Citation: LI He-jian, ZHENG Li, ZHAO Tian-qi, XU Xiu-feng. Effect of preparation parameters on the catalytic performance of hydrothermally synthesized Co₃O₄ in the decomposition of N₂O[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(6): 717-724. shu

Effect of preparation parameters on the catalytic performance of hydrothermally synthesized Co₃O₄ in the decomposition of N₂O

School of Chemistry and Chemical Engineering, Institute of Applied Catalysis, Yantai University, Yantai 264005, China

Corresponding author: XU Xiu-feng, xxf@ytu.edu.cn
Received Date: 24 February 2018
Revised Date: 1 May 2018

Fund Project: Graduate Innovation Foundation of Yantai University YDZD1816The project was supported by the Shandong Provincial Natural Science Foundation (ZR2017MB020) and Graduate Innovation Foundation of Yantai University (YDZD1816)the Shandong Provincial Natural Science Foundation ZR2017MB020

Figures(13)

With hexadecyl trimethyl ammonium bromide (CTAB) as the template, cobaltosic oxide precursors were hydrothermally synthesized. Co₃O₄ catalysts were then prepared by calcining the cobaltosic oxide precursors, which was further modified by impregnation with K₂CO₃ solution and used in the decomposition of N₂O. The catalysts were characterized by means of X-ray diffraction (XRD), nitrogen physisorption, scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), hydrogen temperature-programmed reduction (H₂-TPR), and oxygen temperature-programmed desorption (O₂-TPD); the effect of CTAB concentration, CTAB/cobalt molar ratio and urea/cobalt molar ratio on the catalytic activity of Co₃O₄ was investigated. The results indicated that the Co₃O₄ catalyst prepared by using 0.05 mol/L CTAB solution, with a CTAB to cobalt molar ratio of 1 and a urea to cobalt molar ratio of 4, exhibits high activity in N₂O decomposition. The catalytic performance of Co₃O₄ can be further enhanced by modifying with K. Over the 0.02 K/Co₃O₄ catalyst, the N₂O conversion remains over 91% at 400 ℃ after conducting the N₂O decomposition reaction for 50 h in the presence of oxygen and steam.
- Co₃O₄,
- hydrothermal synthesis,
- preparation parameters,
- catalytic decomposition,
- N₂O
1. [1]
  LIN Y, MENG T, MA Z. Catalytic decomposition of N₂O over RhO_x supported on metal phosphates[J]. J Ind Eng Chem, 2015,28:138-146. doi: 10.1016/j.jiec.2015.02.009
2. [2]
  PACHATOURIDOU E, PAPISTA E, DELIMITIS A, VASILIADES M A, EFSTATHIOU A M, AMIRIDIS M D, ALEXEEV O S, BLOOM D, MARNELLOS G E, KONSOLAKIS M, ILIOPOULOU E. N₂O decomposition over ceria-promoted Ir/Al₂O₃ catalysts:The role of ceria[J]. Appl Catal B:Environ, 2016,187:259-268. doi: 10.1016/j.apcatb.2016.01.049
3. [3]
  CARABINEIRO S A C, PAPISTA E, MARNELLOS G E, TAVARES P B, MALDONADO-HÓDAR F J, KONSOLAKIS M. Catalytic decomposition of N₂O on inorganic oxides:Effect of doping with Au nanoparticles[J]. Mol Catal, 2017,436:78-89. doi: 10.1016/j.mcat.2017.04.009
4. [4]
  XIE P F, MA Z, ZHOU H B, HUANG C Y, YUE Y H, SHEN W, XU H L, HUA W M, GAO Z. Catalytic decomposition of N₂O over Cu-ZSM-11 catalysts[J]. Microporous Mesoporous Mater, 2014,191:112-117. doi: 10.1016/j.micromeso.2014.02.044
5. [5]
  KUBONOVÁ L, PEIKERTOVÁ P, KUTLÁKOVÁ K M, JIRÁTOVÁ K, SŁOWIK G, OBALOVÁ L, COOL P. Catalytic activity of cobalt grafted on ordered mesoporous silicamaterials in N₂O decomposition and CO oxidation[J]. Mol Catal, 2017,437:57-72. doi: 10.1016/j.mcat.2017.04.037
6. [6]
  MELIÁN-CABRERA I, VAN ECK E R H, ESPINOSA S, SILES-QUESADA S, FALCO L, KENTGENS A P M, KAPTEIJN F, MOULIJN J A. Tail gas catalyzed N₂O decomposition over Fe-beta zeolite. On the promoting role of framework connected AlO₆ sites in the vicinity of Fe by controlled dealumination during exchange[J]. Appl Catal B:Environ, 2017,203:218-226. doi: 10.1016/j.apcatb.2016.10.019
