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Citation: SHI Xun-wang, LI Jian-fen, Xin XIN, LI Hong-xia, LU Yao, LIU Zhao, CHEN Qun-peng. Preparation of NiO-Fe2O3/PG-γ-Al2O3 catalysts and its application in pyrolysis of biomass straw[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(12): 1434-1440. shu

Preparation of NiO-Fe2O3/PG-γ-Al2O3 catalysts and its application in pyrolysis of biomass straw

  • School of Chemical and Environmental Engineering, Wuhan Polyteclmic University, Wuhan 430023, China

  • Corresponding author: LI Jian-fen, lijfen@163.com
  • Received Date: 15 July 2017
    Revised Date: 20 October 2017

    Fund Project: The project was supported by the Public Welfare Industry (agriculture) Research special (201503135)and the Project of College Outstanding Technological Innovation in Hubei Province(T201407)the Public Welfare Industry (agriculture) Research special 201503135the Project of College Outstanding Technological Innovation in Hubei Province T201407

Figures(5)

  • The supported NiO-Fe2O3/Palygorskite and Gamma Alumina(NiO-Fe2O3/PG-γ-Al2O3) catalysts were prepared by deposition-precipitation and homogeneous-precipitation methods using PG-γ-Al2O3 as a carrier, and different approaches including EDX, XRD, SEM and N2 isothermal adsorption-desorption were used to characterize the synthetic catalysts. Meanwhile, the catalytic pyrolysis of biomass straw was conducted to test the catalytic activity, the regenerative service life and the anti-carbon capacity of NiO-Fe2O3/PG-γ-Al2O3 catalyst in a tube furnace, and to compare with the catalytic properties of single carrier catalysts. The results indicate that the prepared PG-γ-Al2O3 carriers have a high specific surface area of 134.21 m2/g and the average pore size is 39.65 nm. The active components are loaded uniformly and in a good dispersion over NiO-Fe2O3/PG-γ-Al2O3 catalyst, meanwhile, the Ni-Fe alloy and the nickel-aluminum spinel structure exist simultaneously in the catalyst. The catalytic activity testing shows that the NiO-Fe2O3/PG-γ-Al2O3 catalysts have a very high catalytic activity in pyrolysis of biomass straw. It could obviously improve the quality of the gas such as the content of H2 and CO and the calorific value. The catalytic activity, regeneration effect and anti-carbon deposition ability of NiO-Fe2O3/PG catalyst are better than that with single carrier catalyst.
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