Citation: ZHENG Hu-Fei, MENG Xiang-Suo, YUAN Wei, SHI De-Qing. Synthesis and Crystal Structure of 3'-Ethyl 5'-Methyl 1-Benzyl-4'-methyl-2-oxo-3',4'-dihydrospiro-[indoline-3,2'-pyrrole]-3',5'-dicarboxylate[J]. Chinese Journal of Structural Chemistry, ;2014, 33(6): 871-875. shu

Synthesis and Crystal Structure of 3'-Ethyl 5'-Methyl 1-Benzyl-4'-methyl-2-oxo-3',4'-dihydrospiro-[indoline-3,2'-pyrrole]-3',5'-dicarboxylate

1.
Key Laboratory of Pesticide and Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China

Corresponding author: SHI De-Qing,
Received Date: 25 November 2013
Available Online: 13 March 2014
Fund Project: Supported by the National Natural Science Foundation of China (No. 21342004) (No. 21342004)the Syngenta PhD (postgraduate student) Programme (postgraduate student)

The crystal structure of the title compound (C₂₄H₂₄N₂O₅, M_r=420.45) has been determined by single-crystal X-ray diffraction. The crystal is of triclinic, space group P1 with a=8.991(1), b=11.166(1), c=11.169(1)Å, α=91.413(2), β=105.887(2), γ=90.992(2)°, V=1077.8(2)Å³, Z=2, D_c=1.296 g/cm³, F(000)=444, μ(MoKα)=0.091 mm^-1, the final R=0.0466 and wR=0.1507 for 4185 observed reflections (I>2σ(I)). The single-crystal X-ray diffraction data indicated intermolecular C(17)-H(17)…O(4), C(5)-H(5)…O(4) hydrogen bonds and C-H…π interaction in the structure.
- crystal structure,
- azomethine ylide,
- 2,3-butadienoate,
- 1,3-dipolar cycloaddition,
- pyrrolidinyl-spirooxindole
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