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Citation: CHEN Guang-hui, LI Yu, ZHANG Chang-sen, ZHANG Rui-qin. Influence of CeO2 on the carbonaceous deposition behavior of Ni-Cu/HZSM-5 catalyst in the hydrodeoxygenation of bio-oil[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(4): 449-457. shu

Influence of CeO2 on the carbonaceous deposition behavior of Ni-Cu/HZSM-5 catalyst in the hydrodeoxygenation of bio-oil

  • College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China

  • Corresponding author: ZHANG Rui-qin, rqzhang@zzu.edu.cn
  • Received Date: 30 December 2016
    Revised Date: 4 February 2017

    Fund Project: the Henan Science and Technology Cooperation and Open Project 142106000046

Figures(7)

  • The influence of CeO2 as an additive on the carbonaceous deposition behavior of Ni-Cu/H-ZSM-5 catalyst in the hydrodeoxygenation (HDO) of bio-oil was investigated. Various techniques such as thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy were used to elucidate the content and microstructure of carbon deposited on the catalyst surface, the transformation of various forms of carbon (soft carbon, hard carbon and graphite) in HDO, and the kinetics of carbon deposition. The results indicate that the content of CeO2 added in the Ni-Cu based catalyst and the reaction temperature both have a significant influence on the carbon deposition behavior and the resistance against coking for HDO of bio-oil; for HDO over the Ni-Cu/HZSM-5 catalyst at 270℃, adding 15% CeO2 gives the Ni-Cu catalyst highest resistance against the carbon deposition.
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