Citation: ZHANG Le, LI Qiang, ZHAO Yue, QIN Yu-cai, GAO Xiong-hou, SONG Li-juan. Effect of Ce ion on adsorption and diffusion behavior of benzene in Y zeolite[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(1): 84-92. shu

Effect of Ce ion on adsorption and diffusion behavior of benzene in Y zeolite

ZHANG Le ^1,2 ,
LI Qiang ² ,
ZHAO Yue ² ,
QIN Yu-cai ² ,
GAO Xiong-hou ³ ,
SONG Li-juan ^1,2,*,,

1.
College of Chemical Engineering, China University of Petroleum (East China), Qingdao 266580, China
2.
Liaoning Key Laboratory of Petrochemical Catalytic Science and Technology, Liaoning Shihua University, Fushun 113001, China
3.
Research Institute of Petroleum Processing, SINOPEC, Beijing 100083, China

Corresponding author: SONG Li-juan, tianhuikele@126.com; lsong56@263.net
Received Date: 14 September 2016
Revised Date: 3 November 2016

Fund Project: National Natural Science Foundation of China 21376114

Figures(9)

The liquid ion exchange method was employed to prepare cerium (Ce) cation modified Y zeolite (CeY) with various amount of cerium using different types of Y zeolite (HY, USY and NaY) and characterized by X-ray fluorescence spectrometry (XRF), intelligent gravimetric analyzer (IGA) and a molecular simulation technology (Grand Canonical Monte Carlo simulation, GCMC). A novel calculation method of desorption index (DI) has also been proposed to study the influence of cerium cations on the processes of adsorption-desorption of hydrocarbon molecule (benzene) on the CeY zeolites. The saturated adsorption capacity of benzene, adsorption interaction, desorption thermodynamic parameters, potential distribution curves and diffusion processes of benzene in CeY zeolites were analyzed. The results indicate that Ce ion can reduce the desorption activation energy, weaken the adsorption interaction force between benzene and Y zeolites, and modulate the adsorbed state of benzene molecules from agglomerate state to dispersed state, which are main factors to optimize the product selectivity of light oil components in the fluid catalytic cracking (FCC) process with CeY zeolite catalyst.
- catalysis,
- Y-type zeolite,
- surface,
- sorbents,
- product selectivity,
- Monte Carlo simulation
1. [1]
  GABRIELA D L P, SEDRAN U. Conversion of methylcyclopentane on rare earth exchanged Y zeolite FCC catalysts[J]. Appl Catal A:Gen, 1996,144(1/2):147-158.
2. [2]
  GABRIELA D L P, EDUARDO F S, FATIMA M, Zanon Z, VERA L D C. Influence of different rare earth ions on hydrogen transfer over Y zeolite[J]. Appl Catal A:Gen, 2000,197(1):41-46. doi: 10.1016/S0926-860X(99)00531-1
3. [3]
  LIU X M, LIU S, LIU Y X. A potential substitute for CeY zeolite used in fluid catalytic cracking process[J]. Microporous Mesoporous Mater, 2016,226:162-168. doi: 10.1016/j.micromeso.2015.12.046
4. [4]
  CERQUEIRA H S, CAEIRO G, COSTA L, RAMOA RIBEIRO F J. Deactivation of FCC catalysts[J]. J Mol Catal A:Chem, 2008,292:1-13. doi: 10.1016/j.molcata.2008.06.014
5. [5]
  GUZMAN A, ZUAZO I, FELLER A, OLINDO R, SIEVERS C, LERCHER J A. On the formation of the acid sites in lanthanum exchanged X zeolites used for isobutane/cis-2-butene alkylation[J]. Microporous Mesoporous Mater, 2005,83:309-318. doi: 10.1016/j.micromeso.2005.04.024
6. [6]
  ARBUZNIKOV A, VASILYEV V, GOURSOT A. Relationships between the structure of a zeolite and its adsorption properties[J]. Surf Sci, 1998,397:395-405. doi: 10.1016/S0039-6028(97)00760-7
7. [7]