7. [7]
  SÁDOVSKÁ G, TABOR E, SAZAMA P, LHOTKA M, BERNAUER M, SOBALÍK Z. High temperature performance and stability of Fe-FER catalyst for N₂O decomposition[J]. Catal Commun, 2017,89:133-137. doi: 10.1016/j.catcom.2016.10.029
8. [8]
  MANIAK G, STELMACHOWSKI P, ZASADA F, PISKORZ W, KOTARBA A, SOJKA Z. Guidelines for optimization of catalytic activity of 3d transition metal oxide catalysts in N₂O decomposition by potassium promotion[J]. Catal Today, 2011,176:369-372. doi: 10.1016/j.cattod.2010.11.043
9. [9]
  LIU Z M, HE C X, CHEN B H, LIU H Y. CuO-CeO₂ mixed oxide catalyst for the catalytic decomposition of N₂O in the presence of oxygen[J]. Catal Today, 2017,297:78-83. doi: 10.1016/j.cattod.2017.05.074
10. [10]
  LIU Z M, ZHOU Z Z, HE F, CHEN B H, ZHAO Y Y, XU Q. Catalytic decomposition of N₂O over NiO-CeO₂ mixed oxide catalyst[J]. Catal Today, 2017,293/94:56-60.
11. [11]
  CHROMCÁKOVÁ Z, OBALOVÁ L, KOVANDA F, LEGUT D, TITOV A, RITZ M, FRIDRICHOVÁ D, MICHALIK S, KUSTROWSKI P, JIRÁTOVÁ K. Effect of precursor synthesis on catalytic activity of Co₃O₄ in N₂O decomposition[J[[J]. Catal Today, 2015,257:18-25. doi: 10.1016/j.cattod.2015.03.030
12. [12]
  OHNISHI C, ASANO K, IWAMOTO S, CHIKAMA K, INOUE M. Alkali-doped Co₃O₄ catalysts for direct decomposition of N₂O in the presence of oxygen[J]. Catal Today, 2007,120:145-150. doi: 10.1016/j.cattod.2006.07.042
13. [13]
  MANIAK G, STELMACHOWSKI P, KOTARBA A, SOJKA Z, RICO-PéREZ V, BUENO-LóPEZ A. Rationales for the selection of the best precursor for potassium doping of cobalt spinel based deN₂O catalyst[J]. Appl Catal B:Environ, 2013,136/137:302-307. doi: 10.1016/j.apcatb.2013.01.068
14. [14]
  GRZYBEK G, WÓJCIK S, CIURA K, GRYBO Ś J, INDYKA P, OSZAJCA M, STELMACHOWSKI P, WITKOWSKI S, INGER M, WILK M, KOTARBA A, SOJKA Z. Influence of preparation method on dispersion of cobalt spinel over alumina extrudates and the catalyst deN₂O activity[J]. Appl Catal B:Environ, 2017,210:34-44. doi: 10.1016/j.apcatb.2017.03.053
15. [15]
  YU H B, WANG X P, WU X X, CHEN Y. Promotion of Ag for Co₃O₄ catalyzing N₂O decomposition under simulated real reaction conditions[J]. Chem Eng J, 2018,334:800-806. doi: 10.1016/j.cej.2017.10.079
16. [16]
  WANG Y Z, HU X B, ZHENG K, WEI X H, ZHAO Y X. Effect of SnO₂ on the structure and catalytic performance of Co₃O₄ for N₂O decomposition[J]. Catal Commun, 2018,111:70-74. doi: 10.1016/j.catcom.2018.04.004
17. [17]
  DOU Z, ZHANG H J, PAN Y F, XU X F. Catalytic decomposition of N₂O over potassium-modified Cu-Co spinel oxides[J]. J Fuel Chem Technol, 2014,42(2):238-245. doi: 10.1016/S1872-5813(14)60016-5
18. [18]
  LIU T Q, GUO R, SHEN M, YU W L. Determination of the diffusion coefficients of micelle and the first CMC and second CMC in SDS and CTAB solution[J]. Acta Phys Chim Sin, 1996,12(4):337-340.
19. [19]
  STELMACHOWSKI P, MANIAK G, KOTARBA A, SOJKA Z. Strong electronic promotion of Co₃O₄ towards N₂O decomposition by surface alkali dopants[J]. Catal Commun, 2009,10(7):1062-1065. doi: 10.1016/j.catcom.2008.12.057
20. [20]
  PAN Y F, FENG M, CUI X, XU X F. Catalytic activity of alkali metal doped Cu-Al mixed oxides for N₂O decomposition in the presence of oxygen[J]. J Fuel Chem Technol, 2012,40(5):601-607. doi: 10.1016/S1872-5813(12)60024-3
21. [21]
  FRANKEN T, PALKOVITS R. Investigation of potassium doped mixed spinels Cu_xCo_3-xO₄ as catalysts for an efficient N₂O decomposition in real reaction conditions[J]. Appl Catal B:Environ, 2015,176-177:298-305. doi: 10.1016/j.apcatb.2015.04.002
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
2. [2]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
3. [3]
  Juan CHEN , Guoyu YANG . A porous-layered aluminoborate built by mixed oxoboron clusters and AlO₄ tetrahedra. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 193-200. doi: 10.11862/CJIC.20240341
