Citation: WANG Qing, ZHANG Hong-xi, CHI Ming-shu, CUI Da, XU Xiang-cheng. Effect of mineral matter on product evolution during pyrolysis of Huadian oil shale[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(3): 328-334. shu

Effect of mineral matter on product evolution during pyrolysis of Huadian oil shale

Engineering Research Center of Oil Shale Comprehensive Utilization, Ministry of Education, Northeast Dianli University, Jilin 132012, China

Corresponding author: WANG Qing, rlx888@126.com
Received Date: 12 August 2015
Revised Date: 16 November 2015

Fund Project: The project was supported by the National Natural Science Foundation of China 51276034

Figures(4)

The effect of mineral matter on pyrolysis and product evolution of oil shale was studied by GC and FT-IR. Hudian oil shale was treated by sequential washing with HCl and HF/HCl. The results show that carbonate has catalytic effect on conversion of organic carbon and hydrogen from Kerogen to shale oil, which is inhibited by silicate. The H/C atomic ratio in shale oil increases in both carbonate-free and silicate-free oil shale. Carbonate enhances gas yield and inhibits oil yield, while silicate is just opposite. The contents of CO₂ and H₂ decrease but CO increases in both carbonate-free and silicate-free oil shale. Carbonate can inhibit generation of hydrocarbon in gas product while silicate has catalytic effect on it. All the carbonate and silicate can increase the length and degree of branching aliphatic side chains in shale oil and improve aromatization of the solid product from shale.
- demineralization,
- oil shale,
- pyrolysis,
- GC,
- FT-IR
1. [1]
  QIAN Jia-lin, WANG Jian-qiu, LI Shu-yuan. World oil shale utilization and its future[J]. J Jilin Univ (Earth Sci Ed), 2006,36(6):878-887.
2. [2]
  SAXBY J D. Isolation of kerogen in sediments by chemical methods[J]. Chem Geol, 1970,6:173-184. doi: 10.1016/0009-2541(70)90017-3
3. [3]
  YÜRÜM Y, DROR Y, LEVY M. Effect of acid dissolution on the mineral matrix and organic matter of Zefa Efe oil shale[J]. Fuel Process Technol, 1985,11(1):71-86. doi: 10.1016/0378-3820(85)90017-7
4. [4]
  LU S T, RUTH E, KAPLAN I R. Pyrolysis of kerogens in the absence and presence of montmorillonite-I. The generation, degradation and isomerization of steranes and triterpanes at 200 and 300℃[J]. Org Geochem, 1989,14(5):491-499. doi: 10.1016/0146-6380(89)90029-6
5. [5]
  LU S T, KAPLAN I R. Pyrolysis of kerogens in the absence and presence of montmorillonite-II. Aromatic hydrocarbons generated at 200 and 300℃[J]. Org Geoche, 1989,14(5):501-510. doi: 10.1016/0146-6380(89)90030-2
6. [6]
  KARABAKAN A, YÜRÜM Y. Effect of the mineral matrix in the reactions of oil shales: 1. Pyrolysis reactions of Turkish Göynük and US Green River oil shales[J]. Fuel, 1998,77(12):1303-1309. doi: 10.1016/S0016-2361(98)00045-3
7. [7]
  BORREGO A G, PRADO J G, FUENTE E. Pyrolytic behaviour of Spanish oil shales and their kerogens[J]. J Anal Appl Pyrolysis, 2000,56(1):1-21. doi: 10.1016/S0165-2370(99)00092-3
8. [8]
  BALLICE L. Effect of demineralization on yield and composition of the volatile products evolved from temperature-programmed pyrolysis of Beypazari (Turkey) oil shale[J]. Fuel Process Technol, 2005,86(6):673-690. doi: 10.1016/j.fuproc.2004.07.003
9. [9]
  ABOULKAS A, EL HARFI K. Study of the kinetics and mechanisms of thermal decomposition of Moroccan Tarfaya oil shale and its kerogen[J]. Oil Shale, 2008,25(4):426-443. doi: 10.3176/oil.2008.4.04
10. [10]
  ABOULKAS A, EL HARFI K. Effects of acid treatments on Moroccan Tarfaya oil shale and pyrolysis of oil shale and their kerogen[J]. J Fuel Chem Technol, 2009,37(6):659-667. doi: 10.1016/S1872-5813(10)60013-8
11. [11]
