Citation: LUO Yao-ya, WANG Sen, GUO Shu-jia, YUAN Kai, WANG Hao, DONG Mei, QIN Zhang-feng, FAN Wei-bin, WANG Jian-guo. Study on different synthesis methods of Zn_xCe_2-yZr_yO₄/SAPO-34 catalyst and its catalytic performance in syngas to low-carbon olefins[J]. Journal of Fuel Chemistry and Technology, ;2020, 48(5): 594-600. shu

Study on different synthesis methods of Zn_xCe_2-yZr_yO₄/SAPO-34 catalyst and its catalytic performance in syngas to low-carbon olefins

LUO Yao-ya ^1,2 ,
WANG Sen ^1,, ,
GUO Shu-jia ^1,2 ,
YUAN Kai ^1,2 ,
WANG Hao ^1,, ,
DONG Mei ¹ ,
QIN Zhang-feng ¹ ,
FAN Wei-bin ¹ ,
WANG Jian-guo ^1,2

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Corresponding author: WANG Sen, wangsen@sxicc.ac.cn. WANG Hao, wanghao@sxicc.ac.cn
Received Date: 19 January 2020
Revised Date: 16 March 2020

Fund Project: The project was supported by the National Natural Science Foundation of China (21802157, 21773281) and the Natural Science Foundation of Shanxi Province of China (201901D211581)the National Natural Science Foundation of China 21773281the National Natural Science Foundation of China 21802157the Natural Science Foundation of Shanxi Province of China 201901D211581

Figures(7)

