Citation: XIONG Qing-an, LI Jia-zhou, LI Chun-yu, GUO Shuai, ZHAO Jian-tao, FANG Yi-tian. Migration and transformation behaviors of vanadium (V) with different occurrence modes during combustion of high sulfur petroleum coke[J]. Journal of Fuel Chemistry and Technology, ;2018, 46(2): 145-151. shu

Migration and transformation behaviors of vanadium (V) with different occurrence modes during combustion of high sulfur petroleum coke

1.
Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: ZHAO Jian-tao, zhaojt@sxicc.an.cn
Received Date: 22 September 2017
Revised Date: 2 January 2018

Fund Project: The project was supported by the National Natural Science Foundation of China (21576276, 21506241) and Strategic Priority Research Program of the Chinese Academy of Sciences (XDA07050100)the National Natural Science Foundation of China 21506241Strategic Priority Research Program of the Chinese Academy of Sciences XDA07050100the National Natural Science Foundation of China 21576276

Figures(8)

The occurrence modes and migration behavior of vanadium were investigated by sequential chemical extraction combined with ICP-OES during combustion of high-sulfur petroleum coke. The chemical reaction mechanism was discussed based on thermodynamic analysis. The vanadium in raw petroleum coke is mainly associated with organic matter and stable forms. With increasing temperature organic V disappear and the released vanadium could react with minerals such as Ca, K, Na, Fe to form different vanadium species including water soluble and ion exchange state, carbonates and Fe-Mn oxides. Steady-state vanadium is mainly combined with other minerals to form amorphous substance existing in petroleum coke. These amorphous substances might transform and release vanadium species at high combustion temperatures. The V volatility is correlated with temperature and burn out rate. The volatility may sharply rise because organic matter decomposed and released gaseous VO₂ above 1100℃.
- petroleum coke,
- combustion,
- vanadium,
- occurrence mode,
- migration behavior
1. [1]
  JIN Yan-chun. Supply and demand status and prediction of domestic petroleum coke market[J]. Econ Anal China Pet Chem Ind, 2016(3):57-60.
2. [2]
  BRYERS R W. Utilization of petroleum coke and petroleum coke/coal blends as a means of steam raising[J]. Fuel Process Technol, 1995,44(1/3):121-141.
3. [3]
  CHEN J, LU X. Progress of petroleum coke combusting in circulating fluidized bed boilers-A review and future perspectives[J]. Resour Conserv Recycl, 2007,49(3):203-216.
4. [4]
  ZYCHLINSKI L, BYCZKOWSKI J Z, KULKARNI A P. Toxic effects of long-term intratracheal administration of vanadium pentoxide in rats[J]. Arch Environ Contam Toxicol, 1991,20(3):295-298. doi: 10.1007/BF01064393
5. [5]
  KELEMEN S R, SISKIN M, GORBATY M L, FERRUGHELLI D T, KWIATEK P J, BROWN L D, EPPIG C P, KENNEDY R J. Delayed coker coke morphology fundamentals:Mechanistic implications based on XPS analysis of the composition of vanadium-and nickel-containing additives during coke formation[J]. Energy Fuels, 2007,21(2):927-940. doi: 10.1021/ef060493e
6. [6]
  AMORIM F A C, WELZ B, COSTA A C, LEPRI F G, VALE M G, FERREIRA S L. Determination of vanadium in petroleum and petroleum products using atomic spectrometric techniques[J]. Talanta, 2007,72(2):349-359. doi: 10.1016/j.talanta.2006.12.015
7. [7]
  ZULIANI J E, MIYATA T, MIZOGUCHI T, FENG J, KIRK D W, JIA C Q. Characterization of vanadium in oil sands fluid petroleum coke using electron microscopy[J]. Fuel, 2016,178:124-128. doi: 10.1016/j.fuel.2016.03.015