  AL-HARAHSHEH A, AL-HARAHSHEH M, AL-OTOOM A. Effect of demineralization of El-lajjun Jordanian oil shale on oil yield[J]. Fuel Process Technol, 2009,90(6):818-824. doi: 10.1016/j.fuproc.2009.03.005
12. [12]
  AL-HARAHSHEH M, AL-AYED O, ROBINSON J. Effect of demineralization and heating rate on the pyrolysis kinetics of Jordanian oil shales[J]. Fuel Process Technol, 2011,92(9):1805-1811. doi: 10.1016/j.fuproc.2011.04.037
13. [13]
  SERT M, BALLICE L, YVKSEL M. Effect of mineral matter on product yield and composition at isothermal pyrolysis of Turkish oilshales[J]. Oil Shale, 2009,26(4):463-474. doi: 10.3176/oil.2009.4.03
14. [14]
  YAN J W, JIANG X M, HAN X X. A TG-FTIR investigation to the catalytic effect of mineral matrix in oil shale on the pyrolysis and combustion of kerogen[J]. Fuel, 2013,104:307-317. doi: 10.1016/j.fuel.2012.10.024
15. [15]
  GUO H F, LIN J D, YANG Y D, LIU Y Y. Effect of minerals on the self-heating retorting of oil shale: Self-heating effect and shale-oil production[J]. Fuel, 2014,118:186-193. doi: 10.1016/j.fuel.2013.10.058
16. [16]
  CHAO F, YAN J W, HUANG Y R, HAN X X. XRD and TG-FTIR study of the effect of mineral matrix on the pyrolysis and combustion of organic matter in shale char[J]. Fuel, 2015,139:502-510. doi: 10.1016/j.fuel.2014.09.021
17. [17]
  GAO Xian-zhi, ZHANG Wan-xuan, ZHANG Hou-fu. Research on the Influence of mineral pyrolysis[J]. Pet Geol Exp, 1990,12(2):201-205.
18. [18]
  LIU Xiao-yan. The impact of organic evolution of clay minerals[J]. Nat Gas Geosci, 1995,6(3):23-26.
19. [19]
  LIU Luo-fu, LI Shu-yuan. Progress of hydrocarbon source rocks in the catalytic mechanism[J]. Geol Rev, 2000,46(5):491-498.
20. [20]
  FANG xuan, LEI Huai-yan. Research on the influence of organisms-organic pyrolysis by Clay minerals[J]. Nat Gas Geosci, 1993,4(6):80-85.
21. [21]
  ZHANG Zhi-huan, GAO Xian-zhi. The influence and mechanism of clay minerals on kerogen pyrolysis products[J]. J China Univ Pet (Nat Sci Ed), 1995,19(5):11-17.
22. [22]
  WANG Q, BAI J R, SUN B Z. Comprehensive utilization strategy of Huadian oil shale[J]. Oil shale, 2005,22(3):305-316.
23. [23]
  AL-HARAHSHEH M, SHAWABKEH R, AL-HARAHSHEH A. Surface modification and characterization of Jordanian kaolinite: Application for lead removal from aqueous solutions[J]. Appl Surf Sci, 2009,255(18):8098-8103. doi: 10.1016/j.apsusc.2009.05.024
24. [24]
  WU Ping-xiao. Reserch to montmorillonite activation and its microstructure[D]. Guangzhou: Guangzhou Institute of Geochemistry, Academia Sinica, 2001.
25. [25]
  SCACCIA S. TG-FTIR and kinetics of devolatilization of Sulcis coal[J]. J Anal Appl Pyrolysis, 2013,104(10):95-102.
26. [26]
  HOU Xiang-lin. China Sshale Oil Industry[M]. Beijing: Petroleum Industry Press, 1984.
27. [27]
  LEI Huai-yan, SHI Yu-xin, GUAN Ping. Study of catalysis on transitional gas by clay minerals[J]. Sci China, 1997,27(1):39-44.
28. [28]
  MRÁZIKOVÁ J, SINDLER S, VEVERKA L. Evolution of organic oxygen bonds during pyrolysis of coal[J]. Fuel, 1986,65(3):342-345. doi: 10.1016/0016-2361(86)90293-0
29. [29]
  JOSEPH J T, FORRAI T R. Effect of exchangeable cations on liquefaction of low rank coals[J]. Fuel, 1992,71(1):75-80. doi: 10.1016/0016-2361(92)90195-T
30. [30]
  LIANG Hu-zhen, WANG Chuan-ge, ZENG Fan-gui. Effect of demineralization on lignite structure from Yinmin coalfield by FT-IR investigation[J]. J Fuel Chem Technol, 2014,42(2):129-137.
31. [31]
  IBARRA J V, MOLINER R, BONET A J. FT-IR investigation on char formation during the early stages of coal pyrolysis[J]. Fuel, 1994,73(6):918-924. doi: 10.1016/0016-2361(94)90287-9
32. [32]
  PANDOLFO A G, JOHNS R B, DYRKACZ G R. Separation and preliminary characterization of high-purity maceral group fractions from an Australian bituminous coal[J]. Energy Fuels, 1988,2(5):657-662. doi: 10.1021/ef00011a010
33. [33]
