Citation: SONG Mei-Yue, HUANG Yuan-Yuan, ZHANG Xin, YAO Yuan-Gen. Synthesis, Structure and Luminescent Property of a New bnn-type Zn(Ⅱ) Coordination Polymer[J]. Chinese Journal of Structural Chemistry, ;2014, 33(8): 1222-1226. shu

Synthesis, Structure and Luminescent Property of a New bnn-type Zn(Ⅱ) Coordination Polymer

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a. Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
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b. University of Chinese Academy of Sciences, Beijing 100039, China

Corresponding author: YAO Yuan-Gen,
Received Date: 12 February 2014
Available Online: 3 April 2014
Fund Project: This work was supported by the 973 Program of China (2011CBA00505) (2011CBA00505) National Key Technology R&D Program (2012BAE06B08) (2012BAE06B08) the Chinese Academy of Sciences (KJCX2-YW-H30) (KJCX2-YW-H30)the Science Foundation of Fujian Province (2009HZ0005-1) (2009HZ0005-1)

A new Zn(Ⅱ) coordination polymer, namely [Zn(Htci)(bib)_0.5(H₂O)]_n·nH₂O (1, H₃tci=tri(2-carboxyethyl)isocyanurate, bib=1,4-bis(imidazol-1-ylmethyl)-butane) has been synthesized by combining H₃tci and bib ligands with Zn(Ⅱ) salts under solvothermal conditions. The title compound crystallizes in monoclinic, space group P2₁/c with a=13.3424(7), b=7.9051(5), c=20.4650(12) Å, β=101.935(5)°, V=2111.8(2) Å³, C₁₇H₂₄N₅O₁₁Zn, M_r=539.8, Z=4, D_c=1.698 g/cm³, F(000)=1116, μ=1.236 mm^-1, the final R=0.0398 and wR=0.00879 for 3722 observed reflections (I>2σ(I)). X-ray structural analysis reveals that compound 1 exhibits a three-dimensional (3D) pillar-layered framework, and can be simplified into a 5-connected bnn topological network. Moreover, the luminescent properties for compound 1 were also studied at room temperature.
- Zn(Ⅱ) compound,
- solvothermal synthesis,
- pillar-layered framework,
- luminescence
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