Citation: ZHAO Bo, ZHANG Hong-Ling, TANG Wei, YUAN Wei-Guan, XIONG Fang, JING Lin-Hai, QIN Da-Bin. Structure of Co-crystals Formation from Imidazolium and Aromatic Ligands[J]. Chinese Journal of Structural Chemistry, ;2014, 33(3): 415-421. shu

Structure of Co-crystals Formation from Imidazolium and Aromatic Ligands

1.
Key Laboratory of Chemical Synthesis and Pollution Control of Sichuan Province, College of Chemistry and Chemical Engineering, China West Normal University, Nanchong 637002, China

Corresponding author: QIN Da-Bin,
Received Date: 1 May 2013
Available Online: 25 December 2013
Fund Project: This work was supported by the National Natural Science Foundation of China (21102117) (21102117) the Education Department of Sichuan Province (09ZX010) (09ZX010)

In this study, two new co-crystals based on rigid imidazolium ligand (2,2'-((1,1'-biphenyl)-4,4'-diyl)bis(2H-imidazo[1,5-a]pyridine-4-ium) hexafluorophosphate (L)) and 4,4'-bipyridine (Bpy) and benzene (Ben), formulated as L(Bpy)_0.5 (co-crystal 1) and L(Ben) (co-crystal 2), were obtained. Crystal data for 1: P1 space group with a=10.921(4), b=16.998(6), c=17.666(6) Å, α=95.720(7), β=104.272(7), γ=93.340(6)°, V=3150.5(19) Å³ and Z=2; and crystal data for 2: monoclinic C2/m space group with a=25.90(2), b=9.631(9), c=6.371(6) Å, β=95.26(2)°, V=1583(2) Å³ and Z=2. Co-crystal 1 was dependent on hydrogen bonds and π…π stacking, while only hydrogen bonds are present in 2. Two new co-crystals were characterized by IR, NMR spectra, thermogravimetric and ultraviolet absorption analyses.
- rigid imidazolium,
- aromatic ligand,
- non-covalent interactions,
- co-crystal,
- X-ray diffraction
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