Citation: WANG Hao, WEN Rong-Mei, CHANG Ze, WANG Qian, LI Nan, KONG Ling-Yu. Two New Cu(Ⅱ) Coordination Polymers Based on 2,5-Furandicarboxylic Acid and 2,2'-bipyridine:Synthesis and Crystal Structure[J]. Chinese Journal of Structural Chemistry, ;2014, 33(1): 97-103. shu

Two New Cu(Ⅱ) Coordination Polymers Based on 2,5-Furandicarboxylic Acid and 2,2'-bipyridine:Synthesis and Crystal Structure

WANG Hao ^a ,
WEN Rong-Mei ^a ,
CHANG Ze ^a ,
WANG Qian ^b ,
LI Nan ^b ,
KONG Ling-Yu ^b

1.
a Department of Chemistry, TKL of Metal-and Molecule-based Material Chemistry, Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education), and Synergetic Innovation Center of Chemical Science and Engineering(Tianjin), Nankai University, Tianjin 300071, China;
2.
b Tianjin Institute of Pharmaceutical Sciences, Tianjin 300020, China

Received Date: 17 May 2013
Available Online: 19 August 2013
Fund Project:

Two new Cu(Ⅱ) coordination polymers,[Cu(FDA)(BPY)(H₂O)]_n (1) and {[Cu(FDA)(BPY)(H₂O)]·2H₂O}_n (2) (H₂FDA=2,5-furandicarboxylic acid, BPY=2,2'-bipyridine), have been synthesized and structurally characterized by single-crystal X-ray diffraction as well as elemental analysis and IR. Compound 1 crystallizes in monoclinic, space group P2₁/c, with a=7.5915(15), b=8.4050(17), c=24.204(6) Å, β=99.05(3)°, V=1525.1(6) Å³, D_c=1.706 g/cm³, C₁₆H₁₂CuN₂O₆, M_r=391.82, F(000)=796, μ(MoKα)=1.470 mm^-1, Z=4, R=0.0633 and wR=0.1059 for 2389 observed reflections (I>2σ(I)), R=0.0738, and wR=0.1098 for all data. Complex 2 belongs to triclinic space group P1 with a=8.8660(18), b=8.9112(18), c=12.525(3) Å, α=88.41(3), β=69.38(3), γ=66.95(3)°, V=845.2(3) Å³, D_c=1.681 g/cm³, C₁₆H₁₆CuN₂O₈, M_r=427.85, F(000)=438, μ(MoKα)=1.342 mm^-1, Z=2, R=0.0290 and wR=0.0690 for 2767 observed reflections (I>2σ(I)), R=0.0329 and wR=0.0706 for all data. Complexes 1 and 2 are both coordination polymers with one-dimensional chain structures bridged by the protonated FDA ligands, which are assembled into three-dimensional supramolecular structures through hydrogen bonding interactions and π-π packing interactions between the chains.
- 2,5-furandicarboxylic acid,
- copper complex,
- crystal structure,
- 2,2'-bipyridine
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