  SONG L J, SUN Z L, BAN H Y, DAI M, REES L V C. Studies of unusual adsorption and diffusion behaviour of benzene in silicalite-1[J]. Chem Chem Phys, 2004,6:4722-4731. doi: 10.1039/b406051b
8. [8]
  BLIGAARD T, NÖRSKOV J K, DAHL S, MATTHIESEN J, CHRISTENSEN C H, SEHESTED J. The Brönsted-Evans-Polanyi relation and the volcano curve in heterogeneous catalysis[J]. J Catal, 2004,224(1):206-217. doi: 10.1016/j.jcat.2004.02.034
9. [9]
  BEZVERKHYY I, RYZHIKOV A, GADACZ G, BELLAT J P. Kinetics of thiophene reactive adsorption on Ni/SiO₂ and Ni/ZnO[J]. Catal Today, 2008,130(1):199-205. doi: 10.1016/j.cattod.2007.06.038
10. [10]
  LEE E F T, REES L V C. Calcination of cerium (Ⅲ) exchanged Y zeolite[J]. Zeolites, 1987,7(5):446-450. doi: 10.1016/0144-2449(87)90013-3
11. [11]
  LOPES J M, RIBEIRO F R. Effect of rare-earth nature on the basic properties of zeolite NaX containing occluded rare-earth species[J]. J Mol Catal A:Chem, 2002,179:185-191. doi: 10.1016/S1381-1169(01)00324-7
12. [12]
  CERQUEIRA H S, CAEIRO G, COSTA L, RIBEIRO F R. Deactivation of FCC catalysts[J]. J Mol Catal A:Chem, 2008,292:1-13. doi: 10.1016/j.molcata.2008.06.014
13. [13]
  SHU Y, TRAVERT A, SCHILLER R, ZIEBARTH M, WORMSBECHER R, CHENG C W. Effect of ionic radius of rare earth on USY zeolite in fluid catalytic cracking:Fundamentals and commercial application[J]. Top Catal, 2015,58:334-342. doi: 10.1007/s11244-015-0374-0
14. [14]
  DU X H, GAO X H, ZHANG H T, LI X L, LIU P S. Effect of cation location on the hydrothermal stability of rare earth-exchanged Y zeolites[J]. Catal Commun, 2013,35:17-22. doi: 10.1016/j.catcom.2013.02.010
15. [15]
  BOITON A P. The nature of rare-earth exchanged Y zeolites[J]. J Catal, 1971,22(1):9-15. doi: 10.1016/0021-9517(71)90259-4
16. [16]
  SCHERZER J, RITTER R E. Ion-exchanged ultrastable Y zeolites 3 gas oil cracking over rare earth-exchanged ultrastable Y zeolites[J]. Ind Eng Chem Prod Res Dev, 1978,17(3):219-223. doi: 10.1021/i360067a008
17. [17]
  YU Shan-qin, TIAN Hui-ping, DAI Zhen-yu, LONG Jun. Mechanism of the influence of lanthanum and cerium on the stability of Y zeolite[J]. Chin J Catal, 2010,31(10):1263-1270.
18. [18]
  SHU Y Y, TRAVERT A, SCHILLER R, MICHAEL Z, RICHARD W, WU C C. Effect of ionic radius of rare earth on USY zeolite in fluid catalytic cracking:Fundamentals and commercial application[J]. Top Catal, 2015,58:334-342. doi: 10.1007/s11244-015-0374-0
19. [19]
  LU Tian, CHEN Fei-wu. Comparison of computational methods for atomic charges[J]. Acta Phys-Chim Sin, 2012,28(1):1-18.
20. [20]
  ZHANG Le, QIN Yu-cai, JI De-qiang, YANG Ye, JIA Wei-ming, SONG Li-juan. The effects of cerium ions migration on active sites of y zeolite[J]. Chin Rare Earth, 2016,37(4):16-22.
21. [21]
  LEE C K, ASHTEKAR S, GLADDEN L F, BARRIE P J. Adsorption and desorption kinetics of hydrocarbons in FCC catalysts studied using a tapered element oscillating microbalance (TEOM). Part 1:Experimental measurements[J]. J Chem Eng Sci, 2004,59:1131-1138. doi: 10.1016/j.ces.2004.01.005
22. [22]
  BARRIE P J, LEE C K, GLADDEN L F. Adsorption and desorption kinetics of hydrocarbons in FCC catalysts studied using a tapered element oscillating microbalance (TEOM). Part 2:Numerical simulations[J]. Chem Eng Sci, 2004,59:1139-1151. doi: 10.1016/j.ces.2004.01.008
23. [23]
  DUAN Lin-hai. Adsorption, diffusion on zeolite and it's application[D]. Lanzhou:Lanzhou University, 2006.
24. [24]
