Citation: Wang Lejia, Xiao Ning, Sun Qing, Shen Liangjun, Li Xiaofang, Xiao Xunwen. Preparation, Crystal Structure, and Properties of a New Semiconducting Material Bearing Tetrathiafulvalene-Pyridine[J]. Chemistry, ;2019, 82(7): 606-611. shu

Preparation, Crystal Structure, and Properties of a New Semiconducting Material Bearing Tetrathiafulvalene-Pyridine

Wang Lejia ^1,, ,
Xiao Ning ² ,
Sun Qing ¹ ,
Shen Liangjun ¹ ,
Li Xiaofang ³ ,
Xiao Xunwen ^1,,

1.
College of Material Science and Chemical Engineering, Ningbo University of Technology, Ningbo 315211
2.
College of Material Science and Chemical Engineering, Ningbo University, Ningbo 315211
3.
College of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201

Corresponding author: Wang Lejia, wanglejia@nbut.edu.cn Xiao Xunwen, xunwenxiao@nbut.edu.cn
Received Date: 18 March 2019
Accepted Date: 27 March 2019

Figures(6)

A novel Cu(I) coordination complex[Cu^I(L1)₄](ClO₄)₂, (L1=4-ethylenedithiotetr-athiafulvalenylpyridine) was synthesized by coordination-driven self-assemble method through a solution process and characterized with micro and bulk crystals forms. The purity of the micro crystals was confirmed by the elemental analysis and XRD results. In the bulk crystal form, the complex[Cu^I(L1)₄](ClO₄)₂ is mononuclear and further assembles into a 3D supramolecular network through S…S noncovalent interactions. Moreover, the supramolecular chain[Cu^I(L1)₄]_∞ forms an one-dimensional microporous framework along c axis (8.05×7.67Å). Due to the construction of an one-dimensional uniform array of the TTF^+1/4 along the c axis, a semiconducting behavior is observed in complex[Cu^I(L1)₄](ClO₄)₂ with σ_rt=9.1×10^-2 S·cm^-1 and an activation energy of E_a=50meV.
- Charge-transfer,
- TTF derivative,
- Coordination complexes,
- Microstructures,
- Self-assembly
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沈阳化工大学材料科学与工程学院沈阳 110142