Citation: ZHAO Xin, LI Kai, LI Ming, MA Shan-wei, ZHU Xi-feng. Separating phenols from high-temperature fraction of bio-oil by precipitation[J]. Journal of Fuel Chemistry and Technology, ;2016, 44(02): 201-208. shu

Separating phenols from high-temperature fraction of bio-oil by precipitation

1.
Key Laboratory for Biomass Clean Energy of Anhui Province, University of Science and Technology of China, Hefei 230026, China

Corresponding author: ZHU Xi-feng,
Received Date: 18 September 2015
Available Online: 19 November 2015
Fund Project: 国家重点基础研究发展规划(973计划,2013CB228103) (973计划,2013CB228103)中国科学院重点部署项目(KGZD-EW-304-3)资助. (KGZD-EW-304-3)

To improve the utilization of chemicals in bio-oil,recovery of phenolic compounds from high temperature bio-oil fractions by metal ion precipitation was studied.The effects of concentration of sodium hydroxide solution,reaction temperature and reaction time on the recovery of phenolic compounds by magnesium ion were examined using gas chromatography-mass spectrometry(GC-MS).The results demonstrate that the precipitation was formed instead of a salt of magnesium phenols.The optimum reaction conditions are reaction temperature of 25℃,2.5 mol/L of sodium hydroxide solution,and reaction time of 20 min.In this case,the recovery of 4-ethylphenol from high temperature bio-oil fractions reaches 34.97%.
- bio-oil,
- phenol,
- magnesium ion,
- precipitation,
- recovery
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沈阳化工大学材料科学与工程学院沈阳 110142