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Citation: OU Guang-Chuan, HUANG Zhong-Wen, PAN Ze-Yi, ZHOU Dong-Lai, YUAN Xian-You. Synthesis and Characterization of Two Binuclear Macrocyclic Zinc(Ⅱ) Complexes by Anion Exchange[J]. Chinese Journal of Structural Chemistry, ;2014, 33(6): 903-908. shu

Synthesis and Characterization of Two Binuclear Macrocyclic Zinc(Ⅱ) Complexes by Anion Exchange

a.
a. Department of Biology and Chemistry, Hunan University of Science and Engineering, Yongzhou, Hunan 425199, China;
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b. Key Laboratory of Functional Organometallic Materials of Hunan Province College, Hengyang Normal University, Hengyang, Hunan 421008, China

Received Date: 25 October 2013
Available Online: 27 February 2014
Fund Project: National Undergraduate Training Programs for Innovation and Entrepreneurship (201310551158) (2013-191) the Key Laboratory of Functional Organometallic Materials of Hunan Province College (13K09, 13K10) (201310551158) the Program for Excellent Talents in Hunan University of Science and Engineering, the Construct Program of the Key Discipline in Hunan Province (2011-76) (13B029, 13A030) the Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province (2012-318) (13K09, 13K10)

Two macrocyclic zinc(Ⅱ) complexes {[ZnL(VO₃)₂]·0.33H₂O}_n (1) and [ZnL(H₂O)₂][Ni(CN)₄] (2) (L=5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane) have been obtained from the reactions of [ZnL](ClO₄)₂ with NH₄VO₃ and K₂[Ni(CN)₄], respectively, and structurally characterized by elemental analysis, IR, XRPD, TG and X-ray diffraction. Single-crystal X-ray diffraction analyses indicated that the Zn(Ⅱ) atom lies on an inversion center and is octahedrally coordinated by four nitrogen atoms of the tetradentate macrocyclic ligand in the equatorial plane and two oxygen atoms of [VO₄] tetrahedra in the axial positions in 1, and two oxygen atoms of two water molecules in 2. Complex 1 shows a three-dimensional structure, which is constructed by the links of [VO₃]_n^n- chains with [ZnL]²⁺, forming one-dimensional channels occupied by guest water molecules. The monomers of [ZnL(H₂O)₂]²⁺ and [Ni(CN)₄]^2- are connected through the intermolecular hydrogen bonds to form a two-dimensional sheet in complex 2.
- macrocyclic zinc(Ⅱ) complexes,
- binuclear,
- vanadium,
- anion exchange
1. [1]
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2. [2]
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3. [3]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
4. [4]
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5. [5]
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6. [6]
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7. [7]
  Shuaiwen Li , Zihui Chen , Feng Yang , Wanqing Yue . The age of vanadium-based nanozymes: Synthesis, catalytic mechanisms, regulation and biomedical applications. Chinese Chemical Letters, 2024, 35(4): 108793-. doi: 10.1016/j.cclet.2023.108793
8. [8]
  Manqi Zhao , Heting Hou , Dehua He , Huimin Liu , Shaoyuan Sun , Dezheng Li , Chao Wang , Yiming Lei . Vanadium-based catalysts for propane direct dehydrogenation to propylene: Modification strategies and research direction. Chinese Journal of Structural Chemistry, 2025, 44(11): 100709-100709. doi: 10.1016/j.cjsc.2025.100709
9. [9]
  Sumiya Akter Dristy , Md Ahasan Habib , Mehedi Hasan Joni , Md Najibullah , Rutuja Mandavkar , Shusen Lin , Jihoon Lee . Binder-free bimetallic vanadium-nickel-boride-phosphide spherical structure for highly efficient and stable industrial-level water splitting. Chinese Journal of Structural Chemistry, 2025, 44(12): 100747-100747. doi: 10.1016/j.cjsc.2025.100747
10. [10]
  Xiaofei NIU , Ke WANG , Fengyan SONG , Shuyan YU . Self-assembly of [Pd₆(L)₄]⁸⁺-type macrocyclic complexes for fluorescent sensing of HSO₃^-. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1233-1242. doi: 10.11862/CJIC.20240057
11. [11]
  Anqiu LIU , Long LIN , Dezhi ZHANG , Junyu LEI , Kefeng WANG , Wei ZHANG , Junpeng ZHUANG , Haijun HAO . Synthesis, structures, and catalytic activity of aluminum and zinc complexes chelated by 2-((2,6-dimethylphenyl)amino)ethanolate. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 791-798. doi: 10.11862/CJIC.20230424
12. [12]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
13. [13]
  Yuanyu YANG , Jianhua XUE , Yujia BAI , Lulu CUI , Dongdong YANG , Qi MA . Design, synthesis, and detection of Al³⁺ of two zinc complexes based on Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1207-1216. doi: 10.11862/CJIC.20250005
14. [14]
  Zhenghua ZHAO , Yufeng LIU , Qing ZHANG , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of zinc(Ⅱ), nickel(Ⅱ) and cadmium(Ⅱ) complexes constructed from a terphenyl-tricarboxylate ligand. Chinese Journal of Inorganic Chemistry, 2026, 42(1): 170-180. doi: 10.11862/CJIC.20250161
15. [15]
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16. [16]
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17. [17]
  Jinchen Li , Tangxin Xiao , Kai Diao , Zhouyu Wang , Leyong Wang . Supramolecular catalysis enabled by chiral molecular cages with anion-π interaction capability. Chinese Chemical Letters, 2026, 37(1): 111796-. doi: 10.1016/j.cclet.2025.111796
18. [18]
  Xinguo Mao , Shuo Zhang , Qiang Shi , Hua Cheng , Leyong Wang . Macrocyclic host molecules: Rising as a promising supramolecular material. Chinese Chemical Letters, 2025, 36(6): 110950-. doi: 10.1016/j.cclet.2025.110950
19. [19]
  Hao Chang , Renzhong Qiao , Chao Li . Recent advances in functionalized macrocyclic polyamines for medicine applications. Chinese Chemical Letters, 2025, 36(7): 110675-. doi: 10.1016/j.cclet.2024.110675
20. [20]
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