8. [8]
  CONN R. Environmental evaluation of CFB ash from petroleum coke[C]//Abstracts of Papers of the American Chemical Society. 115516TH ST, NW, WASHINGTON, DC 20036 USA: AMER CHEMICAL SOC, 1998, 216: U768-U768.
9. [9]
  JIA L, ANTHONY E J, CHARLAND J P. Investigation of vanadium compounds in ashes from a CFBC firing petroleum coke[J]. Energy Fuels, 2002,16(2):397-403. doi: 10.1021/ef010238o
10. [10]
  LI Y, ZHANG J, ZHAO Y, ZHENG C. Volatility and speciation of mercury during pyrolysis and gasification of five Chinese coals[J]. Energy Fuels, 2011,25(9):3988-3996. doi: 10.1021/ef2006904
11. [11]
  TESSIER A, CAMPBELL P G C, BISSON M. Sequential extraction procedure for the speciation of particulate trace metals[J]. Anal Chem, 1979,51(7):844-851. doi: 10.1021/ac50043a017
12. [12]
  LI J Z, ZHAO J T, FANG H B, LIU T, FANG Y T. Transformation behavior of vanadium in petroleum coke during high temperature CO₂-gasification[J]. Fuel, 2017,194:83-90. doi: 10.1016/j.fuel.2017.01.002
13. [13]
  SOROKINA T P, BULUCHEVSKAYA L A, POTAPENKO O V, DORONIN V P. Conversion of nickel and vanadium porphyrins under catalytic cracking conditions[J]. Petrol Chem, 2010,50(1):51-55. doi: 10.1134/S096554411001007X
14. [14]
  LI J Z, ZHAO J T, ZHANG L X, DAI X, FANG Y T. Predicting the vanadium speciation during petroleum coke combustion by thermodynamic equilibrium calculation[J]. J Therm Anal Calorim, :1-9.
15. [15]
  LEE J D. Concise Inorganic Chemistry[M]. Oxford:Blackwell Science Ltd. 1998, 979.
16. [16]
  BUNT J R, WAANDERS F B. Trace element behaviour in the Sasol-Lurgi fixed-bed dry-bottom gasifier. Part 2-The semi-volatile elements:Cu, Mo, Ni and Zn[J]. Fuel, 2009,88(6):961-969. doi: 10.1016/j.fuel.2008.10.041
1. [1]
  Jia-He Li , Yu-Ze Liu , Jia-Hui Ma , Qing-Xiao Tong , Jian-Ji Zhong , Jing-Xin Jian . 洛芬碱衍生物的合成、化学发光与重金属离子检测. University Chemistry, 2025, 40(6): 230-237. doi: 10.12461/PKU.DXHX202407080
2. [2]
  Houzhen Xiao , Mingyu Wang , Yong Liu , Bangsheng Lao , Lingbin Lu , Minghuai Yu . Course Ideological and Political Design of Combustion Heat Measurement Experiment. University Chemistry, 2024, 39(2): 7-13. doi: 10.3866/PKU.DXHX202310011
3. [3]
  Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013
4. [4]
  Yun Chen , Daijie Deng , Li Xu , Xingwang Zhu , Henan Li , Chengming Sun . Covalent bond modulation of charge transfer for sensitive heavy metal ion analysis in a self-powered electrochemical sensing platform. Acta Physico-Chimica Sinica, 2026, 42(1): 100144-0. doi: 10.1016/j.actphy.2025.100144
5. [5]
  Junlin Ma , Enze Wang , Haixia Wu . 柔性电化学传感器的制备及其在重金属离子现场便携检测中的应用. University Chemistry, 2026, 41(5): 455-468. doi: 10.12461/PKU.DXHX202509102
6. [6]
  Shuyong Zhang , Yaxian Zhu , Wenqing Zhang , Yuzhi Wang , Jing Lu . Ideological and Political Design of Combustion Heat Measurement Experiment: Determination of Heat Value of Agricultural and Forestry Wastes. University Chemistry, 2024, 39(2): 1-6. doi: 10.3866/PKU.DXHX202303026
7. [7]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . High-Stable Aqueous Zinc Metal Anodes Enabled by an Oriented ZnQ Zeolite Protective Layer with Facile Ion Migration Kinetics. Acta Physico-Chimica Sinica, 2025, 41(1): 100003-0. doi: 10.3866/PKU.WHXB202309003
8. [8]
