Citation: LI Jing, LIU Gui-long, WANG Jia-ming, LIU Yuan. Ni-Co and Ni-Cu bimetallic alloy catalysts for CO methanation[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(5): 610-618. shu

Ni-Co and Ni-Cu bimetallic alloy catalysts for CO methanation

1.
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China
2.
School of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China

Corresponding author: LIU Yuan, yuanliu@tju.edu.cn
Received Date: 20 February 2020
Revised Date: 20 April 2020

Fund Project: the National Natural Science Foundation of China 21576192the National Natural Science Foundation of China 51904152the National Natural Science Foundation of China 21872101the National Natural Science Foundation of China 21962014The project was supported by the National Natural Science Foundation of China (51904152, 21872101, 21576192, 21962014)

Figures(8)

Ni-Co/La₂O₃ and Ni-Cu/La₂O₃ bimetallic alloy catalysts were prepared by using LaNi_0.9Co_0.1O₃ and LaNi_0.9Cu_0.1O₃ perovskite-type oxides precursors. The results demonstrate that the components are diluted with each other in the bimetallic alloy catalyst and exhibit strong anti-sintering ability. The carbon deposited on the catalyst surface mainly depends on the adsorption state of CO, the modulated adsorption state and adsorption strength of CO contribute to the strong anti-carbon deposition ability of the Ni-Co bimetallic catalysts. The Ni-Co bimetallic alloy catalysts show remarkable activity, selectivity, and stability in the CO methanation reaction.
- CO methanation,
- perovskite oxide,
- nickel,
- bi-metal,
- alloy catalyst
1. [1]
  YAO Y, YU F, LI J, LI J, LI Y, WANG Z, ZHU M, SHI Y, DAI B, GUO X. Two-dimensional NiAl layered double oxides as non-noble metal catalysts for enhanced CO methanation performance at low temperature[J]. Fuel, 2019,255115770. doi: 10.1016/j.fuel.2019.115770
2. [2]
  HUSSAIN I, JALIL A A, MAMAT C R, SIANG T J, AZAMI M S, HAMBALI H U. Role of promoters in hoisting the catalytic performance for enhanced CO methanation[J]. J Energy Safety Technol, 2019,2(1):15-20. doi: 10.11113/jest.v2n1.38
3. [3]
  XIONG Wei, DING Ming-yue, TU Jun-ling, CHEN Lun-gang, WANG Tie-jun, ZHANG Qi, MA Long-long. Methanation of biomass pyrolysis gas over Ni catalyst with different supports[J]. J Fuel Chem Technol, 2014,42(8):958-964. doi: 10.3969/j.issn.0253-2409.2014.08.010
4. [4]
  ATKINSON G B, NICKS L J. Mischmetal-nickel alloys as methanation catalysts[J]. J Catal, 1977,46(3):417-419. doi: 10.1016/0021-9517(77)90226-3
5. [5]
  XU Chao, WANG Xing-jun, HU Xian-hui, CHEN Xue-li, WANG Fu-chen. Study on the syngas methanation of nickel-based catalyst[J]. J Fuel Chem Technol, 2012,40(2):216-220. doi: 10.3969/j.issn.0253-2409.2012.02.014
6. [6]
  WANG F, LI Y, CAI W, ZHAN E, MU X, SHEN W. Ethanol steam reforming over Ni and Ni-Cu catalysts[J]. Catal Today, 2009,146(1/2):31-36.
