Citation: Li Yanping, Gao Ge, Feng Chuanqi, Yan Dongwei, Zhou Shaoxiong. Study on the Preparation and Electrochemical Performance of Ni_0.8Co_0.15Al_0.05C₂O₄@Graphene Composites[J]. Chemistry, ;2017, 80(11): 1049-1054. shu

Study on the Preparation and Electrochemical Performance of Ni_0.8Co_0.15Al_0.05C₂O₄@Graphene Composites

Li Yanping ^1,2 ,
Gao Ge ³ ,
Feng Chuanqi ³ ,
Yan Dongwei ^1,2,, ,
Zhou Shaoxiong ^1,2,,

1.
China Iron & Steel Research Institute Group, Beijing 100081
2.
Research and Development Center, Advance Technology & Materials Co., Ltd, Beijing 100081
3.
College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062

Corresponding author: Yan Dongwei, dwyan@iccas.ac.cn Zhou Shaoxiong, sxzhou@atmcn.com
Received Date: 11 July 2017
Accepted Date: 4 August 2017

Figures(5)

Transition metal oxalate/graphene composites have excellent electrochemical performance which are widely used in lithium ion batteries. In this work, with the raw materials of NiSO₄·6H₂O, CoSO₄·7H₂O, Al₂(SO₄)₃·18H₂O and H₂C₂O₄ at a certain molar ratio prepared into solution, precursor Ni_0.8Co_0.15Al_0.05C₂O₄ was obtained by hydrothermal reaction for 12 h under 120℃. Then transition metal oxalate/graphene composites Ni_0.8Co_0.15Al_0.05C₂O₄@Graphene were prepared by reduction of graphene oxide. And the structure, morphology and electrochemical properties of materials were characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM). SEM indicated that all the samples were cuboid with uniform size and irregular shape. Electrochemical test showed that the capacity of NCA-C₂O₄@G was higher than that of NCA-C₂O₄. And the first discharge capacity of NCA-C₂O₄@G composites at 0.1 C density is 1956 mAh/g. After at 0.1 C, 0.2 C, 0.5 C, 1.0 C, 2.0 C for cycles, the discharge capacity of composite material could be quickly increased to 720 mAh/g when the test conditions recovered to 100 mA/g, and the capacity keeps stable in the subsequent 50 cycles. These indicated that as-prepared NCA-C₂O₄@G composites have good electrochemical performance.
- Ni_0.8Co_0.15Al_0.05C₂O₄,
- Hydrothermal reaction,
- Transition metal oxalate,
- Graphene,
- Composites
1. [1]
  E Uchaker, G Cao. Nano Today, 2014, 9(4):499~524.
2. [2]
  M M Thackeray, C Wolverton, E D Isaacs. Energy Environ. Sci., 2012, 5(7):7854~7863.
3. [3]
  B Dunn, J M Tarascon. Science, 2011, 334(6058):928.
4. [4]
  Z Wu, G Zhou, L Yin et al. Nano Energy, 2012, 1(1):107~131.
5. [5]
  Y Xu, G Jian, Y Liu. Nano Energy, 2014, 3:26~35.
6. [6]
  Q An, F Lv, Q Liu et al. Nano Lett., 2014, 14(11):6250~6256.
7. [7]
  Q Zhang, H Chen, X Han et al. ChemSusChem, 2016, 9(2):186~196.
8. [8]
  X Jia, Z Chen, X Cui et al. ACS Nano, 2012, 6(11):9911~9919.
9. [9]
  H Sohn, Z Chen, Y S Jung et al. J. Mater. Chem. A, 2013, 1(14):4539~4545.
10. [10]
  K Yang, Y Hong, Y Kang et al. ChemSusChem, 2013, 6(12):2299~2303.
11. [11]
  G Zhang, X W D Lou. Angew. Chem. Int. Ed., 2014, 53(34):9041~9044.
12. [12]
  Y Guo, L Yu, C Wang et al. Adv. Funct. Mater., 2015, 25(32):5184~5189.
13. [13]
  L Shen, Q Che, H Li et al. Adv. Funct. Mater., 2014, 24(18):2630~2637.
14. [14]
  G Huang, F Zhang, X Du et al. ACS Nano, 2015, 9(2):1592~1599.
15. [15]
  X Fan, J Shao, X Xiao et al. J. Mater. Chem. A, 2014, 2(43):18367~18374.
16. [16]
  B Liu, J Zhang, X Wang et al. Nano Lett., 2012, 12(6):3005~3011.
17. [17]
  W Zhou, J Zhu, C Cheng et al. Energy Environ. Sci., 2011, 4(12):4954~4961.
18. [18]
  Y Li, Q Zhang, J Zhu et al. J. Mater. Chem. A, 2014, 2(9):3163~3168.
19. [19]
  W Wei, S Yang, H Zhou et al. Adv. Mater., 2013, 25(21):2909~2914.
20. [20]
  X Wang, X Zhou, K Yao et al. Carbon, 2011, 49(1):133~139.
21. [21]
  H Sun, X Sun, T Hu et al. J. Phys. Chem. C, 2014, 118(5):2263~2272.
22. [22]
  S Choi, Y Kang. ChemSusChem, 2014, 7(2):523~528.
23. [23]
  S Yang, X Feng, S Ivanovici et al. Angew. Chem., 2010, 122(45):8586~8589.
24. [24]
25. [25]
26. [26]
27. [27]
  L Eben, B Wang, H Peng et al. J. Power Sources, 2014, 258(1):9~18.
28. [28]
  G Hou, B Cheng, Y Cao et al. Nano Energy, 2016, 24(7):111~120.
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Study on the Preparation and Electrochemical Performance of Ni_0.8Co_0.15Al_0.05C₂O₄@Graphene Composites