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Citation: TANG Guo-Dong, ZHANG Jin-Fang, SONG Ying-Lin, ZHANG Chi, LU Lu-De. Structure and Nonlinear Optical Property of the Cluster Compound V₂S₆O₂Cu₆(3-MePy)₆[J]. Chinese Journal of Structural Chemistry, ;2014, 33(6): 921-927. shu

Structure and Nonlinear Optical Property of the Cluster Compound V₂S₆O₂Cu₆(3-MePy)₆

TANG Guo-Dong ^a,b,, ,
ZHANG Jin-Fang ^b,c ,
SONG Ying-Lin ^d ,
ZHANG Chi ^b,c,, ,
LU Lu-De ^b

a.
a. Jiangsu Key Laboratory for Chemistry of Low-dimensional Materials, School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huaian 223001, China;
b.
b. Material Chemistry Laboratory, Nanjing University of Science and Technology, Nanjing 210094, China;
c.
c. Research Center for Advanced Molecular Materials, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjing 212013, China;
d.
d. School of Physical Science and Technology, Suzhou University, Suzhou 215006, China

Corresponding author: TANG Guo-Dong, ZHANG Chi,
Received Date: 22 July 2013
Available Online: 8 April 2014
Fund Project: This project was supported by Jiangsu Key Laboratory for Chemistry of Low-dimensional Materials Foundation (No. JSKC12110) (No. JSKC12110) the funds of high-grade scientific research project from Huaiyin Normal University, the National Science Foundation of Educational Commission of Jiangsu Province (No.12KJA150004) (No.12KJA150004)

A cluster compound V₂S₆O₂Cu₆(3-MePy)₆ (3-MePy=3-methyl pyridine) has been synthesized by using skiving method and the crystal structure was characterized by X-ray diffraction: space group P1, Z=1, a=9.7278(4), b=10.4180(5), c=11.9230(6)Å, α=108.240(3), β=98.120(2), γ=99.500(2)°, R=0.052 and wR=0.104. The NLO properties were studied by Z-scan technique with 8 ns pulsed laser at 532 nm. The cluster exhibits strong NLO absorptive ability (α₂=1.7×10^-10 m·W^-1) and effective self-focusing performance (n₂=1.27×10^-18 m²·W^-1) in a 1.58×10^-4 mol·dm^-3 DMF solution.
- crystal structure,
- nonlinear optics,
- vanadium cluster
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