7. [7]
  TAKEGUCHIA T, KANIA Y, YANOA T, KIKUCHIA R, EGUCHIA K, TSUJIMOTOB K, UCHIDAC Y, UENOC A, OMOSHIKIC K, AIZAWAC M. Study on steam reforming of CH₄ and C₂ hydrocarbons and carbon deposition on Ni-YSZ cermets[J]. J Power Sources, 2002,112:588-595. doi: 10.1016/S0378-7753(02)00471-8
8. [8]
  LIU P, ZHAO B, LI S, SHI H, MA M, LU J, YANG F, DENG X, JIA X, MA X, YAN X. Influence of the microstructure of Ni-Co bimetallic catalyst on CO methanation[J]. Ind Eng Chem Res, 2020,59(5):1845-1854. doi: 10.1021/acs.iecr.9b05951
9. [9]
  KUSTOV A L, FREY A M, LARSEN K E, JOHANNESSEN T, NØRSKOV J K, CHRISTENSEN C H. CO methanation over supported bimetallic Ni-Fe catalysts:From computational studies towards catalyst optimization[J]. Appl Catal A:Gen, 2007,320:98-104. doi: 10.1016/j.apcata.2006.12.017
10. [10]
  TANAKAA H, MISONOB M. Advances in designing perovskite catalysts[J]. Curr Opin Solid State Mater Sci, 2001,5:381-387. doi: 10.1016/S1359-0286(01)00035-3
11. [11]
  SILVA C R B, DA CONCEICÃO L, RIBEIRO N F P, SOUZA M M V M. Partial oxidation of methane over Ni-Co perovskite catalysts[J]. Catal Commun, 2011,12(7):665-668. doi: 10.1016/j.catcom.2010.12.025
12. [12]
  MANEERUNG T, HIDAJAT K, KAWI S. LaNiO₃ perovskite catalyst precursor for rapid decomposition of methane:Influence of temperature and presence of H₂ in feed stream[J]. Catal Today, 2011,171(1):24-35. doi: 10.1016/j.cattod.2011.03.080
13. [13]
  LI S, TANG H, GONG D, MA Z, LIU Y. Loading Ni/La₂O₃ on SiO₂ for CO methanation from syngas[J]. Catal Today, 2017,297:298-307. doi: 10.1016/j.cattod.2017.06.014
14. [14]
  GALLEGO G N S, BATIOT-DUPEYRAT C, BARRAULT J L, FLOREZ E, MONDRAGO'N F. Dry reforming of methane over LaNi_1-yB_yO_3±δ (B=Mg, Co) perovskites used as catalyst precursor[J]. Appl Catal A:Gen, 2008,334(1/2):251-258.
15. [15]
  LI C, ZHOU G, WANG L, DONG S, LI J, CHENG T. Effect of ceria on the MgO-γ-Al₂O₃ supported CeO₂/CuCl₂/KCl catalysts for ethane oxychlorination[J]. Appl Catal A:Gen, 2011,400(1/2):104-110.
16. [16]
  TOUAHRA F, CHEBOUT R, LERARI D, HALLICHE D, BACHARI K. Role of the nanoparticles of Cu-Co alloy derived from perovskite in dry reforming of methane[J]. Energy, 2019,171:465-474. doi: 10.1016/j.energy.2019.01.085
17. [17]
  ZHONG S, SUN Y, XIN H, YANG C, CHEN L, LI X. NO oxidation over Ni-Co perovskite catalysts[J]. Chem Eng J, 2015,275:351-356. doi: 10.1016/j.cej.2015.04.046
18. [18]
  RAMESH S, YANG E H, JUNG J S, MOON D J. Copper decorated perovskite an efficient catalyst for low temperature hydrogen production by steam reforming of glycerol[J]. Int J Hydrogen Energy, 2015,40(35):11428-11435. doi: 10.1016/j.ijhydene.2015.02.013
19. [19]
  DE IMA LS M, DA SILVA A M, DA COSTA L O O, ASSAF J M, JACOBS G, DAVIS B H, MATTOS L V, NORONHA F B. Evaluation of the performance of Ni/La₂O₃ catalyst prepared from LaNiO₃ perovskite-type oxides for the production of hydrogen through steam reforming and oxidative steam reforming of ethanol[J]. Appl Catal A:Gen, 2010,377(1/2):181-190.
