Citation: LI Jing, LIU Gui-long, WANG Jia-ming, LIU Yuan. Ni-Co and Ni-Cu bimetallic alloy catalysts for CO methanation[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(5): 610-618. shu

Ni-Co and Ni-Cu bimetallic alloy catalysts for CO methanation

1.
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China
2.
School of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471934, China

Corresponding author: LIU Yuan, yuanliu@tju.edu.cn
Received Date: 20 February 2020
Revised Date: 20 April 2020

Fund Project: the National Natural Science Foundation of China 21576192the National Natural Science Foundation of China 51904152the National Natural Science Foundation of China 21872101the National Natural Science Foundation of China 21962014The project was supported by the National Natural Science Foundation of China (51904152, 21872101, 21576192, 21962014)

Figures(8)

Ni-Co/La₂O₃ and Ni-Cu/La₂O₃ bimetallic alloy catalysts were prepared by using LaNi_0.9Co_0.1O₃ and LaNi_0.9Cu_0.1O₃ perovskite-type oxides precursors. The results demonstrate that the components are diluted with each other in the bimetallic alloy catalyst and exhibit strong anti-sintering ability. The carbon deposited on the catalyst surface mainly depends on the adsorption state of CO, the modulated adsorption state and adsorption strength of CO contribute to the strong anti-carbon deposition ability of the Ni-Co bimetallic catalysts. The Ni-Co bimetallic alloy catalysts show remarkable activity, selectivity, and stability in the CO methanation reaction.
- CO methanation,
- perovskite oxide,
- nickel,
- bi-metal,
- alloy catalyst
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