Citation: CHEN Ran, LIU Jie, ZHANG Xiang-wen. Enhancement of thermal oxidation stability of endothermic hydrocarbon fuels by using oxygen scavengers[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(2): 249-256. shu

Enhancement of thermal oxidation stability of endothermic hydrocarbon fuels by using oxygen scavengers

CHEN Ran ¹ ,
LIU Jie ^1,2,, ,
ZHANG Xiang-wen ^1,2,,

1.
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
2.
Key Laboratory for Advanced Fuel and Chemical Propellant of Ministry of Education, Tianjin 300072, China

Corresponding author: LIU Jie, jie.liu@tju.edu.cn ZHANG Xiang-wen, zhangxiangwen@tju.edu.cn
Received Date: 16 October 2019
Revised Date: 21 December 2019

Fund Project: the National Natural Science Foundation of China 21476168The project was supported by the National Natural Science Foundation of China (21476168)

Figures(7)

Thermal oxidation stability is one of the important properties for evaluating fuel quality during the storage and use of endothermic hydrocarbon fuels; it reflects the extent to which jet fuel is affected by dissolved oxygen below 260℃ and the depth of oxidation reaction. In this work, the basic properties and thermal stability of endothermic hydrocarbon fuels with oxygen scavengers were evaluated by accelerated oxidation method combined with titration, infrared spectroscopy, particle size distribution and JFTOT. The effect of three oxygen scavengers, viz., triphenylphosphine (TPP), dicyclohexylphenylphosphine (DCP) and 1, 2, 5-trimethylpyrrole (TMP), on the auto-oxidation process of endothermic hydrocarbon fuels were comparatively investigated and the optimal addition amount within the test range was determined. The results show that there is no significant change in the fuel composition and basic physical properties after the addition of oxygen scavengers. The dissolved oxygen concentration in the fuel decreases with the increase of the amount of oxygen scavengers, and the maximum drop is 31.95 mg/m³. The peroxide value and acid value of the samples show different degrees of decline after accelerated oxidation, and the particle size distribution of the micelles tends to be smaller. The JFTOT test results can meet the national standards. In general, the addition of oxygen scavenger can effectively improve the thermal oxidation stability of the fuel; the effect of three oxygen scavengers follows the order of TMP >TPP ≈ DCP and the optimal addition amount is 1.5×10^-5 (by mass fraction).
- oxygen scavenger,
- endothermic hydrocarbon fuels,
- thermal oxidation stability,
- deoxygenation
1. [1]
  BABOK K K. Jet Fuel and Rocket Fuel[M]. ZHANG Pu et al, translation. Beijing: China Industry Press, 1965.
2. [2]
  TAYLOR W F. Jet Fuel Thermal Stability[Z]. USA: NASA, 1979.
3. [3]
  DENNSOV E T, KOVALEV G I. Oxidation & Antioxidation of Jet Fuel[M]. CHANG Ru-ji translation. Beijing: Hydrocarbon Processing Press, 1987.
4. [4]
  FAN Qi-ming, MI Zhen-tao, ZHANG Xiang-wen, YU Yan. Progress in research of improving thermal stability of aviation fuels[J]. Petrochem Technol Appl, 2002,20(4):261-263. doi: 10.3969/j.issn.1009-0045.2002.04.014
5. [5]
  ROAN M A, BOEHMAN A L. The effect of fuel composition and dissolved oxygen on deposit formation from potential JP-900 basestocks[J]. Energy Fuels, 2004,18(3):835-843.
6. [6]
  ZABARNICK S. Chemical kinetic modeling of jet fuel autoxidation and antioxidant chemistry[J]. Ind Eng Chem Res, 1993,32(6):1012-1017. doi: 10.1021/ie00018a003
7. [7]
  ALBORZI E, GADSBY P, ISMAIL M S, SHEIKHANSARI A, DWYER M R, MEIJER A J, BLAKEY S G, POURKASHANIAN M. Comparative study of the effect of fuel deoxygenation and polar species removal on jet fuel surface deposition[J]. Energy Fuels, 2019,33(3):1825-1836.
8. [8]