20. [20]
  LIU F, QU Y, YUE Y, LIU G, LIU Y. Nano bimetallic alloy of Ni-Co obtained from LaCo_xNi_1-xO₃ and its catalytic performance for steam reforming of ethanol[J]. RSC Adv, 2015,5(22):16837-16846. doi: 10.1039/C4RA14131H
21. [21]
  WANG Z, WANG C, CHEN S, LIU Y. Co-Ni bimetal catalyst supported on perovskite-type oxide for steam reforming of ethanol to produce hydrogen[J]. Int J Hydrogen Energy, 2014,39(11):5644-5652. doi: 10.1016/j.ijhydene.2014.01.151
22. [22]
  MEERTEN R Z C V, BEAUMONT A H G M, NISSELROOIJ P F M T V, COENEN J W E. Structure sensitivity and crystallite size change of nickel during methanantion of CO/H₂ on Nickel-Silica catalysts[J]. Surf Sci, 1983,135:565-579. doi: 10.1016/0039-6028(83)90242-X
23. [23]
  O S, YAN J, WANG H, WANG Z, JIANG Q. Ni/La₂O₃ catalyst containing low content platinum-rhodium for the dehydrogenation of N₂H₄·H₂O at room temperature[J]. J Power Sources, 2014,262:386-390. doi: 10.1016/j.jpowsour.2014.03.059
24. [24]
  ZHI G, GUO X, WANG Y, JIN G, GUO X. Effect of La₂O₃ modification on the catalytic performance of Ni/SiC for methanation of carbon dioxide[J]. Catal Commun, 2011,16(1):56-59. doi: 10.1016/j.catcom.2011.08.037
25. [25]
  BENJARAM M. REDDYA, BISWAJIT CHOWDHURY A, SMIRNIOTIS P G. An XPS study of La₂O₃ and In₂O₃ influence on the physicochemical properties of MoO₃/TiO₂ catalysts[J]. Appl Catal A:Gen, 2001,219:53-60. doi: 10.1016/S0926-860X(01)00658-5
26. [26]
  LIU Xin-hua, MIAO Yin, LI Xiao-li, SHENG Shi-shan. The promoting effect of La₂O₃ on Ni/γ-Al₂O₃ methanation catalyst[J]. Acta Phys-Chim Sin, 1995,11(8):746-750. doi: 10.3866/PKU.WHXB19950816
27. [27]
  MAO M, XU J, LI L, ZHAO S, LI X, LI Y, LIU Z. High performance hydrogen production of MoS₂-modified perovskite LaNiO₃ under visible light[J]. Ionics, 2019,25(10):4533-4546. doi: 10.1007/s11581-019-03210-2
28. [28]
  MCINTYRE N S, JOHNSTON D D, COATSWORTH L L, DAVIDSON R D, BROWN J R. X-ray photoelectron spectroscopic studies of thin film oxides of cobalt and molybdenum[J]. Surf Interface Anal, 1990,15:265-272. doi: 10.1002/sia.740150406
29. [29]
  KLEIN J C, HERCULES D M. Surface characterization of model urushibara catalysts[J]. J Catal, 1983,82:424-441. doi: 10.1016/0021-9517(83)90209-9
30. [30]
  LIU Q, TIAN Y, AI H. Methanation of carbon monoxide on ordered mesoporous NiO-TiO₂-Al₂O₃ composite oxides[J]. RSC Adv, 2016,6(25):20971-20978. doi: 10.1039/C6RA00392C
31. [31]
  WAGNER C D. Chemical shifts of auger lines, and the auger parameter[J]. Faraday Discuss Chem Soc, 1975,60:291-300. doi: 10.1039/dc9756000291
32. [32]
  CHAPMAN D. Electronegativity and the stability of metal complexes[J]. Nature, 1954,174:887-888. doi: 10.1038/174887a0
33. [33]
  LOUZGUINE D V, INOUE A. Electronegativity of the constituent rare-earth metals as a factor stabilizing the supercooled liquid region in Al-based metallic glasses[J]. Appl Phys Lett, 2001,79(21):3410-3412. doi: 10.1063/1.1420781
