Citation: LI Xiu-ping, ZHAO Rong-xiang, XING Peng-fei. Preparation of NiWO₄/g-C₃N₄ and its ultra-deep desulfurization properties in ionic liquid[J]. Journal of Fuel Chemistry and Technology, ;2017, 45(11): 1340-1348. shu

Preparation of NiWO₄/g-C₃N₄ and its ultra-deep desulfurization properties in ionic liquid

1.
School of chemistry and Materials Science, College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning University of Petroleum & Chemical Technology, Fushun 113001, China
2.
School of Petrochemical Engineering, College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning University of Petroleum & Chemical Technology, Fushun 113001, China

Corresponding author: ZHAO Rong-xiang, zylhzrx@126.com
Received Date: 12 April 2017
Revised Date: 27 July 2017

Figures(12)

The NiWO₄ nanoparticles were synthesized by hydrothermal method. The supported catalysts NiWO₄/g-C₃N₄ were prepared by a simple mixing-calcination method. XRD, FT-IR, EDS, SEM, BET and XPS were used to characterize the morphology and structure of NiWO₄/g-C₃N₄. The prepared NiWO₄/g-C₃N₄ was used as catalyst, hydrogen peroxide as oxidant, 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid ([BMIM]BF₄) as extractant for oxidative desulfurization. The effects of catalyst loading, the amount of hydrogen peroxide, ionic liquid and catalyst, reaction temperature, reaction time, and different sulfur compounds on desulfurization efficiency were studied. The desulfurization rate can reach 97.35% at the optimum reaction conditions:5 mL of model oil, 0.2 mL of hydrogen peroxide, 1.0 mL of [BMIM] BF₄, 0.03 g of NiWO₄/g-C₃N₄, 80 ℃ of reaction temperature and 140 min of reaction time. The results showed that NiWO₄/g-C₃N₄ had good catalytic stability, and the catalytic activity was not significantly reduced after 5 repeated reactions.
- NiWO₄/g-C₃N₄,
- oxidative desulfurization,
- dibenzothiophene,
- ionic liquid
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of NiWO4/g-C3N4 and its ultra-deep desulfurization properties in ionic liquid

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通讯作者: 陈斌, bchen63@163.com

Preparation of NiWO₄/g-C₃N₄ and its ultra-deep desulfurization properties in ionic liquid