  WANG Chen-chen, PENG Xiao-tian, WANG Su-ming, LIU Wei-hua, FENG Shi-yu. Summarization of the effect of dissolved oxygen content on fuel coking[J]. J Civil Avia Flight Univ Chin, 2018,29(5):19-22+27. doi: 10.3969/j.issn.1009-4288.2018.05.005
9. [9]
  BEAVER B D. Development of oxygen scavenger additives for jet fuels[D]. Pittsburgh: Duquesne University, 1993.
10. [10]
  BEAVER B D, DEMUNSHI R, HENEGHAN S P, WHITACRE S D, NETA P. Model studies directed at the development of new thermal oxidative stability enhancing additives for future jet fuels[J]. Energy Fuels, 1997,11(2):396-401.
11. [11]
  BEAVER B D, GAO L, FEDAK M G, COLEMAN M M, SOBKOWIAK M. Model studies examining the use of dicyclohexylphenylphosphine to enhance the oxidative and thermal stability of future jet fuels[J]. Energy Fuels, 2002,16(5):1134-1140.
12. [12]
  BEAVER B D, TENG Y, GUIRIEC P, HAPIOT P, NETA P. Mechanisms of oxidation of 1, 2, 5-trimethylpyrrole:Kinetic, spectroscopic, and electrochemical studies[J]. J Phys Chem A, 1998,102(30):6121-6128.
13. [13]
  THAVASI V, BETTENS R P A, LEONG L P. Temperature and solvent effects on radical scavenging ability of phenols[J]. J Phys Chem A, 2009,113(13):3068-3077.
14. [14]
  MACLEAN P D, CHAPMAN E E, DOBROWOLSKI S L, THOMPSON A, BARCLAY L R C. Pyrroles as antioxidants:Solvent effects and the nature of the attacking radical on antioxidant activities and mechanisms of pyrroles, dipyrrinones, and bile pigments[J]. J Org Chem, 2008,73(17):6623-6635. doi: 10.1021/jo8005073
15. [15]
  IUGA C, URIBE S O, MIRANDA L D, VIVIER BUNGE A. Selectivity in radical alkylation of substituted pyrroles[J]. Int J Quantum Chem, 2010,110(3):697-705.
16. [16]
  GB/T-6537-2018, No.3 jet fuel[S].
17. [17]
  GB/T-1884-2000, Crude petroleum and liquid petroleum products-Laboratory determination of density-Hydrometer method[S].
18. [18]
  GB/T-384-1981, Determination of calorific value of petroleum products[S].
19. [19]
  GB/T-2429-1988, Aviation fuels-Calculation of net heat of combustion[S].
20. [20]
  GB/T-3536-2008, Petroleum products-Determination of flash and fire points-Cleveland open cup method[S].
21. [21]
  GB/T-265-1988, Petroleum products-Determination of kinematic viscosity and calculation of dynamic viscosity[S].
22. [22]
  GB/T 601-2016, Chemical reagent-Preparations of reference titration solutions[S].
23. [23]
  SH/T 0176-1992, Standard test method for hydroperoxide number of aviation turbine fuels, gasoline and diesel fuels[S].
24. [24]
  GB/T 12574—1990, Jet fuels-Determination of total acid number[S].
25. [25]
  GB/T-9169-2010, Standard test method for thermal oxidation stability of aviation turbine fuels.JFTOT procedure[S].
26. [26]
  GB/T-3555-1992, Petroleum products-Determination of Saybolt color-Saybolt chromometer method[S].
27. [27]
  SH/T-0174-2015, Petroleum products and hydrocarbon solvents-Detection of thiols and other sulfur species-Doctor test[S].
28. [28]
  ZHAO L, ZHANG X, PAN L, LIU J. Storage period prediction and metal compatibility of endothermic hydrocarbon fuels[J]. Fuel, 2018,233:1-9. doi: 10.1016/j.fuel.2018.06.034
29. [29]
  MIL-T-5624P, Military specification: Turbine fuel, aviation, grades JP-4, JP-5, and JP-5 / JP-8[S].
30. [30]
  ERVIN J, HENEGHAN S, MARTEL C, WILLIAMS T. Surface effects on deposits from jet fuels[J]. J Eng Gas Turb Power, 1996,118(2):278-285. doi: 10.1115/1.2816589
31. [31]
  BEAVER B D, CLIFFORD C B, FEDAK M G, GAO L, IYER P S, SOBKOWIAK M. High heat sink jet fuels. Part 1. Development of potential oxidative and pyrolytic additives for JP-8[J]. Energy Fuels, 2006,20(4):1639-1646.
32. [32]
  MASNOVI J, KOCHI J. Direct observation of ion-pair dynamics[J]. J Am Chem Soc, 1985,107(26):7880-7893.
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