Citation: YUAN Dan-dan, SONG Hua-lin, YOU Man-yu, SONG Hua. Synthesis of P/W-coupled polyionic liquids for oxidative desulfurization of model oil[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(7): 876-881. shu

Synthesis of P/W-coupled polyionic liquids for oxidative desulfurization of model oil

YUAN Dan-dan ^1,2 ,
SONG Hua-lin ³ ,
YOU Man-yu ¹ ,
SONG Hua ^1,2,*,,

1.
College of Chemistry & Chemical Engineering, Northeast Petroleum University, Daqing 163318, China
2.
Provincial Key Laboratory of Oil & Gas Chemical Technology, Northeast Petroleum University, Daqing 163318, China
3.
Department of Image School, Mudanjiang Medical University, Mudanjiang 157011, China

Corresponding author: SONG Hua, songhua2004@sina.com
Received Date: 26 February 2016
Revised Date: 28 April 2016

Fund Project: Foster Fund Projects of Northeast Petroleum University NEPUPY-1-09Guiding Science and Technology Project of Daqing szdfy-2015-01The project was supported by National Natural Science Foundation of China 21276048Project of Education Department of Heilongjiang Province 12541080

Figures(9)

A novel PW-coupled polyionic liquid (1-n-butyl-3-vinylimidazolium phosphotungstate) (PBVImPW) was successfully synthesized and characterized by FT-IR, XRD, TG, ICP and CHN analysis. The prepared catalyst was applied in oxidative desulfurization processes of the model oil in the presence of H₂O₂. Several parameters including temperature, time, the amount of hydrogen peroxide and catalyst were investigated. PBVImPW is proved to be a highly efficient catalyst, and 99.4% benzothiophene conversion is achieved at reaction temperature of 50 ℃, n(H₂O₂)/n(S) ratio of 8, n(PBVImPW (P))/n(BT) ratio of 0.4 and reaction time of 150 min. There is not a significant decrease in the activity of the catalyst after being recycled four times.
- polyionic liquids,
- phosphotungstic acid (HPW),
- oxidative desulfurization (ODS)
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