Citation: Maliwan Subsadsana, Pitsanuphong Kham-or, Pakpoom Sangdara, Pirom Suwannasom, Chalerm Ruangviriyachai. Synthesis and catalytic performance of bimetallic NiMo-and NiW-ZSM-5/MCM-41 composites for production of liquid biofuels[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(7): 805-816. shu

Synthesis and catalytic performance of bimetallic NiMo-and NiW-ZSM-5/MCM-41 composites for production of liquid biofuels

Materials Chemistry Research Center and Center of Excellence for Innovation in Chemistry, Department of Chemistry, Faculty of Science, Khon Kaen University, Khon Kaen 40002, Thailand

Corresponding author: Chalerm Ruangviriyachai, chal_ru@kku.ac.th
Received Date: 23 January 2017
Revised Date: 2 May 2017

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This work presents a synthesis of bimetallic NiMo and NiW modified ZSM-5/MCM-41 composites and their heterogeneous catalytic conversion of crude palm oil (CPO) to biofuels. The ZSM-5/MCM-41 composites were synthesized through a self-assembly of cetyltrimethylammonium bromide (CTAB) surfactant with silica-alumina from ZSM-5 zeolite, prepared from natural kaolin by the hydrothermal technique. Subsequently, the synthesized composites were deposited with bimetallic NiMo and NiW by impregnation method. The obtained catalysts presented a micro-mesoporous structure, confirmed by XRD, SEM, TEM, EDX, NH₃-TPD, XRF and N₂ adsorption-desorption measurements. The results of CPO conversion demonstrate that the catalytic activity of the synthesized catalysts decreases in the series of NiMo-ZSM-5/MCM-41 > NiW-ZSM-5/MCM-41 > Ni-ZSM-5/MCM-41 > Mo-ZSM-5/MCM-41 > W-ZSM-5/MCM-41 > NiMo-ZSM-5 > NiW-ZSM-5 > ZSM-5/MCM-41 > ZSM-5 > MCM-41. It was found that the bimetallic NiMo-and NiW-ZSM-5/MCM-41 catalysts give higher yields of liquid hydrocarbons than other catalysts at a given conversion. Types of hydrocarbon in liquid products, identified by simulated distillation gas chromatography-flame ionization detector (SimDis GC-FID), are gasoline (150-200 ℃; C_5-12), kerosene (250-300 ℃; C_5-20) and diesel (350 ℃; C_7-20). Moreover, the conversion of CPO to biofuel products using the NiMo-and NiW-ZSM-5/MCM-41 catalysts offers no statistically significant difference (P > 0.05) at 95% confidence level, evaluated by SPSS analysis.
- self-assembly of surfactant,
- ZSM-5/MCM-41 composite,
- micro-mesoporous structure,
- hydrocracking process,
- liquid biofuels
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