Citation: Yu Gui LI, Xue Feng ZHU. STUDIES ON THE SYNTHESIS AND REACTIONS OF N－(1－OXO－4－CARBONYL－2,6,7－TRIOXA－1－PHOSPHABICYCLO ［2．2．2］ OCTANE)－N'－ARYL THIOUREAS[J]. Chinese Chemical Letters, ;1995, 6(1): 19-22. shu

STUDIES ON THE SYNTHESIS AND REACTIONS OF N－(1－OXO－4－CARBONYL－2,6,7－TRIOXA－1－PHOSPHABICYCLO ［2．2．2］ OCTANE)－N'－ARYL THIOUREAS

Yu Gui LI ,
Xue Feng ZHU

Institute of Elemento-Organic Chemistry, Nankai University, Tianjin, 300071

Received Date: 7 March 1994

Fund Project: This project was supported by the National Naturd Science Foundation of China.

N-(1-oxo-4-carbonyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2] octane)-N'-aryl thioureas(4) were synthesized in this paper.(4) reacted with AgNO₃-H₂O and chloroacetyl chloride to afford the corresponding urea derivatives (5) and cyclired products (10),respectively.The mechanism of desulphurisation of (4) has also been studied.
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