Citation: LI Di, LI Pan, WANG Xian-hua, SHAO Jing-ai, YANG Hai-ping, CHEN Han-ping. Experimental study on bio-oil from catalytic pyrolysis on Fe modified HZSM-5[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(5): 540-547. shu

Experimental study on bio-oil from catalytic pyrolysis on Fe modified HZSM-5

State Key Laboratory of Coal Combustion, China-EU Institute for Clean and Renewable Energy, Huazhong University of Science and Technology, Wuhan 430074, China

Corresponding author: WANG Xian-hua, wangxianhua@hust.edu.cn
Received Date: 10 November 2015
Revised Date: 29 January 2016

Fund Project: Special Fund for Agro-Scientific Research in the Public Interest 201303095the Major State Basic Research Development Program of China 973 programthe National Natural Science Foundation of China 51376075the Major State Basic Research Development Program of China 973 program, 2013CB228102

Figures(6)

The 2% Fe modified HZSM-5 zeolite catalysts were prepared by ion-exchange and characterized by laser particle size analyzer, specific surface area and pore size analyzer, and X-ray diffraction (XRD) to investigate the pore and surface properties. The catalytic pyrolysis of wood was carried out at 550 ℃ to get the maximum oil yield. After pyrolysis, the bio-oil was separated to the lighter (upper layer) and heavier component (bottom layer). The results indicate that with Fe modified HZSM-5 catalysts, the bio-oil yield increases significantly (maximum 7%) the same as that of the lighter one, while the heavier one is nearly constant. Ketones and furans in the lighter oil decreases, while acids and phenols increase significantly; in the heavier oil, ketones and furans decreased dramatically, phenols and naphthalenes increase significantly. The Fe modified HZSM-5 catalysts play an important role in pyrolysis of wood dusts, and have a critical influence on oil yield because the modified catalysts promote the shape-selective modifying of the initial pyrolysis steam and inhibit the secondary coking reaction of steam. The product tends to much lighter bio-oil component and lower oxygen content.
- Fe modified,
- HZSM-5,
- catalytic pyrolysis,
- bio-oil
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