  Zijun Huang , Feng Wu , Shaofeng Pi , Saijin Huang , Zhengjun Fang . Knowledge Graph-based Development of AI Curriculum for Inorganic Chemistry Experiments and Exploration of New Teaching Paradigm. University Chemistry, 2025, 40(9): 228-237. doi: 10.12461/PKU.DXHX202504052
9. [9]
  Huan Zhang , Guoqing Zhong , Qiying Jiang , Wenyuan Hu , Dingming Yang , Juan shen , Yatang Dai , Hongbo Li . Development and Practice of the “Five Rings and One Heart” Teaching Model in Inorganic Chemistry. University Chemistry, 2025, 40(11): 42-51. doi: 10.12461/PKU.DXHX202412076
10. [10]
  Zi Wang , Zhihua Peng , Longli Zhang , Linhua Song , Da Yang , Cuiyu Jiang . Exploration and Practice of Ideological and Political Education in Organic Chemistry Curriculum Integrated with Petroleum Industry Characteristics. University Chemistry, 2026, 41(4): 104-111. doi: 10.12461/PKU.DXHX202502086
11. [11]
  Xinlong XU , Chunxue JING , Yuzhen CHEN . Bimetallic MOF-74 and derivatives: Fabrication and efficient electrocatalytic biomass conversion. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1545-1554. doi: 10.11862/CJIC.20250046
12. [12]
  Wenjuan SHI , Yuke LU , Xiuyuan LI , Lei HOU , Yaoyu WANG . Mg(Ⅱ) metal-organic frameworks based on biphenyltetracarboxylic acid: Synthesis and CO₂ adsorption and catalytic conversion performance. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2455-2463. doi: 10.11862/CJIC.20250220
13. [13]
  Xiaomin Kang , Chuanbao Jiao . Application of Metal-Organic Frameworks in CO₂ Catalytic Conversion: Promoting “Double Carbon” Actions for a Beautiful China. University Chemistry, 2026, 41(2): 208-217. doi: 10.12461/PKU.DXHX202503011
14. [14]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
15. [15]
  Lin Wang , Xiaozhou Li , Haishuang Zhao , Yutang Wang , Jianguo Wang , Junru Wang . Design and Practice of New-Form Course Resources for Physical Chemistry in Agricultural and Forestry Universities: A Case Study of Teaching in Food Science and Engineering Major. University Chemistry, 2026, 41(2): 146-153. doi: 10.12461/PKU.DXHX202412149
16. [16]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
17. [17]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . Designing thermodynamically stable noble metal single-atom photocatalysts for highly efficient non-oxidative conversion of ethanol into high-purity hydrogen and value-added acetaldehyde. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-0. doi: 10.1016/j.actphy.2025.100067
18. [18]
  Ping Song , Nan Zhang , Jie Wang , Rui Yan , Zhiqiang Wang , Yingxue Jin . Experimental Teaching Design on Synthesis and Antitumor Activity Study of Cu-Pyropheophorbide-a Methyl Ester. University Chemistry, 2024, 39(6): 278-286. doi: 10.3866/PKU.DXHX202310087
19. [19]
  Pingping Zhu , Yongjun Xie , Yuanping Yi , Yu Huang , Qiang Zhou , Shiyan Xiao , Haiyang Yang , Pingsheng He . Excavation and Extraction of Ideological and Political Elements for the Virtual Simulation Experiments at Molecular Level: Taking the Project “the Simulation and Computation of Conformation, Morphology and Dimensions of Polymer Chains” as an Example. University Chemistry, 2024, 39(2): 83-88. doi: 10.3866/PKU.DXHX202309063
20. [20]
  Dongqi Cai , Fuping Tian , Zerui Zhao , Yanjuan Zhang , Yue Dai , Feifei Huang , Yu Wang . Exploration of Factors Influencing the Determination of Ion Migration Number by Hittorf Method. University Chemistry, 2024, 39(4): 94-99. doi: 10.3866/PKU.DXHX202310031

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(5780)
HTML views(2412)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142