Citation: WEN Xiong, ZHANG Yu-hua, LIU Cheng-chao, HONG Jing-ping, WEI Liang, CHEN Yao, LI Jin-lin. Performance of hierarchical ZSM-5 supported cobalt catalyst in the Fischer-Tropsch synthesis[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(8): 950-955. shu

Performance of hierarchical ZSM-5 supported cobalt catalyst in the Fischer-Tropsch synthesis

Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission & Ministry of Education, Wuhan 430074, China

Corresponding author: LI Jin-lin, jinlinli@aliyun.com
Received Date: 3 May 2017
Revised Date: 12 June 2017

Fund Project: The project was supported by National Natural Science Foundation of China 21203253The project was supported by National Natural Science Foundation of China (21203253, 21473259)The project was supported by National Natural Science Foundation of China 21473259

Figures(8)

Uniform ZSM-5 nanoparticles (around 180 nm) were synthesized by steam assisted crystallization method (SAC), which have a hierarchically porous structure, composed of abundant open mesopores from the stacking of ZSM-5 particles and micropores in the ZSM-5 crystallites. The hierarchical ZSM-5 supported cobalt catalyst, with a cobalt loading of 15%, was then prepared through incipient impregnation and used in Fischer-Tropsch synthesis (FTS). The hierarchical ZSM-5 support and Co-based catalyst were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and N₂ sorption. The results indicate that the hierarchical ZSM-5 supported cobalt catalyst performs excellently in FTS, since the mesoporous structure in the hierarchical ZSM-5 support can enhance the mass transfer of the reaction products and the acid sites on the microporous ZSM-5 framework can promote the hydrocracking of long chain hydrocarbon products. In comparison with the cobalt catalysts supported on bulk ZSM-5 and commercial ZSM-5, the hierarchical ZSM-5 supported cobalt catalyst exhibits much higher activity in FTS, lower selectivity to CH₄, and higher selectivity to C_5-20 hydrocarbons (68.9%).
- ZSM-5,
- steam assisted crystallization,
- hierarchical structure,
- cobalt-based catalyst,
- Fischer-Tropsch synthesis
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