Citation: Zhou Fang, Li Qiong, Jiang Xinyu. Removal of Pb(Ⅱ) Ions from Aqueous Solution by Thiol-Functionalized Graphene Oxide[J]. Chemistry, ;2017, 80(4): 361-366. shu

Removal of Pb(Ⅱ) Ions from Aqueous Solution by Thiol-Functionalized Graphene Oxide

School of Chemistry and Chemical Engineering, Central South University, Changsha 410083

Corresponding author: Jiang Xinyu, jiangxinyu@csu.edu.cn
Received Date: 1 September 2016
Accepted Date: 16 November 2016

Figures(8)

The graphene oxide were prepared via modified Hummers method. Thiol-functionalized graphene oxide (GO-SH) was synthesized by condensation reaction of cysteamine with graphene oxide. The synthesized materials were characterized by FT-IR, SEM and XPS. The results indicated that cysteamine has been successfully grafted on the surface of graphite oxide. And then the synthesized GO-SH was used to simulate the adsorption of Pb(Ⅱ) in aqueous solution. Under the optimized condition, GO-SH exhibited a maximum adsorption capacity for Pb(Ⅱ) of 205.25 mg/g. The adsorption isotherms and kinetics matched well with the Langmuir isotherm model and pseudo-second-order equation. The GO-SH reported in this paper has great potential application in wastewater treatment and purification.
- Graphene oxide,
- Cysteamine,
- Lead ions,
- Adsorption
1. [1]
  F N Acar, Z Eren. J. Hazard. Mater., 2006, 137(2): 909~914.
2. [2]
  M M Saeed, M Ahmed. Anal. Chim. Acta, 2004, 525(2): 289~297.
3. [3]
4. [4]
  M Suwalsky, R Castro, F Villena et al. J. Inorg. Biochem., 2008, 102(4): 842~849.
5. [5]
  D Lin, X Tian, T Li et al. Environ. Pollut., 2012, 167: 138~147.
6. [6]
  N A Kabbashi, M A Atieh, A Al-Mamun et al. J. Environ. Sci., 2009, 21: 539~544.
7. [7]
  M Valcárcel, S Cárdenas, B M Simonet. Anal. Chem., 2007, 79(13): 4788~4797.
8. [8]
  G D Vukovič, A D Marinkovič, MČolič et al. Chem. Eng. J., 2010, 157(1): 238~248.
9. [9]
  G P Rao, C Lu, F Su. Sep. Purif. Technol., 2007, 58(1): 224~231.
10. [10]
  A Gupta, S R Vidyarthi, N Sankararamakrishnan. J. Hazard. Mater., 2014, 274: 132~144.
11. [11]
  C Zhang, J Sui, J Li et al. Chem. Eng. J., 2012, 210: 45~52.
12. [12]
  S B Yang, J Hu, C L Chen et al. Environ. Sci. Technol., 2011, 45:3621~3627.
13. [13]
  X W Peng, L X Zhong, J L Ren et al. J. Agr. Food Chem., 2012, 60:3909~3916.
14. [14]
  C J Corwin, R S Summers. Environ. Sci. Technol., 2010, 44:5403~5408.
15. [15]
  T Asada, K Oikawa, K Kawata. J. Health Sci., 2004, 50(6):588~593.
16. [16]
  Y H Li, J Ding, Z Luan et al. Carbon, 2003, 42(14): 2787~2792.
17. [17]
  P M Pimentel, G González, M F A Melo et al. Sep. Purif. Technol., 2007, 56(3): 348~353.
18. [18]
  L Fan, C Luo, M Sun et al. Colloid. Surf. B, 2013, 103: 523~529.
19. [19]
  H Yan, L Yang, Z Yang et al. J. Hazard. Mater., 2012, 229: 371~380.
20. [20]
  Y Cao, X Li. Adsorption, 2014, 20(5/6): 713~727.
21. [21]
  S Kim, S S Kwon, J H Woo et al. J. Electrochem. Soc., 2016 (11): 759~759.
22. [22]
  P Nuengmatcha, R Mahachai, S Chanthai. Asian J. Chem., 2015, 27(11): 4167.
23. [23]
  M Yari, M Norouzi, A H Mahvi et al. Desalin. Water Treat., 2015: 1~16.
24. [24]
  L Fan, C Luo, X Li et al. J. Hazard. Mater., 2012, 215: 272~279.
25. [25]
  V Chandra, K S Kim. Chem. Commun., 2011, 47(13): 3942~3944.
26. [26]
  D K V Ramana, J S Yu, K Seshaiah. Chem. Eng. J., 2013, 223: 806~815.
27. [27]
  L Liu, C Li, C Bao et al. Talanta, 2012, 93:350~357.
28. [28]
  V Chandra, K S Kim. Chem. Commun., 2011, 47:3942~3944.
29. [29]
  G Liu, S Gui, H Zhou et al. Dalton Transac., 2014, 43(19): 6977~6980.
30. [30]
  M Yari, M Rajabi, O Moradi et al. J. Mol. Liq., 2015, 209: 50~57.
31. [31]
  C J Madadrang, H Y Kim, G Gao et al. ACS Appl. Mater. Interf., 2012, 4(3): 1186~1193.
32. [32]
  Q Li, J Yu, F Zhou et al. Colloid. Surf. A, 2015, 482: 306~314.
33. [33]
  M Nadeem, M Shabbir, M A Abdullah et al. Chem. Eng. J., 2009, 148(2): 365~370.
34. [34]
  J Yu, M Tong, X Sun et al. React. Funct. Polym., 2007, 67(6): 564~572.
35. [35]
  I Langmuir. J. Am. Chem. Soc., 1918, 40(9): 1361~1403.
36. [36]
  Q Zhang, Y Gao, Y A Zhai et al. Carbohyd. Polym., 2008, 73(2): 359~363.
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