  LIU Dao-sheng, HAN Chun-yu, DUAN Lin-hai, SONG Li-juan, SUN Zhao-lin. Activation energy of temperature programmed desorption calculated using least-squares method for benzene, thiophene and octane on NaY[J]. Acta Phys-Chim Sin, 2009,25(3):470-476.
25. [25]
  BROIDO A J. Sensitive graphical method of treating thermogravimetric analysis data[J]. Polym Sci Part B:Polym Phys, 1969,7(10):1761-1773. doi: 10.1002/pol.1969.160071012
26. [26]
  FALCONER J L, MADIX R J. Desorption rate isotherms in flash desorption analysis[J]. J Catal, 1977,48(1/3):262-268.
27. [27]
  KISSINGER H E. Reaction kinetics in differential thermal analysis[J]. Anal Chem, 1957,29(11):1703-1706.
28. [28]
  YANG R T, STEINBERG M. Reaction kinetics and differential thermal analysis[J]. J Phys Chem, 1976,80(9):965-968. doi: 10.1021/j100550a009
29. [29]
  SUN Shu-hong, PANG Xin-mei, ZHENG Shu-qin, ZHANG Zhong-dong. Preparation of FCC catalyst containing REUSY[J]. Chin Pet Proc Pet Technol, 2001,32(6):25-28.
30. [30]
  SOUSA-AGUIAR E F, TRIGUEIRO F E, ZOTIN F M Z. The role of rare earth elements in zeolites and cracking catalysts[J]. Catal Today, 2013,218-219:115-122. doi: 10.1016/j.cattod.2013.06.021
31. [31]
  ZHANG Le, GAO Xiong-hou, ZHANG Yan-hui, SU Yi, ZHANG Ai-ping. Effects of sodium content on physicochemical properties of USY zeolite[J]. J Synthetic Crystals, 2014,43(2):454-464.
32. [32]
  SANDOVAL-DÍAZ L E, MARTÍNEZ-GIL J M, TRUJILLO C A. The combined effect of sodium and vanadium contamination upon the catalytic performance of USY zeolite in the cracking of n-butane:Evidence of path-dependent behavior in Constable-Cremer plots[J]. J Catal, 2012,294:89-98. doi: 10.1016/j.jcat.2012.07.009
1. [1]
  Qingtao CHEN , Xiangdong SHI , Xianghai RAO , Liying JIANG , Chunxiao JIA , Fenghua CHEN . Catalytic and in situ surface-enhanced Raman scattering detection properties of graphene oxide/gold nanorod assembly. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 120-128. doi: 10.11862/CJIC.20250091
2. [2]
  Wenjuan SHI , Yuke LU , Xiuyuan LI , Lei HOU , Yaoyu WANG . Mg(Ⅱ) metal-organic frameworks based on biphenyltetracarboxylic acid: Synthesis and CO₂ adsorption and catalytic conversion performance. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2455-2463. doi: 10.11862/CJIC.20250220
3. [3]
  Kun JIANG , Yutong XUE , Kelin LIU , Miao WANG , Tongming SUN , Yanfeng TANG . CeVO₄ hollow microspheres: Fabrication and adsorption performance for dyes. Chinese Journal of Inorganic Chemistry, 2025, 41(11): 2229-2236. doi: 10.11862/CJIC.20250223
4. [4]
  Pengfei WANG , Qiuyan WU . Nano-sized 1D copper coordination polymer: Room-temperature solid-state synthesis and efficient adsorption performance toward Congo red dye. Chinese Journal of Inorganic Chemistry, 2026, 42(10): 2099-2108. doi: 10.11862/CJIC.20260150
5. [5]
  Ran Yu , Chen Hu , Ruili Guo , Ruonan Liu , Lixing Xia , Cenyu Yang , Jianglan Shui . Catalytic Effect of H₃PW₁₂O₄₀ on Hydrogen Storage of MgH₂. Acta Physico-Chimica Sinica, 2025, 41(1): 100001-0. doi: 10.3866/PKU.WHXB202308032
6. [6]
  Tianhao GE , Sirong LU , Zhiyin XIAO , Wei ZHONG . Synthesis of porphyrin-based ionic polymeric materials for catalytic application in CO₂ conversion. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 722-736. doi: 10.11862/CJIC.20250312
7. [7]
  Xiaogang Liu , Mengyu Chen , Yanyan Li , Xiantao Ma . Experimental Reform in Applied Chemistry for Cultivating Innovative Competence: A Case Study of Catalytic Hydrogen Production from Liquid Formaldehyde Reforming at Room Temperature. University Chemistry, 2025, 40(7): 300-307. doi: 10.12461/PKU.DXHX202408007
