Citation: Wang Minghao, Chen Mingsen, Xu Guofeng, Wu Si. Photoinduced Reversible Solid-to-liquid Transitions of Azopolymers[J]. Chemistry, ;2020, 83(7): 600-609, 587. shu

Photoinduced Reversible Solid-to-liquid Transitions of Azopolymers

Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Soft Matter Chemistry, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, 230026

Corresponding author: Xu Guofeng, gfxu@ustc.edu.cn Wu Si, siwu@ustc.edu.cn
Received Date: 10 February 2020
Accepted Date: 9 March 2020

Figures(14)

Azobenzene compounds are very attractive and commonly used photoresponsive materials. This minireview mainly introduced the photoresponsive property of azobenzene. The syntheses and the mechanisms of photoinduced reversible solid-to-liquid transitions of some azobenzene-containing polymers (azopolymers) were further introduced. The potential applications of azopolymers based on photoinduced reversible solid-to-liquid transitions were also presented, such as adhesive materials, photoactuators, photothermally conductive switching devices and non-thermal nanoimprinting.
- Azobenzene,
- Azopolymer,
- Photoinduced solid-to-liquid transition
1. [1]
  Hartley G. Nature, 1937, 140(3537):281.
2. [2]
  Sun S, Liang S, Xu W, et al. Polym. Chem., 2019, 10(32):4389~4401.
3. [3]
  Izumi A, Nomura R, Masuda T. Macromolecules, 2001, 34(13):4342~4347.
4. [4]
  Schmidt H W. Angew. Chem. Int. Ed., 1989, 28(7):940~946.
5. [5]
  Ikeda T, Tsutsumi O. Science, 1995, 268(5219):1873~1875.
6. [6]
  Akiyama H, Yoshida M. Adv. Mater., 2012, 24(17):2353~2356.
7. [7]
  Zhou H, Xue C, Weis P, et al. Nat. Chem., 2017, 9(2):145~151.
8. [8]
  Chen M, Yao B, Kappl M, et al. Adv. Funct. Mater., 2020, 30(4):1906752.
9. [9]
  Zhou Y, Chen M S, Ban Q F, et al. ACS Macro Lett., 2019,8(8):968~972.
10. [10]
  Weis P, Hess A, Kircher G, et al. Chem. Eur. J., 2019, 25(46):10946~10953.
11. [11]
  Tian Y, Watanabe K, Kong X, et al. Macromolecules, 2002, 35(9):3739~3747.
12. [12]
  Zhao Y, Qi B, Tong X, et al. Macromolecules, 2008, 41(11):3823~3831.
13. [13]
  Ravi P, Sin S L, Gan L H, et al. Polymer, 2005, 46(1):137~146.
14. [14]
  Ito S, Yamashita A, Akiyama H, et al. Macromolecules, 2018, 51(9):3243~3253.
15. [15]
  Ito S, Akiyama H, Mori M, et al. Chem. Phys., 2019, 220(12):1900105.
16. [16]
  Bandara H M D, Burdette S C. Chem. Soc. Rev., 2012, 41(5):1809~1825.
17. [17]
  Akiyama H, Fukata T, Yamashita A, et al. J. Adhes., 2017, 93(10):823~830.
18. [18]
  Weis P, Hess A, Kircher G, et al. Chem. Eur. J., 2019, 25(46):10946~10953.
19. [19]
  Ito S, Akiyama H, Sekizawa R, et al. ACS Appl. Mater. Interf., 2018, 10(38):32649~32658.
20. [20]
  S Ito, H Akiyama, R Sekizawa et al. Polym. Chem., 2019, 57(7):806~813.
21. [21]
  Wool R P. Macromolecules, 1993, 26(7):1564~1569.
22. [22]
  Xu W, Sun S, Wu S. Angew. Chem. Int. Ed., 2019, 58(29):9712~9740.
23. [23]
  Cui J, Drotlef D M, Larraza I, et al. Adv. Mater., 2012, 24(34):4601~4604.
24. [24]
