Citation: JIA Wei-Guo, ZHAO Cheng-An, MA Li-Ya, SHENG En-Hong. Synthesis and Characterization of Nickel(Ⅱ) Complex Bearing 2,9-di-tert-butyl-1,10-phenanthroline Ligand[J]. Chinese Journal of Structural Chemistry, ;2014, 33(2): 189-192. shu

Synthesis and Characterization of Nickel(Ⅱ) Complex Bearing 2,9-di-tert-butyl-1,10-phenanthroline Ligand

1.
College of Chemistry and Materials Science, Center for Nano Science and Technology, The Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecular-based Materials, Anhui Normal University, Wuhu 241000, China

Corresponding author: JIA Wei-Guo,
Received Date: 17 July 2013
Available Online: 15 November 2013
Fund Project: This work was financially supported by the National Natural Science Foundation of China (21102004) (21102004)

The complex DtbpNiCl₂ (Dtbp=2,9-di-tert-butyl-1,10-phenanthroline) was synthesized and characterized by X-ray single-crystal structure analysis. For the complex:C₂₀H₂₄C₁₂N₂Ni·CH₂Cl₂, M_r=506.95, monoclinic, space group P2₁/c, a=9.5905(3), b=13.7587(3), c=17.3364(5) Å, β=94.244(2)°, V=2281.31(11) Å³, Z=4, D_c=1.476 g/cm³, λ=1.54184 Å, μ=5.606 mm^-1, F(000)=1048,S=1.079, R=0.0402 and wR=0.1010 for 3223 observed reflections with I>2σ(I). In complex DtbpNiCl₂, the nickel adopts a distorted tetrahedral geometry coordinated by two nitrogen atoms of Dtbp and two chlorine ions. The complex is connected by intermolecular C-H…Cl hydrogen bonds to form a 1D structure in the solid state.
- nickel,
- complex,
- crystal structure,
- hydrogen bonds
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