Citation: Jing Mei YIN, Ming GUO, Rui WANG, Guang Yun ZHOU, Da Bin GAO, Xiang Sheng WANG, Xin Wen GUO, Jian Qin ZHUANG. Cobalt-catalyzed Photochemical Methoxycarbonylation of Olefins with Carbon Dioxide under Ambient Conditions[J]. Chinese Chemical Letters, ;2000, 11(3): 223-224. shu

Cobalt-catalyzed Photochemical Methoxycarbonylation of Olefins with Carbon Dioxide under Ambient Conditions

a Department of Chemistry & Chemical Engineering, Dalian University, Dalian, 116622;
b Open Laboratory of Carbon Resource Utilization, Dalian University of Technology, Dalian, 116012;
c Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023

Received Date: 1 November 1999

Fund Project: We are indebted to the Natural Science & technology Foundation Council of Liaoning Province, and Open Laboratory of Carbon Resource Utilization of Dalian University of Technology, for the generous financial support.

The methoxycarbonylations of cyclohexene and 1-decene with CO₂ can take place under ambient conditions by catalysis of[Co]([Co]=Co(acac)₂,Co(OAc)₂,CoCl₂) in the presence of ultraviolet irradiation.
- Carbon dioxide,
- methoxycarbonylation,
- cobalt catalyst
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