Citation: Hai Yan LU, Nan Jing ZRANG, Yu Fen ZHAO. Pentacoordinated Spirophosphoranes from Amino Acid Sodium Salts[J]. Chinese Chemical Letters, ;1997, 8(5): 397-400. shu

Pentacoordinated Spirophosphoranes from Amino Acid Sodium Salts

Bioorganic Phosphorus Chemistry Laboratory, Dcyartinen of Chemistry, Tsinghua Universlty, Beijing 100084

Received Date: 10 January 1997

Fund Project: The authors would like to thank the financial support from the National Natural Science Foundation of China.

The reactions of 2-chloro-1,3,2-dioxaphospholane with various sodium salts of amino acids to afford the pentacoordinated spirophosphoranes containing amino acid were studied by NMR spectra techniques.The results showed that natural α-amino acids had greater ability than β-amino acids to form the pentacoordinated species,which is important in the biosynthesis and prebiotic synthesis of oligopeptides and proteins.
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