Citation: TAN Hai-Yan, LIU Cheng, WANG Zhao-Hui, WU Jin-Ping. Simple Preparation, Structure and Conductivity of Nickel(Ⅱ) Benzenetricarboxylate Ni₃(BTC)₂·12H₂O[J]. Chinese Journal of Structural Chemistry, ;2014, 33(3): 401-406. shu

Simple Preparation, Structure and Conductivity of Nickel(Ⅱ) Benzenetricarboxylate Ni₃(BTC)₂·12H₂O

1.
Sustainable Energy Laboratory, Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 430074, China

Received Date: 29 November 2013
Available Online: 7 January 2014
Fund Project: This study was supported by the Natural Science Foundation of Hubei Province of China (No. 2011CDA070) (No. 2011CDA070)

Proton-conductive crystalline metal-organic framework nickel(Ⅱ) benzenetricar-boxylate Ni₃(BTC)₂·12H₂O(MOF-Ni) was prepared by the reaction of nickel(Ⅱ) nitrate and 1,3,5-benzenetricarboxylic (BTC) acid in a mixed solvent of N,N-dimethylformami-de(DMF)/C₂H₅OH/H₂O (1:1:1, ν/ν) at low temperature and short reaction time. It was characterized by thermogravimetric analyses (TG), FT-IR and N₂ adsorption-desorption. Single-crystal X-ray diffraction analysis indicated that the complex belongs to monoclinic system, space group C2 with a=17.407(6), b=12.878(5), c=6.542(2) Å, β=112.07°, V=1359.0(8) Å³, D_c=1.971 g/cm³, μ=2.166 mm^-1 and Z=2. Linear polarization resistance (LPR) analysis showed that the complex possesses semiconducting properties.
- metal-organic framework,
- solvothermal synthesis,
- mixed solution,
- semiconducting properties
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