO₂ hydrogenation. Acta Physico-Chimica Sinica, 2025, 41(11): 100133-0. doi: 10.1016/j.actphy.2025.100133
3. [3]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . High-Stable Aqueous Zinc Metal Anodes Enabled by an Oriented ZnQ Zeolite Protective Layer with Facile Ion Migration Kinetics. Acta Physico-Chimica Sinica, 2025, 41(1): 100003-0. doi: 10.3866/PKU.WHXB202309003
4. [4]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
5. [5]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
6. [6]
  Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224
7. [7]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
8. [8]
  Yajie Li , Bin Chen , Yiping Wang , Hui Xing , Wei Zhao , Geng Zhang , Siqi Shi . Inhibiting Dendrite Growth by Customizing Electrolyte or Separator to Achieve Anisotropic Lithium-Ion Transport: A Phase-Field Study. Acta Physico-Chimica Sinica, 2024, 40(3): 2305053-0. doi: 10.3866/PKU.WHXB202305053
9. [9]
  Weijie Yang , Mansheng Chen , Chen Xu , Fujian Xu . Hydroxyl-Rich Polycations: Innovative Materials Empowering Life and Health. University Chemistry, 2025, 40(9): 332-343. doi: 10.12461/PKU.DXHX202410072
10. [10]
  Wenhui Li , Yakun Tang , Yusheng Zhou , Yue Zhang , Wenhai Zhang , Qingtao Ma , Lang Liu , Sen Dong , Yuliang Cao . Enhanced sodium storage performance of asphalt-derived hard carbon through intramolecular oxidation for high-performance sodium-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(10): 100119-0. doi: 10.1016/j.actphy.2025.100119
11. [11]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
12. [12]
  Yang Lv , Yingping Jia , Yanhua Li , Hexiang Zhong , Xinping Wang . Integrating the Ideological Elements with the “Chemical Reaction Heat” Teaching. University Chemistry, 2024, 39(11): 44-51. doi: 10.12461/PKU.DXHX202402059
13. [13]
  Yang ZHOU , Lili YAN , Wenjuan ZHANG , Pinhua RAO . Thermal regeneration of biogas residue biochar and the ammonia nitrogen adsorption properties. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1574-1588. doi: 10.11862/CJIC.20250032
14. [14]
  Kexin Yan , Zhaoqi Ye , Lingtao Kong , He Li , Xue Yang , Yahong Zhang , Hongbin Zhang , Yi Tang . Seed-Induced Synthesis of Disc-Cluster Zeolite L Mesocrystals with Ultrashort c-Axis: Morphology Control, Decoupled Mechanism, and Enhanced Adsorption. Acta Physico-Chimica Sinica, 2024, 40(9): 2308019-0. doi: 10.3866/PKU.WHXB202308019
15. [15]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
16. [16]
  Yuting Bai , Cenqi Yan , Zhen Li , Jiaqiang Qin , Pei Cheng . Preparation of High-Strength Polyimide Porous Films with Thermally Closed Pore Property by In Situ Pore Formation Method. Acta Physico-Chimica Sinica, 2024, 40(9): 2306010-0. doi: 10.3866/PKU.WHXB202306010
17. [17]
  Jiaxing Cai , Wendi Xu , Haoqiang Chi , Qian Liu , Wa Gao , Li Shi , Jingxiang Low , Zhigang Zou , Yong Zhou . Highly Efficient InOOH/ZnIn₂S₄ Hollow Sphere S-Scheme Heterojunction with 0D/2D Interface for Enhancing Photocatalytic CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(11): 2407002-0. doi: 10.3866/PKU.WHXB202407002
18. [18]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 2404023-0. doi: 10.3866/PKU.WHXB202404023
19. [19]
  Zhiming Feng , Lili Wu , Chengming Wang . Doubly Oxidized Carbene. University Chemistry, 2025, 40(9): 326-331. doi: 10.12461/PKU.DXHX202411008
20. [20]
  Yongqing Xu , Yuyao Yang , Mengna Wu , Xiaoxiao Yang , Xuan Bie , Shiyu Zhang , Qinghai Li , Yanguo Zhang , Chenwei Zhang , Robert E. Przekop , Bogna Sztorch , Dariusz Brzakalski , Hui Zhou . Review on Using Molybdenum Carbides for the Thermal Catalysis of CO₂ Hydrogenation to Produce High-Value-Added Chemicals and Fuels. Acta Physico-Chimica Sinica, 2024, 40(4): 2304003-0. doi: 10.3866/PKU.WHXB202304003

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(1176)
HTML views(263)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142