Citation: YANG Qin-Huan, XIE Bin, ZOU Li-Ke, HE Lin-Xin, WANG Jun, LI Yu-Long, WU Yu. Syntheses, Characterizations, and Crystal Structures of Two Binuclear Silver Complexes Based on O,O'-Dialkyldithiophosphate and 1,10-Phenanthroline[J]. Chinese Journal of Structural Chemistry, ;2014, 33(8): 1215-1221. shu

Syntheses, Characterizations, and Crystal Structures of Two Binuclear Silver Complexes Based on O,O'-Dialkyldithiophosphate and 1,10-Phenanthroline

1.
College of Materials and Chemical Engineering, Institute of Functional Materials, University Key Laboratory of Green Chemistry of Sichuan Institutes of Higher Education, Sichuan University of Science & Engineering, Zigong 643000, China

Corresponding author: XIE Bin,
Received Date: 30 April 2014
Available Online: 21 July 2014
Fund Project: The work was supported by the project of Science & Technology Department of Sichuan Province (2011JY0052, 2012JY0115) (2011JY0052, 2012JY0115) Sichuan University of Science & Engineering (2012PY04, 2012PY14, 2012KY12) (2012PY04, 2012PY14, 2012KY12)

Two binuclear silver complexes, [Ag₂{μ-S₂P(OCH₂Ph)₂}₂(phen)₂] (1) and [Ag₂{μ-S₂P(OCH₂CH₂Ph)₂}₂(phen)₂] (2), were synthesized and characterized by elemental analysis, infrared spectrum, thermo-gravimetric analysis and X-ray single-crystal diffraction. Complex 1 crystallizes in the triclinic system, space group P1 with a=9.7881(4), b=10.7726(4), c=13.1952(6) Å, α=103.686(4), β=99.477(3), γ=107.494(4)°, V=1246.88(9) Å³, D_c=1.591 g·m^-3 and Z=1; Complex 2 is of monoclinic system, space group P2₁/n with a=10.6014(8), b=24.3969(15), c=11.5353(10) Å, β=14.125(10)°, V=2722.9(4) Å³, D_c=1.526 g·m^-3 and Z=2. In the molecules of 1 and 2, O,O'-dialkyldithiophosphate anions, (PhCH₂O)PS₂^- and (PhCH₂CH₂O)PS₂^- act as bridging ligands and connect two Ag(I) centers into a binuclear unit with Ag₂S₄P₂ eight-membered rings in "chair" conformations. In both crystal structures, face-to-face π-π stacking interactions between the adjacent paralleling aromatic rings of 1,10-phenanthroline play a prominent role in the crystal packing and result in a 1D chain. And such 1D chains are further linked into 3D networks by weak intermolecular C-H…π interactions for 1.
- binuclear silver complex,
- O,O'-dialkyldithiophosphate,
- crystal structure
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