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旋转滑动弧氩等离子体裂解甲烷制氢

张浩 ,  朱凤森 ,  李晓东 ,  吴昂键 ,  薄拯 ,  岑可法

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引用本文: 张浩, 朱凤森, 李晓东, 吴昂键, 薄拯, 岑可法. 旋转滑动弧氩等离子体裂解甲烷制氢[J]. 燃料化学学报, 2016, 44(02): 192-200. shu
Citation:  ZHANG Hao, ZHU Feng-sen, LI Xiao-dong, WU Ang-jian, BO Zheng, CEN Ke-fa. Rotating gliding arc plasma assisted hydrogen production from methane decomposition in argon[J]. Journal of Fuel Chemistry and Technology, 2016, 44(02): 192-200. shu

旋转滑动弧氩等离子体裂解甲烷制氢

  • 1.

    浙江大学 能源清洁利用国家重点实验室, 浙江 杭州 310027

    • 通讯作者: 李晓东
  • 基金项目:

    国家自然科学基金(51576174) (51576174)

    高等学校博士学科点专项科研基金(20120101110099) (20120101110099)

    中央高校基本科研业务费专项资金(2015FZA4011)项目资助. (2015FZA4011)

摘要: 采用切向气流和磁场协同驱动的旋转滑动弧氩等离子体,先通过光谱分析法计算了其电子温度和电子密度,了解其物理特性,将其应用于甲烷裂解制氢,研究了进气流量和CH4/Ar比对反应效果的影响。结果表明,该滑动弧系统电子温度为1.0-2.0 eV,电子密度高达1015 cm-3,是介于热与低温等离子体之间的一种等离子体形式,具有独特的物理特性,可以在达到较高反应效率的同时,保持较大的处理量;在CH4裂解制氢实验中,CH4转化率可达22.1%-70.2%,并随进气流量和CH4/Ar比的增大均逐渐降低;H2选择性为21.2%-61.2%,并随进气流量的增大先基本不变后有所增大,随CH4/Ar比的增大逐渐降低;与应用于甲烷裂解的不同形式的低温等离子体对比(如微波、射频、介质阻挡放电等)可以发现,旋转滑动弧在获得较高甲烷转化率、较高H2选择性和较低制氢能耗的同时,还可以保持较大的处理量,即进气流量可达6-20 L/min。

English

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  • 收稿日期:  2015-06-09
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