Citation: WANG Xiu-Yan, LIU Fu-Yi, ZHANG Yan-Na, XU Zhan-Lin. Synthesis, Crystal Structure and Photoluminescence of a New Zn(Ⅱ) Dimer Constructed by 1,10-Phenanthroline Derivative and Flexible Dicarboxylate[J]. Chinese Journal of Structural Chemistry, ;2014, 33(1): 33-36. shu

Synthesis, Crystal Structure and Photoluminescence of a New Zn(Ⅱ) Dimer Constructed by 1,10-Phenanthroline Derivative and Flexible Dicarboxylate

WANG Xiu-Yan ^a,b ,
LIU Fu-Yi ^a,b ,
ZHANG Yan-Na ^a,b ,
XU Zhan-Lin ^a,b,,

1.
a Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Jilin Normal University, Siping 136000, China;
2.
b Department of Chemistry, Jilin Normal University, Siping 136000, China

Corresponding author: XU Zhan-Lin,
Received Date: 23 May 2013
Available Online: 24 September 2013
Fund Project: the Education Office of Jilin Province (No.2013212) (No.201115220)

A new compound,[Zn(L)(1,4-chdc)]₂·2H₂O (1, 1,4-chdc=1,4-cyclohexanedicar-boxylate and L=11-fluoro-dipyrido[3,2-a:2',3'-c]phenazine), has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction. The crystal of 1 belongs to triclinic, space group P1 with a=9.4679(19), b=10.915(2), c=12.577(3) Å, α=77.22(3), β=74.73(3), γ=65.47(3)°, C₅₂H₃₉F₂N₈O₁₀Zn₂, M_r=1104.65, V=1131.4(4) Å³, Z=1, D_c=1.621 g/cm³,S=1.091, μ(MoKα)=1.143 mm^-1, F(000)=565, R=0.0426 and wR=0.1171. In 1, two 1,4-chdc anions bridge two Zn(Ⅱ) atoms to form a dimer. The neighboring dimers are further extended by π-π stacking interactions to form a 2D supramolecular layer. The luminescent property of the compound has also been investigated.
- crystal structure,
- coordination polymer,
- 1,4-cyclohexanedicarboxylate,
- luminescence
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