8. [8]
  Mengyang LI , Zhonghao NIU , Hao XU , Jingli XIE . One-pot synthesis of 4H-pyran derivatives catalyzed by viologen-modified metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2026, 42(7): 1513-1522. doi: 10.11862/CJIC.20250205
9. [9]
  Qin′ai FENG , Jianjun LI , Lili ZHANG , Linxin WU , Huiling WANG , Wenjing HOU , Lei WANG , Mingjie REN . Amphiphilic surface modification of magnetic adsorbents and its adsorption properties of two microplastics. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 789-807. doi: 10.11862/CJIC.20250208
10. [10]
  Yongxin LIU , Xingchen LI , Hongjia LIU , Danni LI , Tao ZHANG , Xi CHEN . Enhancement effect of Fe₃O₄ conversion to MIL-100(Fe) on activation of persulfate for degradation of antibiotic. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2503-2513. doi: 10.11862/CJIC.20250169
11. [11]
  Ting YANG , Jia AN , Jinyu ZHANG , Ruonan FAN , Rong YAN , Xiaoxia JING , Panpan CHANG , Wei YAN . Synergistic enhancement of ion migration and sulfur conversion kinetics in lithium-sulfur batteries by CeO₂/g-C₃N₄. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 519-530. doi: 10.11862/CJIC.20250274
12. [12]
  Qing ZHANG , Kexin ZHOU , Yanjun GUO , Guangjun CHEN , Bai HE , Bo YU , Songshan JIANG , Guoyuan YUAN , Huidong QIU . Preparation, functional modification, and applications of Fe₃O₄ nanoparticles. Chinese Journal of Inorganic Chemistry, 2026, 42(7): 1383-1411. doi: 10.11862/CJIC.20250344
13. [13]
  Shiyan Cheng , Yonghong Ruan , Lei Gong , Yumei Lin . Research Advances in Friedel-Crafts Alkylation Reaction. University Chemistry, 2024, 39(10): 408-415. doi: 10.12461/PKU.DXHX202403024
14. [14]
  Xinyu Xu , Jiale Lu , Bo Su , Jiayi Chen , Xiong Chen , Sibo Wang . Steering charge dynamics and surface reactivity for photocatalytic selective methane oxidation to ethane over Au/Ti-CeO₂. Acta Physico-Chimica Sinica, 2025, 41(11): 100153-0. doi: 10.1016/j.actphy.2025.100153
15. [15]
  Feifei Yang , Wei Zhou , Chaoran Yang , Tianyu Zhang , Yanqiang Huang . Enhanced Methanol Selectivity in CO₂ Hydrogenation by Decoration of K on MoS₂ Catalyst. Acta Physico-Chimica Sinica, 2024, 40(7): 2308017-0. doi: 10.3866/PKU.WHXB202308017
16. [16]
  Jianan Zhang , Mengzhen Xu , Jiamin Liu , Yufei He . 面向“双碳”目标的脱氯吸附剂开发研究型综合实验设计. University Chemistry, 2025, 40(6): 248-255. doi: 10.12461/PKU.DXHX202408068
17. [17]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
18. [18]
  Jingkun Yu , Xue Yong , Ang Cao , Siyu Lu . Bi-Layer Single Atom Catalysts Boosted Nitrate-to-Ammonia Electroreduction with High Activity and Selectivity. Acta Physico-Chimica Sinica, 2024, 40(6): 2307015-0. doi: 10.3866/PKU.WHXB202307015
19. [19]
  Ze Luo , Yukun Zhu , Yadan Luo , Guangmin Ren , Yonghong Wang , Hua Tang . Photocatalytic selective oxidation of 5-hydroxymethylfurfural coupled with H₂ evolution over In₂O₃/ZnIn₂S₄ S-scheme heterojunction. Acta Physico-Chimica Sinica, 2026, 42(3): 100166-0. doi: 10.1016/j.actphy.2025.100166
20. [20]
  Zhen Li , Sujuan Zhang , Zhongliao Wang , Jinfeng Zhang , Gaoli Chen , Shifu Chen . Rational design of S-scheme CdS/MnO₂ heterojunctions for high-value photothermal synergistic catalytic oxidation of toluene. Acta Physico-Chimica Sinica, 2026, 42(4): 100179-0. doi: 10.1016/j.actphy.2025.100179

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(3208)
HTML views(316)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142