34. [34]
  ARANDIYAN H, KASAEIAN G, NEMATOLLAHI B, WANG Y, SUN H, BARTLETT S, DAI H, REZAEI M. Self-assembly of flower-like LaNiAlO₃-supported nickel catalysts for CO methanation[J]. Catal Commun, 2018,115:40-44. doi: 10.1016/j.catcom.2018.07.001
35. [35]
  OKAMOTO Y, FUKINO K, IMANAKA T, TERANISHI S. Surface state and catalytic activity and selectivity of nickel catalysts in hydrogenation reactions[J]. J Catal, 1982,74:173-182. doi: 10.1016/0021-9517(82)90020-3
36. [36]
  ZENG Y, MA H, ZHANG H, YING W, FANG D. Highly efficient NiAl₂O₄ -free Ni/γ-Al₂O₃ catalysts prepared by solution combustion method for CO methanation[J]. Fuel, 2014,137:155-163. doi: 10.1016/j.fuel.2014.08.003
37. [37]
  TEJUCA L G, FIERRO J L G. XPS and TPD probe techniques for the study of LaNiO₃ perovskite oxide[J]. Thermochim Acta, 1989,147(2):361-375. doi: 10.1016/0040-6031(89)85191-3
38. [38]
  SAW E T, OEMAR U, TAN X R, DU Y, BORGNA A, HIDAJAT K, KAWI S. Bimetallic Ni-Cu catalyst supported on CeO₂ for high-temperature water-gas shift reaction:Methane suppression via enhanced CO adsorption[J]. J Catal, 2014,314:32-46. doi: 10.1016/j.jcat.2014.03.015
39. [39]
  YU Y, JIN G, WANG Y, GUO X. Synthesis of natural gas from CO methanation over SiC supported Ni-Co bimetallic catalysts[J]. Catal Commun, 2013,31:5-10. doi: 10.1016/j.catcom.2012.11.005
40. [40]
  LIU J, CAO A, SI J, ZHANG L, HAO Q, LIU Y. Nanoparticles of Ni-Co alloy derived from layered double hydroxides and their catalytic performance for CO methanation[J]. NANO, 2016,11(10)1650118. doi: 10.1142/S1793292016501186
41. [41]
  TAVARES M T, ALSTRUP I, BERNARDO C A A. Coking and decoking during methanation and methane decomposition on Ni-Cu supported catalysts[J]. Mater Corros, 1999,50:681-685. doi: 10.1002/(SICI)1521-4176(199912)50:12<681::AID-MACO681>3.0.CO;2-5
42. [42]
  KANG N, YANG Q, AN K, LI S, ZHANG L, LIU Y. Mixed oxides of La-Ga-O modified Co/ZrO₂ for higher alcohols synthesis from syngas[J]. Catal Today, 2019,330:46-53. doi: 10.1016/j.cattod.2018.01.034
43. [43]
  SAN JOSÉ ALONSO D, JUAN-JUAN J, ILLÁN-GÓMEZ M J, ROMÁN-MARTÍNEZ M C. Ni, Co and bimetallic Ni-Co catalysts for the dry reforming of methane[J]. Appl Catal A:Gen, 2009,371(1/2):54-59. doi: 10.1016/j.apcata.2009.09.026
44. [44]
  MA S, TAN Y, HAN Y. Methanation of syngas over coral reef-like Ni/Al₂O₃ catalysts[J]. J Nat Gas Chem, 2011,20(4):435-440. doi: 10.1016/S1003-9953(10)60192-2
45. [45]
  ESTEPHANE J, AOUAD S, HANY S, EL KHOURY B, GENNEQUIN C, EL ZAKHEM H, EL NAKAT J, ABOUKAÏS A, ABI AAD E. CO₂ reforming of methane over Ni-Co/ZSM5 catalysts. Aging and carbon deposition study[J]. Int J Hydrogen Energy, 2015,40(30):9201-9208. doi: 10.1016/j.ijhydene.2015.05.147
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