Citation: WANG Ji-Jiang, TIAN Bo-Nian, ZHAO Zhong-Min, HOU Xiang-Yang, TANG Long, ZHANG Mei-Li. Syntheses, Structures, and Properties of Two New Coordination Polymers Based on Tetracarboxylate and 2,2'-Bipyridine Mixed Ligands[J]. Chinese Journal of Structural Chemistry, ;2014, 33(6): 915-920. shu

Syntheses, Structures, and Properties of Two New Coordination Polymers Based on Tetracarboxylate and 2,2'-Bipyridine Mixed Ligands

a.
a. Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an 716000, China;
b.
b. Yan'an Middle School, Yan'an 716000, China

Corresponding author: WANG Ji-Jiang,
Received Date: 26 March 2014
Available Online: 16 May 2014
Fund Project: Supported by the National Natural Science Foundation of China (No. 21373178) (No. 21373178)the Natural Scientific Research Foundation of Shaanxi Provincial Education Office of China (No. 13JS124) (No. 13JS124)

Two new coordination polymers {[Zn₂L¹(2,2'-bpy)₂(H₂O)₂]·4H₂O}_n (1) and [Zn₂L²(2,2'-bpy)₂(H₂O)₂]_n (2) (H₄L¹=terphenyl-2,2',4,4'-tetracarboxylic acid, H₄L²=quarterphenyl-2,2',4,4'-tetracarboxylic acid, and 2,2'-bpy=2,2'-bipyridine) have been synthesized and characterized by elemental analysis, IR and X-ray single-crystal diffraction studies. Complex 1 displays 2D wavelike networks, which are further joined together through O-H…O hydrogen bonds to give a 3D supramolecular network. Complex 2 exhibits 1D ladder-like chains, and they are further joined together by π-π stacking and O-H…O hydrogen bonding interactions to form a 3D supramolecular network. The results indicate that the backbone of carboxylate ligands has significant effects on the formation and structure of the resulting functional coordination polymers. Additionally, thermal stability and photoluminescent properties of 1 and 2 are also investigated in detail.
- Zn(Ⅱ),
- syntheses,
- crystal structure,
- photoluminescent properties
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