Citation: YUAN Xin-hua, TANG Guo-xu, ZHANG Li-qiang, ZHU Xi-feng. Separating phenols from different fractions of bio-oil by precipitation of Ba²⁺[J]. Journal of Fuel Chemistry and Technology, ;2019, 47(1): 53-59. shu

Separating phenols from different fractions of bio-oil by precipitation of Ba²⁺

School of Engineering Science, University of Science and Technology of China, Hefei 230026, China

Corresponding author: ZHU Xi-feng, xfzhu@ustc.edu.cn
Received Date: 11 October 2018
Revised Date: 19 November 2018

Fund Project: the National Natural Science Foundation of China 51676179The project was supported by the National Natural Science Foundation of China (51676179)

Figures(6)

The phenolic substances in the bio-oil fractions collected at different temperature intervals were extracted by barium ion precipitation method at different concentrations of NaOH reagent, reaction temperatures and reaction times, and the extraction effect was analyzed by GC-MS. The results show that the effect of barium ion precipitation on guaiacols separation is more outstanding. The temperature (30-50℃), concentration of NaOH (1.0-6.0 mol/L) and reaction time (10-40 min) have great influence on the extraction rate of guaiacols. The optimum reaction parameters include the NaOH solution of 5.5 mol/L, the temperature of 35℃ and the reaction time of 20 min. Under the optimum condition, the extraction rate of guaiacols in the three fractions of low temperature water, low temperature oil and high temperature are 34.1%, 33.8% and 33.5%, respectively.
- bio-oil,
- bio-oil fraction,
- phenol,
- barium ion precipitation method,
- recycling
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Separating phenols from different fractions of bio-oil by precipitation of Ba2+

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通讯作者: 陈斌, bchen63@163.com

Separating phenols from different fractions of bio-oil by precipitation of Ba²⁺