Citation: MA Long, ZHANG Yu-xi, GAO Xin-hua, MA Qing-xiang, ZHANG Jian-li, ZHAO Tian-sheng. Preparation of Fe₃O₄@PI and its catalytic performances in Fischer-Tropsch synthesis[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(7): 813-820. shu

Preparation of Fe₃O₄@PI and its catalytic performances in Fischer-Tropsch synthesis

State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, Ningxia University, Yinchuan 750021, China

Corresponding author: GAO Xin-hua, gxh@nxu.edu.cn ZHANG Jian-li, zhangjl@nxu.edu.cn
Received Date: 3 April 2020
Revised Date: 4 June 2020

Fund Project: the National Natural Science Foundation of China 21965029the National Natural Science Foundation of China 21968025The project was supported by the Key R & D Project of Ningxia (2018BEE03010) and the National Natural Science Foundation of China (21968025, 21965029)the Key R & D Project of Ningxia 2018BEE03010

Figures(11)

Polyimide (PI) modified Fe₃O₄@PI and Fe₃O₄-PI catalyst samples were prepared by hydrothermal-coating and ball milling methods, respectively. The effect of PI modification on the product distribution of the Fe-based catalysts for Fischer-Tropsch synthesis was investigated. The catalysts were characterized by XRD, SEM, TEM, H₂-TPR, CO-TPD, FT-IR, XPS, TG and contact angle measurements. The results showed that Fe₃O₄, Fe₃O₄@PI and Fe₃O₄-PI were spherical with uniform particle size, and the Fe₃O₄@PI particle size was smaller. PI modification promoted the reduction and the hydrophilicity of Fe₃O₄. For Fe₃O₄@PI sample, PI was uniformly coated on Fe₃O₄ surface, which led to good thermal stability. Compared with Fe₃O₄ and Fe₃O₄-PI samples, CO adsorption was promoted on Fe₃O₄@PI. Compared with Fe₃O₄, the catalytic activity of Fe₃O₄@PI and Fe₃O₄-PI decreased, and the secondary hydrogenation ability was inhibited, resulting in increase of olefin selectivity. For Fe₃O₄@PI, the olefin selectivity was enhanced significantly with olefin to alkane ratio in C_2-4 fraction increased from 0.50 to 2.15. PI modification with suitable content favored the formation of C₅₊ hydrocarbons.
- Fe₃O₄@PI catalyst,
- Fischer-Tropsch synthesis,
- light olefins,
- product distribution
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Preparation of Fe₃O₄@PI and its catalytic performances in Fischer-Tropsch synthesis