Citation: WANG Xiu-Yan, LIU Fu-Yi, ZHANG Yan-Na, GENG Li-Rong, ZHOU Hao, XU Zhan-Lin. A New Cadmium(Ⅱ) Coordination Polymer Constructed by 2-(2-Chloro-6-fluorophenyl)-1H-imidazo[4,5-f][1, 10]phenanthroline and 1,2,3-Benzenecarboxylate: Synthesis, Structure and Luminescence[J]. Chinese Journal of Structural Chemistry, ;2014, 33(3): 468-472. shu

A New Cadmium(Ⅱ) Coordination Polymer Constructed by 2-(2-Chloro-6-fluorophenyl)-1H-imidazo[4,5-f][1, 10]phenanthroline and 1,2,3-Benzenecarboxylate: Synthesis, Structure and Luminescence

WANG Xiu-Yan ^a,b ,
LIU Fu-Yi ^a,b ,
ZHANG Yan-Na ^a,b ,
GENG Li-Rong ^a,b ,
ZHOU Hao ^a,b ,
XU Zhan-Lin ^a,b,,

a.
a. Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Siping 136000, China;
b.
b. Department of Chemistry, Jilin Normal University, Siping 136000, China

Corresponding author: XU Zhan-Lin,
Received Date: 15 May 2013
Available Online: 19 February 2014
Fund Project:

A new Cd(Ⅱ) coordination polymer, namely, [Cd₃(1,2,3-BTC)₂(L)₂]·2.25H₂O (1, L=2-(2-chloro-6-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,2,3-BTC=1,2,3-ben-zenetricarboxylate), has been synthesized under hydrothermal conditions. The compound was characterized by single-crystal X-ray diffraction. It crystallizes in triclinic, space group P1 with a=11.650(2), b=12.240(2), c=19.760(4) Å, α=72.01(3), β=77.11(3), γ=83.48(3)°, V=2609.4(9) Å³, Z=2, C₅₆H₃₁Cd₃Cl₂F₂N₈O_14.25, M_r=1489.99, D_c=1.896 g/cm³, F(000)=1466, μ(MoKa)=1.401 mm^-1, R=0.0401 and wR=0.1104. Compound 1 shows a 1D chain structure, and the nei-ghboring 1D chains of 1 are joined together by π…π interactions to result in a 2D supramolecular layer. In addition, the luminescent property of 1 has been studied in the solid state at room temperature.
- coordination polymer,
- crystal structure,
- 1,2,3-benzenetricarboxylate,
- 2-(2-chloro-6-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline
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