Citation: LI Jie, SHENG Tian-Lu, HUANG Yi-Hui, FU Rui-Biao, HU Sheng-Min, WEN Yue-Hong, WU Xin-Tao. A Three-dimensional Cd(Ⅱ) Coordination Polymer with Unique 8-Connected LOMFOI Topology Based on Mixed Flexible N/O Ligands[J]. Chinese Journal of Structural Chemistry, ;2014, 33(1): 43-48. shu

A Three-dimensional Cd(Ⅱ) Coordination Polymer with Unique 8-Connected LOMFOI Topology Based on Mixed Flexible N/O Ligands

LI Jie ^a,b ,
SHENG Tian-Lu ^a ,
HUANG Yi-Hui ^a,b ,
FU Rui-Biao ^a ,
HU Sheng-Min ^a ,
WEN Yue-Hong ^a ,
WU Xin-Tao ^a,,

1.
a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
2.
b Graduate University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: WU Xin-Tao,
Received Date: 17 June 2013
Available Online: 16 September 2013
Fund Project: the National Science Foundation of China (21073192, 21203194 and 21233009) (2012CB821702)

A new metal-organic framework, {[Cd(DPA)(OBA)]·(H₂O)}_n (1, DPA=4,4'-dipyri-dylamine, H₂OBA=4,4'-oxybisbenzoic acid), has been synthesized and characterized by elemental analysis, IR and single-crystal X-ray diffraction. Single-crystal X-ray analysis shows that it is a 3-D framework. Complex 1 crystallizes in monoclinic, space group C2/c with a=21.699(7), b=12.192(4), c=17.566(5) Å, β=105.254(5)°, V=4483.43 Å³, Z=8, D_c=1.653 g/cm³, μ=1.021 mm^-1, F(000)=2240, the final R=0.0307, wR=0.0867 (I>2σ(I)). Complex 1 exhibits a rare three-dimensional highly 8-connected LOMFOI topology with a point symbol of {4²⁴·6⁴}. Thermogravimetric analysis shows that the decomposition temperature of the host framework of the complex is above 400℃.
- coordination polymer,
- 8-connected,
- lomfoi topology
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