4. [4]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
5. [5]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
6. [6]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
7. [7]
  Linping Li , Junhui Su , Yanping Qiu , Yangqin Gao , Ning Li , Lei Ge . Design and fabrication of ternary Au/Co3O4/ZnCdS spherical composite photocatalyst for facilitating efficient photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2024, 43(12): 100472-100472. doi: 10.1016/j.cjsc.2024.100472
8. [8]
  Ruiying Liu , Li Zhao , Baishan Liu , Jiayuan Yu , Yujie Wang , Wanqiang Yu , Di Xin , Chaoqiong Fang , Xuchuan Jiang , Riming Hu , Hong Liu , Weijia Zhou . Modulating pollutant adsorption and peroxymonosulfate activation sites on Co3O4@N,O doped-carbon shell for boosting catalytic degradation activity. Chinese Journal of Structural Chemistry, 2024, 43(8): 100332-100332. doi: 10.1016/j.cjsc.2024.100332
9. [9]
  Xin Li , Wanting Fu , Ruiqing Guan , Yue Yuan , Qinmei Zhong , Gang Yao , Sheng-Tao Yang , Liandong Jing , Song Bai . Nucleophiles promotes the decomposition of electrophilic functional groups of tetracycline in ZVI/H₂O₂ system: Efficiency and mechanism. Chinese Chemical Letters, 2024, 35(10): 109625-. doi: 10.1016/j.cclet.2024.109625
10. [10]
  Qinwen Zheng , Xin Liu , Lintao Tian , Yi Zhou , Libing Liao , Guocheng Lv . Mechanism of Fenton catalytic degradation of Rhodamine B induced by microwave and Fe₃O₄. Chinese Chemical Letters, 2025, 36(4): 109771-. doi: 10.1016/j.cclet.2024.109771
11. [11]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
12. [12]
  Qingwang LIU . MoS₂/Ag/g-C₃N₄ Z-scheme heterojunction: Preparation and photocatalytic performance. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 821-832. doi: 10.11862/CJIC.20240148
13. [13]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064
14. [14]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
15. [15]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
16. [16]
  Hui Li , Yanxing Qi , Jia Chen , Juanjuan Wang , Min Yang , Hongdeng Qiu . Synthesis of amine-pillar[5]arene porous adsorbent for adsorption of CO₂ and selectivity over N₂ and CH₄. Chinese Chemical Letters, 2024, 35(11): 109659-. doi: 10.1016/j.cclet.2024.109659
17. [17]
  Mingjiao Lu , Zhixing Wang , Gui Luo , Huajun Guo , Xinhai Li , Guochun Yan , Qihou Li , Xianglin Li , Ding Wang , Jiexi Wang . Boosting the performance of LiNi_0.90Co_0.06Mn_0.04O₂ electrode by uniform Li₃PO₄ coating via atomic layer deposition. Chinese Chemical Letters, 2024, 35(5): 108638-. doi: 10.1016/j.cclet.2023.108638
18. [18]
  Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
19. [19]
  Hualin Jiang , Wenxi Ye , Huitao Zhen , Xubiao Luo , Vyacheslav Fominski , Long Ye , Pinghua Chen . Novel 3D-on-2D g-C₃N₄/AgI._x._y heterojunction photocatalyst for simultaneous and stoichiometric production of H₂ and H₂O₂ from water splitting under visible light. Chinese Chemical Letters, 2025, 36(2): 109984-. doi: 10.1016/j.cclet.2024.109984
20. [20]
  Shiyi WANG , Chaolong CHEN , Xiangjian KONG , Lansun ZHENG , Lasheng LONG . Polynuclear lanthanide compound [Ce₄^ⅢCe₆^Ⅳ(μ₃-O)₄(μ₄-O)₄(acac)₁₄(CH₃O)₆]·2CH₃OH for the hydroboration of amides to amine. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 88-96. doi: 10.11862/CJIC.20240342

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(1314)
HTML views(88)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of preparation parameters on the catalytic performance of hydrothermally synthesized Co3O4 in the decomposition of N2O

Metrics

通讯作者: 陈斌, bchen63@163.com

Effect of preparation parameters on the catalytic performance of hydrothermally synthesized Co₃O₄ in the decomposition of N₂O