A series of Zn_xCe_2-yZr_yO₄ metal oxides were synthesized by sol gel method, hydrothermal method and co-precipitation method respectively and characterized by XRD, BET, HRTEM, CO-TPD, Raman and XPS. The effects of the synthesis method on the morphology, grain size and oxygen vacancy concentration and the catalytic performance in syngas to low-carbon olefin reaction of the Zn_xCe_2-yZr_yO₄ catalysts were investigated. The results show that the shape, exposed crystal surface, grain size and surface oxygen vacancy concentration of Zn_xCe_2-yZr_yO₄ solid solution are strongly dependent on the synthesis method. Under the reaction conditions of 300 ℃ and 1.0 MPa, the dual-functional catalysts of Zn_xCe_2-yZr_yO₄/SAPO-34 prepared by sol-gel method have the highest low-carbon olefin (C_2-4⁼) selectivity (79.5%), while the selectivities of methane and CO₂ are only 5.5% and 10.7%, respectively. Here the direct conversion of syngas to low-carbon olefins are realized at low temperature and pressure and the formation of methane and CO₂ is greatly reduced.
- syngas to olefin,
- sol-gel method,
- hydrothermal method,
- co-precipitation method,
- low temperature and pressure
1. [1]
  TORRES GALVIS H M, DE JONG K P. Catalysts for production of lower olefins from synthesis gas:A review[J]. ACS Catal, 2013,3(9):2130-2149. doi: 10.1021/cs4003436
2. [2]
  WANG W, WANG S P, MA X B, GONG J L. Recent advances in catalytic hydrogenation of carbon dioxide[J]. Chem Soc Rev, 2011,40(7):3703-3727. doi: 10.1039/c1cs15008a
3. [3]
  ARESTA M, DIBENEDETTO A, ANGELINI A. Catalysis for the valorization of exhaust carbon:from CO₂ to chemicals, materials, and fuels. technological use of CO₂[J]. Chem Rev, 2014,114(3):1709-1742. doi: 10.1021/cr4002758
4. [4]
  GALVIS H M T, BITTER J H, DAVIDIAN T, MATTHIJS R, DUGULAN A L, JONG K P D. Iron particle size effects for direct production of lower olefins from synthesis gas[J]. JACS, 2012,134(39):16207-16215. doi: 10.1021/ja304958u
5. [5]
  CHENG K, KANG J C, KING D L, SUBRAMANIAN V Y, ZHOU C, ZHANG Q H, WANG Y. Advances in catalysis for syngas conversion to hydrocarbons[J]. Adv Catal, 2017,60:125-208.
6. [6]
  JIAO F, LI J, PAN X L, XIAO J, LI H, MA H, WEI M, PAN Y, ZHOU Z, LI M. Selective conversion of synthesis gas into lower olefins[J]. Science, 2016,351(6277):1065-1068. doi: 10.1126/science.aaf1835
7. [7]
  CHENG K, GU B, LIU X, KANG J C, ZHANG Q H, WANG Y. Direct and highly selective conversion of synthesis gas to lower olefins:Design of a bifunctional catalyst combining methanol synthesis and carbon-carbon coupling[J]. Angew Chem Int Ed, 2016,55(15):4725-4728. doi: 10.1002/anie.201601208
8. [8]
  ZHU Y F, PAN X L, JIAO F, LI J, YANG J H, DING M Z, HAN Y, LIU Z, BAO X H. Role of manganese oxide in syngas conversion to light olefins[J]. ACS Catal, 2017,7:2800-2804. doi: 10.1021/acscatal.7b00221
9. [9]
  LIU X L, ZHOU W, YANG Y, CHENG K, KANG J C, ZHANG L, ZHANG G Q, MIN X J, ZHANG Q H, WANG Y. Design of efficient bifunctional catalysts for direct conversion of syngas into lower olefins via methanol/dimethyl ether intermediates[J]. Chem Sci, 2018,9(20):4708-4718. doi: 10.1039/C8SC01597J
10. [10]
  SU J J, WANG D, Wang Y D, ZHOU H B, LIU C, LIU S, WANG C M, YANG W M, XIE Z K, HE M Y. Direct conversion of syngas to light olefins over Zr-In₂O₃ and SAPO-34 bifunctional catalysts:Design of oxide component and construction of reaction network[J]. ChemCatChem, 2018,10:1536-1541. doi: 10.1002/cctc.201702054
11. [11]
  REDDY B M, KHAN A, LAKSHMANAN P, AOUINE M, LORIDANT S, VOLTA J C. Structural characterization of nanosized CeO₂-SiO₂, CeO₂-TiO₂, and CeO₂-ZrO₂ catalysts by XRD, Raman, and HREM techniques[J]. J Phys Chem B, 2005,109(8):3355-3363. doi: 10.1021/jp045193h
12. [12]
  CHEN A L, ZHOU Y, TA N, LI Y, SHEN W J. Redox properties and catalytic performance of ceria-zirconia nanorods[J]. Catal Sci Technol, 2015,5(8):4184-4192. doi: 10.1039/C5CY00564G
13. [13]
  ZHANG P P, TAN L, YANG G H, TSUBAKI N. One-pass selective conversion of syngas to paraxylene[J]. Chem Sci, 2017,8(12):7941-7946. doi: 10.1039/C7SC03427J
14. [14]
  ZHOU C, SHI J Q, ZHOU W, CHENG K, ZHANG Q H, KANG J C, WANG Y. Highly active ZnO-ZrO₂ aerogels integrated with H-ZSM-5 for aromatics synthesis from carbon dioxide[J]. ACS Catal, 2020,10(1):302-310.
15. [15]
  ZHANG Z X, WANG Y H, LU J M, ZHANG C F, WANG M, LI M R, LIU X B, WANG F. Conversion of isobutene and formaldehyde to diol using praseodymium-doped CeO₂ catalyst[J]. ACS Catal, 2016,8:2635-2644.
16. [16]
  LIANG F L, YU Y, ZHOU W, XU X Y, ZHU Z H. Highly defective CeO₂ as a promoter for efficient and stable water oxidation[J]. J Mater Chem A, 2015,3(2):634-640. doi: 10.1039/C4TA05770H
17. [17]
  PIUMETTI M, BENSAID S, RUSSO N, FINO D. Nanostructured ceria-based catalysts for soot combustion:Investigations on the surface sensitivity[J]. Appl Catal B:Environ, 2015,165:742-751. doi: 10.1016/j.apcatb.2014.10.062
1. [1]
