Citation: HUANG Yong-Qing, WAN Yi, CHENG Hai-Di, ZHAO Yue. Syntheses and Crystal Structures of Two New Ag(Ⅰ) Complexes with Betaine Derivative: Structure Changes via Metal-to-ligand Ratio[J]. Chinese Journal of Structural Chemistry, ;2014, 33(6): 928-934. shu

Syntheses and Crystal Structures of Two New Ag(Ⅰ) Complexes with Betaine Derivative: Structure Changes via Metal-to-ligand Ratio

a.
a. College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, China;
b.
b. Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, China

Received Date: 11 November 2013
Available Online: 5 March 2014
Fund Project: This work was financially supported by the National Natural Science Foundation of China (No. 21201111) (No. 21201111)

Two new Ag(Ⅰ) complexes {Ag₂(L)(NO₃)(H₂O)}_n (1) and {Ag(L)}_n·nH₂O (2) have been synthesized via the reaction of silver nitrate and betaine derivative 1-carboxymethylpyridinium^-3-carboxylate (L) by only changing the metal-to-ligand ratio. The results of X-ray crystallographic analysis indicate that complexes 1 and 2 both crystallize in the monoclinic space group P2₁/c with a=5.0809(14), b=17.390(5), c=13.399(4)Å, β=91.677(5)°, V=1183.4(6)Å³, Z=4, M_r=475.90, D_c=2.671 g/cm³, F(000)=912, μ=3.352 mm^-1, S=1.259, the final R=0.0320 and wR=0.0831 for 2036 observed reflections with I>2σ(I) for 1 and a=12.180(2), b=5.0283(10), c=14.396(3)Å, β=94.87(3)°, V=878.5(3)Å³, Z=4, M_r=306.02, D_c=2.314 g/cm³, F(000)=600, μ=2.294 mm^-1, S=1.053, the final R=0.0283 and wR=0.0684 for 2011 observed reflections with I>2σ(I) for 2. Complexes 1 and 2 both feature a unique 2D structure. For 1, the 2D undulated network consists of 1D infinite helical chains running parallel to the b axis, while for 2, the 2D network is made up of 1D tubes along the b axis. Moreover, the Ag…Ag interactions in complexes 1 and 2 are also discussed.
- silver(Ⅰ),
- coordination polymer,
- crystal structure,
- betaine derivative
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