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Citation: CHANG HUNG-TZE, FONG HAN-PAO, VOONG SING-TUH. SYNTHESIS AND CYCLOPOLYMERIZATION OF DI-(α-CHLOROALLYL) -DIMETHYLSILANE[J]. Acta Polymerica Sinica, ;1964, 6(6): 487-488. shu

SYNTHESIS AND CYCLOPOLYMERIZATION OF DI-(α-CHLOROALLYL) -DIMETHYLSILANE

Received Date: 30 July 1964

Di-(α-chloroallyl)-dimethylsilane, a new silicon-containing α-ω-diene monomer, was synthesized through coupling of dimethylsilicondichloride with α-chloroallyl-magnesium chloride in tetrahydrofuran with 84 % yield. It was then polymerized with ABN, but not with BPO, at rather low temperature (60? to a white powder polymer with softening range of 80-100°. The structure of polymer was elucidated primarily through IR spectra to be the ladder type cyclo-polymer.
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