Citation: CHEN Jun-hao, LU Liang, WANG Shu-rong. Mild hydrogenation of simulated bio-oil based on molecular distillation[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(9): 1056-1063. shu

Mild hydrogenation of simulated bio-oil based on molecular distillation

State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China

Corresponding author: WANG Shu-rong, zzk@zjut.edu.cn
Received Date: 3 May 2017
Revised Date: 11 June 2017

Fund Project: National Natural Science Foundation of China 51476142National Basic Research Program of China 973 Program, 2013CB228101National Science and Technology Supporting Plan Through Contract 2015BAD15B06The project was supported by the National Science and Technology Supporting Plan Through Contract (2015BAD15B06), the National Natural Science Foundation of China (51476142) and the National Basic Research Program of China (973 Program, 2013CB228101)

Figures(6)

A mild hydrogenation of simulated bio-oil was carried out in a fixed-bed reactor. Based on the experimental results, 300℃/4 MPa was chosen as an optimum condition for the mild hydrogenation, the simulated bio-oil was nearly completely converted. Besides, the liquid product selectivity achieved 85.0% and its (H/C)_eff was significantly promoted from 1.266 to 1.554. The liquid composition was greatly improved and a notable decrease of phenols and acids contents was observed. In this case, the product activity was significantly enhanced and then the subsequent catalytic cracking was favored.
- bio-oil,
- model compounds,
- mild hydrogenation,
- effective hydrogen to carbon ratio
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