  Zunyuan Xie , Lijin Yang , Zixiao Wan , Xiaoyu Liu , Yushan He . Exploration of the Preparation and Characterization of Nano Barium Titanate and Its Application in Inorganic Chemistry Laboratory Teaching. University Chemistry, 2024, 39(4): 62-69. doi: 10.3866/PKU.DXHX202310137
2. [2]
  Shuting Zhuang , Lida Zhao . Teaching through Research: A Comprehensive Experiment on Carbon Quantum Dots from Microplastic Waste. University Chemistry, 2025, 40(10): 217-224. doi: 10.12461/PKU.DXHX202412010
3. [3]
  Tiejun Su . The Construction and Application of the Calculation Formula for Endpoint Error in Precipitation Titration: A Case Study of the Mohr Method. University Chemistry, 2024, 39(11): 384-387. doi: 10.12461/PKU.DXHX202402039
4. [4]
  Ranhui Fu , Shixin Zhou , Ran Ji , Feifei Gao , Hui Xu . 季膦盐合成实验的改进与拓展——水相一步法合成乙基三苯基溴化膦及其力致发光锰配合物的制备及表征. University Chemistry, 2026, 41(5): 252-263. doi: 10.12461/PKU.DXHX202510018
5. [5]
  Zhou Fang , Zhihao Zhang , Weihan Jiang , Kin Shing Chan . Warfarin: From Poison to Cure, the Remarkable Journey of a Molecule. University Chemistry, 2025, 40(4): 326-330. doi: 10.12461/PKU.DXHX202406038
6. [6]
  Zhi Zheng , Qi Ma , Feiyang Liu , Gukui Chen , Junlong Zhao . Defeating Dental Plaque with Science: Unlocking the Power of Biofilm Management. University Chemistry, 2026, 41(2): 295-300. doi: 10.12461/PKU.DXHX202502088
7. [7]
  Mei-Xia Yang , Zhen-Hong He , Long-Rui Wang , You-Xing Yang . Route for Turning Waste CH₄ and CO₂ into Valuable Products: Reforming for Syngas. University Chemistry, 2026, 41(2): 197-207. doi: 10.12461/PKU.DXHX202503012
8. [8]
  Min Hu , Yinghuan Li , Yanhong Bai , Yanping Ren , Juanjuan Song , Yongxian Fan , Dongcheng Liu , Xiuqiong Zeng , Faqiong Zhao , Wenwei Zhang , Mei Shi , Wan Li , Xiuyun Wang , Weihong Li , Xiaohang Qiu , Yong Fan , Jianrong Zhang , Shuyong Zhang . Suggestions on the Method of Hydrothermal-Solventthermal Synthesis and Their Operation Standards. University Chemistry, 2026, 41(3): 208-215. doi: 10.12461/PKU.DXHX202507034
9. [9]
  Jiaojiao Yu , Bo Sun , Na Li , Cong Wen , Wei Li . Improvement of Classical Organic Experiment Based on the “Reverse-Step Optimization Method”: Taking Synthesis of Ethyl Acetate as an Example. University Chemistry, 2025, 40(3): 333-341. doi: 10.12461/PKU.DXHX202405177
10. [10]
  Haoying ZHAI , Lanzong WEN , Wenjie LIAO , Qin LI , Wenjun ZHOU , Kun CAO . Metal-organic framework-derived sulfur-doped iron-cobalt tannate nanorods for efficient oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 1037-1048. doi: 10.11862/CJIC.20240320
11. [11]
  Haoying ZHAI , Jing WEI , Wenjie LIAO , Jiarui HUANG , Yangli EQI , Weimin GUO , Wenjun ZHOU . B-doped FeCo phytate complex as an efficient electrocatalyst for oxygen evolution reaction. Chinese Journal of Inorganic Chemistry, 2026, 42(6): 1276-1288. doi: 10.11862/CJIC.20260011
12. [12]
  Bingliang Li , Yuying Han , Dianyang Li , Dandan Liu , Wenbin Shang . One-Step Synthesis of Benorilate Guided by Green Chemistry Principles and in vivo Dynamic Evaluation. University Chemistry, 2024, 39(6): 342-349. doi: 10.3866/PKU.DXHX202311070
13. [13]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF-Templated Synthesis of Nitrogen-Doped Carbon for Enhanced Electrochemical Sodium Ion Storage and Removal. Acta Physico-Chimica Sinica, 2025, 41(3): 100026-0. doi: 10.3866/PKU.WHXB202405002
14. [14]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
15. [15]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-0. doi: 10.1016/j.actphy.2025.100054
16. [16]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
17. [17]
  Wan JIANG , Shiman ZHAO , Wenting ZHANG , Duihai TANG . Mo₂N nanoparticles encapsulated with N-doped carbon materials: Synthesis by solvent-free method and hydrogen evolution electrocatalytic performance. Chinese Journal of Inorganic Chemistry, 2026, 42(5): 906-916. doi: 10.11862/CJIC.20250348
18. [18]
  Xinxin Dai , Di Lan , Xingliang Chen , Xingwei Wang , Guangbin Ji . One pot green synthesis and electromagnetic wave absorption performance of manganese dioxide@nitrogen-doped carbon@NiFe₂O₄ hybrids. Acta Physico-Chimica Sinica, 2026, 42(8): 100302-0. doi: 10.1016/j.actphy.2026.100302
19. [19]
  Mengyang LI , Zhonghao NIU , Hao XU , Jingli XIE . One-pot synthesis of 4H-pyran derivatives catalyzed by viologen-modified metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2026, 42(7): 1513-1522. doi: 10.11862/CJIC.20250205
20. [20]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204

Get Citation

PDF

XML

Metrics

PDF Downloads(13)
Abstract views(1742)
HTML views(351)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Study on different synthesis methods of ZnxCe2-yZryO4/SAPO-34 catalyst and its catalytic performance in syngas to low-carbon olefins

Metrics

通讯作者: 陈斌, bchen63@163.com

Study on different synthesis methods of Zn_xCe_2-yZr_yO₄/SAPO-34 catalyst and its catalytic performance in syngas to low-carbon olefins