  (a) Wu Z L, Buguin A, Yang H, et al. Adv. Funct. Mater., 2013, 23(24):3070~3076; (b) Kizilkan E, Strueben J, Staubitz A, et al. Sci. Robot., 2017, 2(2):eaak9454; (c) Liu D, Broer D J. Angew. Chem. Int. Ed., 2014, 53(18):4542~4546; (d) Yang R, Zhao Y. Angew. Chem. Int. Ed., 2017, 56(45):14202~14206.
25. [25]
  Yang B, Cai F, Huang S, et al. Angew. Chem. Int. Ed., 2020, 59(10):4035~4042.
26. [26]
  Shin J, Sung J, Kang M, et al. PNAS, 2019, 116(13):5973~5978.
1. [1]
  Wen-Bing Hu . Systematic Introduction of Polymer Chain Structures. University Chemistry, 2025, 40(4): 15-19. doi: 10.3866/PKU.DXHX202401014
2. [2]
  Yuhui Yang , Jintian Luo , Biao Zuo . A Teaching Approach to Polymer Surface and Interface in Undergraduate Polymer Physics Courses. University Chemistry, 2025, 40(4): 126-130. doi: 10.12461/PKU.DXHX202408056
3. [3]
  Laiying Zhang , Yinghuan Wu , Yazi Yu , Yecheng Xu , Haojie Zhang , Weitai Wu . Innovation and Practice of Polymer Chemistry Experiment Teaching for Non-Polymer Major Students of Chemistry: Taking the Synthesis, Solution Property, Optical Performance and Application of Thermo-Sensitive Polymers as an Example. University Chemistry, 2024, 39(4): 213-220. doi: 10.3866/PKU.DXHX202310126
4. [4]
  Wenbing Hu , Jin Zhu . Flipped Classroom Approach in Teaching Professional English Reading and Writing to Polymer Graduates. University Chemistry, 2024, 39(6): 128-131. doi: 10.3866/PKU.DXHX202310015
5. [5]
  Pingsheng He , Haiyang Yang , Pingping Zhu . Philosophical Reflections in Polymer Physics Course: Emphasizing Reverse Thinking. University Chemistry, 2025, 40(4): 27-32. doi: 10.3866/PKU.DXHX202403029
6. [6]
  Rui Xu , Wei Li , Tianyi Li . Exploration of Teaching Reform in the Course of “Principles of Chemical Engineering” in the Polymer Materials and Engineering Major. University Chemistry, 2025, 40(4): 54-58. doi: 10.12461/PKU.DXHX202404081
7. [7]
  Chunyang Bao , Ruoxuan Miao , Yuhan Ding , Qingfu Ban , Yusheng Qin , Jie Liu , Zhirong Xin . The Comprehensive Experiment Design of Preparation of Depolymerizable Thermosetting Polymers. University Chemistry, 2025, 40(4): 59-65. doi: 10.12461/PKU.DXHX202405087
8. [8]
  Hujun Qian , Rui Shi , Guanglu Wu , Xuanbo Zhu . A Preliminary Study on the Development of a Virtual Simulation Platform for Polymer Physics Teaching and Its Teaching Practice. University Chemistry, 2025, 40(4): 147-153. doi: 10.12461/PKU.DXHX202409009
9. [9]
  Jiashuang Lu , Xiaoyang Xu , Youqing He , Mingyue Wu , Ruixin Shi , Wenfang Yu , Hang Lu , Ji Liu , Qingzeng Zhu . 生命健康中的有机硅高分子. University Chemistry, 2025, 40(8): 169-180. doi: 10.12461/PKU.DXHX202409143
10. [10]
  Pingping Zhu , Qiang Zhou , Yu Huang , Haiyang Yang , Pingsheng He , Shiyan Xiao . Design and Practice of Ideological and Political Cases in the Course of Polymer Physics Experiments: Molecular Weight Determination of Polymers by Dilute Solution Viscosity Method as an Example. University Chemistry, 2025, 40(4): 94-99. doi: 10.12461/PKU.DXHX202405170
