Citation: Cao Cheng, Qiu Manhong, You Xingmei, Lu Beibei, Ji Xiangdong. Syntheses of Tripodal Benzoyl Thiourea Ions Receptors and Their Recognition Properties[J]. Chemistry, ;2020, 83(3): 246-252. shu

Syntheses of Tripodal Benzoyl Thiourea Ions Receptors and Their Recognition Properties

Key Laboratory of Hexi Corridor Resources Utilization of Gansu, College of Chemistry and Chemical Engineering, Hexi University, Zhangye, 734000

Corresponding author: Ji Xiangdong, jxdsn@163.com
Received Date: 30 September 2019
Accepted Date: 14 November 2019

Figures(10)

Two new tripodal receptors 1 and 2 containing benzoyl thiourea units were synthesized and characterized by conventional technical methods. Studies have shown that this type of receptor compound exhibits good UV-Vis recognition ability for F^-, Ac^- and CN^-. Since the receptor compound 1 has a strong intramolecular charge transfer effect, it exhibits naked eye recognition performance for anions. UV titration indicated that this class of compounds had better binding ability to F^- and CN^-. Nuclear magnetic titration showed that the anion formed a host-guest complex through the intermolecular hydrogen bond with the host, and the proton detonation behavior occurred at the high concentration of F^-. In addition, this class of subjects had a certain ability to selectively recognize Hg²⁺.
- Thiourea,
- Tripodal ligand,
- Ions recognition,
- Synthesis
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沈阳化工大学材料科学与工程学院沈阳 110142