Citation: Yuan Qi YIN, Hong Sui SUN, Zhuan Yun ZHAO. SYNTHESES OF TETRAHEDRAL METAL CLUSTER COMPOUNDS[J]. Chinese Chemical Letters, ;1992, 3(7): 551-554. shu

SYNTHESES OF TETRAHEDRAL METAL CLUSTER COMPOUNDS

a Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000;
b Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Received Date: 27 January 1992

The carbyne compound [Br(CO)₂(Py)₂Mo(≡CC₆H₅)] (Py=pyridine) (1a) reacts with Co₂(CO)₈, Fe₂(CO)₉ and Mn₂(CO)₁₀ to give tetrahedral tri-metal cluster compounds Co₂Mo(μ₃-CC₆H₅)Br(CO)₈(Py)₂ (2), Fe₂Mo(μ₃-CC₆H₅)Br(CO)₉(Py)₂ (3) and Mn₂Mo(μ₃-CC₆H₅)Br(CO)₁₀(Py)₂ (4)respectively.Tri-metal cluster compound Co₂Mo(μ₃-CC₆H₅)Br(CO)₈(bipy) (bipy=α,α'dipyridyl) (5) is prepared in a similar reaction sequence from [Br(CO)₂(bipy)Mo(≡CC₆H₅)] (1b) and Co₂(CO)₈. IR,¹H and ¹³C NMR spectral data of these compounds are reported and discussed.The crystal structure of compound (5) has been determined by X-ray diffraction.
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