11. [11]
  Yi Li . Exploring the New Teaching Mode of the General Education of Polymer Science by Integrating Aesthetics, Ideological and Political Ideas: Teaching Practice of the General Education Course “Appreciation of Aesthetics in the Polymer World”. University Chemistry, 2025, 40(4): 20-26. doi: 10.12461/PKU.DXHX202402031
12. [12]
  Kai Yang , Gehua Bi , Yong Zhang , Delin Jin , Ziwei Xu , Qian Wang , Lingbao Xing . Comprehensive Polymer Chemistry Experiment Design: Preparation and Characterization of Rigid Polyurethane Foam Materials. University Chemistry, 2024, 39(4): 206-212. doi: 10.3866/PKU.DXHX202308045
13. [13]
  Chengyi Xiao , Xiaoli Sun , Chen Zhang , Weiwei Li . An In-Depth Analysis of the Scientific Connotations, Testing Methods, and Applications of Free Volume in Polymer Physics. University Chemistry, 2025, 40(4): 33-45. doi: 10.12461/PKU.DXHX202403069
14. [14]
  Lilong Gao , Yuhao Zhai , Dongdong Zhang , Linjun Huang , Kunyan Sui . Exploration of Thiol-Ene Click Polymerization in Polymer Chemistry Experiment Teaching. University Chemistry, 2025, 40(4): 87-93. doi: 10.12461/PKU.DXHX202405143
15. [15]
  Jiamin Zhang , Zhen Fan , Jianzhong Du . Integrated Teaching Method Combining Domestic and International Perspectives: A Case Study on Cultivating Innovative Talents in Polymeric Biomaterials. University Chemistry, 2025, 40(7): 156-160. doi: 10.12461/PKU.DXHX202409131
16. [16]
  Lijun Huo , Mingcun Wang , Tianyi Zhao , Mingjie Liu . Exploration of Undergraduate and Graduate Integrated Teaching in Polymer Chemistry with Aerospace Characteristics. University Chemistry, 2024, 39(6): 103-111. doi: 10.3866/PKU.DXHX202312059
17. [17]
  Feng Zheng , Ruxun Yuan , Xiaogang Wang . “Research-Oriented” Comprehensive Experimental Design in Polymer Chemistry: the Case of Polyimide Aerogels. University Chemistry, 2024, 39(10): 210-218. doi: 10.12461/PKU.DXHX202404027
18. [18]
  Qi Wang , Yicong Gao , Feng Lu , Quli Fan . Preparation and Performance Characterization of the Second Near-Infrared Phototheranostic Probe: A New Design and Teaching Practice of Polymer Chemistry Comprehensive Experiment. University Chemistry, 2024, 39(11): 342-349. doi: 10.12461/PKU.DXHX202404141
19. [19]
  Wenjun Yang , Qiaoling Tan , Wenjiao Xie , Xiaoyu Pan , Youyong Yuan . Construction and Characterization of Calcium Alginate Microparticle Drug Delivery System: A Novel Design and Teaching Practice in Polymer Experiments. University Chemistry, 2025, 40(3): 371-380. doi: 10.12461/PKU.DXHX202405150
20. [20]
  Bei Liu , Heng Li , Mei Yang , Yijiang Liu . Teaching Reform and Exploration in Polymer Chemistry with an “Experiment-Intensified” Approach for Masters in Materials and Chemical Engineering. University Chemistry, 2025, 40(4): 10-14. doi: 10.3866/PKU.DXHX202401010

Get Citation

PDF

XML

Metrics

PDF Downloads(83)
Abstract views(2515)
HTML views(1130)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142