  IBARRA J V, MUNOZ E, MOLINER R. FT-IR study of the evolution of coal structure during the coalification process[J]. Org Geochem, 1996,24(6):725-735.
34. [34]
  WANG S, TANG Y, SCHOBERT H H. FT-IR and 13C NMR investigation of coal component of late Permian coals from southern China[J]. Energy Fuels, 2011,25(12):5672-5677. doi: 10.1021/ef201196v
35. [35]
  LI Fan, ZHANG Yong-fa. Effect of the mineral matter on the pyrolysis reaction of coal macerals[J]. J Fuel Chem Technol, 1992,30(3):300-306.
1. [1]
  Supin Zhao , Jing Xie . Understanding the Vibrational Stark Effect of Water Molecules Using Quantum Chemistry Calculations. University Chemistry, 2025, 40(3): 178-185. doi: 10.12461/PKU.DXHX202406024
2. [2]
  Yang Wang , Yunpeng Fu , Xiaoji Liu , Guotao Zhang , Guobin Li , Wanqiang Liu , Jinglun Wang . Structural Analysis of Nitrile Solutions Based on Infrared Spectroscopy Probes. University Chemistry, 2025, 40(4): 367-374. doi: 10.12461/PKU.DXHX202406113
3. [3]
  Qiuting Zhang , Fan Wu , Jin Liu , Zian Lin . Chromatographic Stationary Phase and Chiral Separation Using Frame Materials. University Chemistry, 2025, 40(4): 291-298. doi: 10.12461/PKU.DXHX202405174
4. [4]
  Houjin Li , Lin Wu , Xingwen Sun , Yuan Zheng , Zhanxiang Liu , Shuanglian Cai , Ying Xiong , Guangao Yu , Qingwen Liu , Jie Han , Xin Du , Chengshan Yuan , Qihan Zhang , Jianrong Zhang , Shuyong Zhang . Basic Operations and Specification Suggestions for Organic Chemical Chromatography Experiments. University Chemistry, 2025, 40(5): 93-105. doi: 10.12461/PKU.DXHX202408100
5. [5]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
6. [6]
  Jingming Li , Bowen Ding , Nan Li , Nurgul . Application of Comparative Teaching Method in Experimental Project Design of Instrumental Analysis Course: A Case Study in Chromatography Experiment Teaching. University Chemistry, 2024, 39(8): 263-269. doi: 10.3866/PKU.DXHX202312078
7. [7]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
8. [8]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
9. [9]
  Fan Wu , Wenchang Tian , Jin Liu , Qiuting Zhang , YanHui Zhong , Zian Lin . Core-Shell Structured Covalent Organic Framework-Coated Silica Microspheres as Mixed-Mode Stationary Phase for High Performance Liquid Chromatography. University Chemistry, 2024, 39(11): 319-326. doi: 10.12461/PKU.DXHX202403031
10. [10]
  Zhongyan Cao , Youzhi Xu , Menghua Li , Xiao Xiao , Xianqiang Kong , Deyun Qian . Electrochemically Driven Denitrative Borylation and Fluorosulfonylation of Nitroarenes. University Chemistry, 2025, 40(4): 277-281. doi: 10.12461/PKU.DXHX202407017
11. [11]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
12. [12]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
13. [13]
  Yang Lv , Yingping Jia , Yanhua Li , Hexiang Zhong , Xinping Wang . Integrating the Ideological Elements with the “Chemical Reaction Heat” Teaching. University Chemistry, 2024, 39(11): 44-51. doi: 10.12461/PKU.DXHX202402059
14. [14]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
15. [15]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011
16. [16]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
17. [17]
  Yao Ma , Xin Zhao , Hongxu Chen , Wei Wei , Liang Shen . Progress and Perspective of Perovskite Thin Single Crystal Photodetectors. Acta Physico-Chimica Sinica, 2025, 41(4): 100030-. doi: 10.3866/PKU.WHXB202309045
18. [18]
  Jian Li , Yu Zhang , Rongrong Yan , Kaiyuan Sun , Xiaoqing Liu , Zishang Liang , Yinan Jiao , Hui Bu , Xin Chen , Jinjin Zhao , Jianlin Shi . 高效靶向示踪钙钛矿纳米系统光电增效抗肿瘤. Acta Physico-Chimica Sinica, 2025, 41(5): 100042-. doi: 10.1016/j.actphy.2024.100042
19. [19]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
20. [20]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(658)
HTML views(76)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142