Citation: LI Chao, MENG Su-Qin, LAN Mei-Ying, YU Ying-Hua, CHEN Jian-Xin, ZHANG Zhi-Chun. Synthesis, Structure and Norbornene Polymerization Catalyzed by Bis{1-[[(3-ethyl-6-methyl-2-pyridinyl)imino]methyl-enyl]-2-naphthalenolato-N,O}nickel(Ⅱ)[J]. Chinese Journal of Structural Chemistry, ;2014, 33(2): 289-293. shu

Synthesis, Structure and Norbornene Polymerization Catalyzed by Bis{1-[[(3-ethyl-6-methyl-2-pyridinyl)imino]methyl-enyl]-2-naphthalenolato-N,O}nickel(Ⅱ)

1.
a College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou 350007, China;
2.
b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: CHEN Jian-Xin,
Received Date: 2 June 2013
Available Online: 22 September 2013
Fund Project: Supported by the Natural Science Foundation of Fujian Province (2010J01026) (2010J01026) the Ministry of Education of China (No.208066) (No.208066) the Education Department of Fujian Province (JA07029) (JA07029)

The title complex bis{1-[[(3-ethyl-6-methyl-2-pyridinyl)imino]methylenyl]-2-naphthalenola-to-N,O}nickel has been synthesized by the reaction of 1-[[(3-ethyl-6-methyl-2-pyridinyl) imino] methylenyl]-2-naphthalenol with Ni(CH₃COO)₂·4H₂O, and characterized by IR spectrum and single-crystal X-ray diffraction analysis. The crystal belongs to the orthorhombic system, space group Pbca with a=11.100(2), b=15.900(3), c=18.000(4) Å, V=3176.8(11) Å³, C₃₈H₃₄N₄NiO₂, M_r=637.40, Z=4, D_c=1.333 g/cm³, μ=0.651 mm^-1, F(000)=1336, the final R=0.0783 and wR=0.2119. This title compound was investigated for the catalytic behavior towards norbornene (NB) vinyl addition polymerization. And the complex exhibited good catalytic activity to catalyze norbornene polymerization using MAO as a cocatalyst.
- nickel complex,
- catalyst,
- crystal structure,
- norbornene polymerization
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